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研究生： 林姵瓊
Lin, Pei-Chiung
論文名稱： 鐵、銅、鎳、鈦及其合金於氯化鋁與氯化1-乙基-3-甲基咪唑離子液體中的腐蝕行為探討
Corrosion Characteristics of Iron, Copper, Nickel, Titanium and the Alloys in Aluminum Chloride – 1-ethyl-3-methylimidazolium Chloride Ionic Liquid
指導教授： 孫亦文
Sun, I-Wen
學位類別： 碩士
Master
系所名稱： 理學院 - 數學系應用數學碩博士班
Department of Mathematics
論文出版年： 2011
畢業學年度： 99
語文別： 中文
論文頁數： 100
中文關鍵詞： AlCl3EMIC離子液體 、鐵 、鎳 、銅 、鈦 、腐蝕行為
外文關鍵詞： AlCl3EMIC ionic liquid, iron, nickel, copper, titanium, corrosion behavior
相關次數： 點閱：62  下載：4 
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    • 本實驗選擇九種常用的金屬材料(304不銹鋼、316不銹鋼、碳鋼、鈦金屬、鎳金屬、銅金屬、黃銅、鎳基合金600、鎳銅合金400)，在三種不同比例的室溫離子液體進行腐蝕行為的探討，此三種離子液體分別為中性離子液體(AlCl3/EMIC：50/50 mol%)、酸性離子液體(AlCl3/EMIC：60/40 mol%)以及鹼性離子液體(AlCl3/EMIC：44/56 mol%)。利用交流阻抗、動電位極化掃描、定電位電化學技術探討和掃描試電子顯微鏡分析表面形貌。
    金屬材料在離子液體中的腐蝕行為和過去的傳統水溶液中不同。在中性離子液體中，304不銹鋼、316不銹鋼、鎳金屬、鎳基合金600、鎳銅合金400以及黃銅為一抗蝕性佳的金屬材料，而碳鋼為「活性轉鈍化」的腐蝕行為，銅金屬和鈦金屬則是抗蝕性較差的金屬材料。在鹼性離子液體中，鈦金屬有一大約0.6V鈍化區，其餘金屬材料在此離子液體中抗蝕性較差。在酸性離子液體中，所有的金屬在此液體中抗蝕性較差。尋找其他防蝕的金屬材料或是理想處理離子液體與金屬材料之間之腐蝕問題的方法為主要課題。

    In this study, we discuss the corrosion behavior of nine common metal materials (304 stainless steel, 316 stainless steel, carbon steel, titanium, nickel, copper, brass, Inconel 600 and Monel 400) in three different proportions of the room-temperature ionic liquid including neutral ionic liquid (AlCl3/EMIC: 50/50 mol%), alkaline ionic liquid (AlCl3/EMIC: 44/56 mol%) and acidic ionic liquids (AlCl3/EMIC: 60/40 mol%). the surface morphologies were analyzed by using impedance, potentiodynamic polarization scan, potential electrochemical techniques and scanning electron microscopy.
    Metal corrosion behavior in the ionic liquid is quite different from the traditional liquid. In the neutral ionic liquid, 304 stainless steel, 316 stainless steel and nickel-metal have good ability to resist corrosion and carbon steel has an "active passive transfer" corrosion behavior while the copper and titanium are the less metallic materials. In the alkaline ionic liquid, titanium has a passivation region approximately 0.6V while the corrosion resistances of remaining metals are poor. In the acidic ionic liquid, all of the metals in this study have poor corrosion resistances. To find other good anti-corrosion metals or other approaches to deal with the metal corrosion problem in ionic liquid have become the main topic in this field.

    中文摘要...................................................I Abstract.................................................II 誌謝.....................................................III 目錄.....................................................V 表目錄...................................................VII 圖目錄..................................................VIII 一、 緒論..............................................1 二、 背景資料與文獻回顧..................................2 2-1 離子液體的介紹與應用....................................2 2-1-1 離子液體的介紹.......................................2 2-1-2 離子液體的應用.......................................7 2-1-3 鹵素鋁鹽離子液體....................................11 2-2 金屬材料與離子液體....................................17 三、 研究動機..........................................19 四、 實驗相關資料......................................20 4-1 實驗步驟與方法........................................20 4-1-1 試片製作與準備......................................20 4-1-2 離子液體配置........................................22 4-1-3 電化學實驗..........................................22 4-1-4 試片分析...........................................24 4-2 實驗裝置設備..........................................26 4-2-1 參考電極(reference electrode)......................26 4-2-2 輔助電極(counter electrode)........................26 4-2-3 工作電極(working electrode)........................27 4-2-4 手套箱(Glove Box)..................................27 4-2-5 電化學恆電位儀(Autolab potentiostat)................28 4-2-6 掃描式電子顯微鏡(Scanning Electron Microscopy)......28 4-3 藥品.................................................30 五、 結果與討論........................................33 5-1 三種比例的離子液體電化學性質...........................33 5-2 金屬行為探討.........................................35 5-2-1 中性離子液體與3.5wt%氯化鈉水溶液的差異...............35 5-2-2 酸性離子液體.......................................66 5-2-3 鹼性離子液體中.....................................77 5-2-4 不同材料於三種環境之腐蝕特性.........................92 六、 結論.............................................95 七、 參考文獻.........................................97

    (1)Chang, J.-K.; Sun, I.-W.; Pan, S.-J.; Chuang, M.-H.; Deng, M.-J.; Tsai, W.-T. Transactions of the Institute of Metal Finishing 2008, 8, 227.
    (2)Chang, J.-K.; Chen, S.-Y.; Tsai, W.-T.; Deng, M.-J.; Sun, I.-W. Electrochemistry Communications 2007, 9, 1602.
    (3)Chang, J.-K.; Chen, S.-Y.; Tsai, W.-T.; Deng, M.-J.; Sun, I.-W. Journal of The Electrochemical Society 2008, 155, C112.
    (4)Ashassi-Sorkhabi, H.; Es'haghi, M. Materials Chemistry and Physics 2009, 114, 267.
    (5)Forsyth, M.; Neil, W. C.; Howlett, P. C.; Macfarlane, D. R.; Hinton, B. R. W.; Rocher, N.; Kemp, T. F.; Smith, M. E. Applied Materials & Interfaces 2009, 1, 1045.
    (6)Efthimiadis, J.; Neil, W. C.; Bunter, A.; Howlett, P. C.; Hinton, B. R. W.; MacFarlane, D. R.; Forsyth, M. Applied Materials & Interfaces 2010, 2, 1317.
    (7)Howletta, P. C.; Khooa, T.; Mooketsia, G.; Efthimiadisa, J.; MacFarlane, D. R.; Forsyth, M. Electrochimica Acta 2010, 55, 2377.
    (8)Uerdingen, M.; Treber, C.; Balser, M.; Schmitt, G.; Werner, C. Green Chemistry 2005, 7, 321.
    (9)Perissi, I.; Bardi, U.; Caporali, S.; Fossati, A.; Lavacchi, A. Corrosion Science 2006, 48, 2349.
    (10)Shkurankov, A.; Abedin, S. Z. E.; Endres, F. Australian Journal of Chemistry 2007, 60, 35.
    (11)Arenas, M. F.; Reddy, R. G. Journal of Mining and Metallurgy 2003, 39(1-2)B, 81.
    (12)Perissi, I.; Bardi, U.; Caporali, S.; Fossati, A.; Lavacchi, A. Solar Energy Materials & Solar Cells 2008, 92, 510.
    (13)Tseng, C. H.; Chang, J. K.; Chen, J. R.; Tsai, W. T.; Deng, M. J.; Sun, I. W. Electrochemistry Communications 2010, 12, 1091.
    (14)Schafir, J. M.; Plambeck, J. A. Canadian Journal of Chemistry 1970, 48, 2131.
    (15)Sun, I. W.; Edwards, A. G.; Mamantov, G. Jouranl of the Electrochemical Society 1993, 140, 2733.
    (16)Stafford, G. R. Jouranl of the Electrochemical Society 1994, 141, 945.
    (17)Shafir, J. M.; Plambeck, J. A. Canadian Journal of Chemistry 1970, 48, 2131-&.
    (18)Plechkova, N. V.; Seddon, K. R. Chemical Society Reviews 2008, 37, 123.
    (19)Mamantov, G.; Chen, G. S.; Xiao, H.; Yang, Y.; Hondrogiannis Jouranl of the Electrochemical Society 1995, 142, 1785.
    (20)Gruen, D. M.; Mcbth, R. L. Pure and Applied Chemistry 1963, 6, 23.
    (21)Phillips, J.; Osteryoung, R. A. Jouranl of the Electrochemical Society 1977, 124, 1465.
    (22)Earle, M. J.; Seddon, K. R. Pure and Applied Chemistry 2000, 72, 1391-1398.
    (23)Chen, P. Y. Chemistry 2006, 64, 235.
    (24)Nanjundiah, C.; McDevitt, S. F.; Koch, V. R. Journal of The Electrochemical Society 1997, 144, 3392-3397.
    (25)Ue, M.; Takeda, M.; Toriumi, A.; Kominato, A.; Hagiwara, R.; Ito, Y. Journal of The Electrochemical Society 2003, 150, A499-A502.
    (26)Sakaebe, H.; Matsumoto, H. Electrochemistry Communications 2003, 5, 594.
    (27)Sato, T.; Maruo, T.; Marukane, S.; Takagi, K. Journal of Power Sources 2004, 138, 253.
    (28)Papageorgiou, N.; Athanassov, Y.; Armand, M.; Bonhote, P.; Pettersson, H.; Azam, A.; Gratzel, M. Journal of the Electrochemical Society 1996, 143, 3099.
    (29)Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Gratzel, M. Journal of Physical Chemistry B 2003, 107, 13280.
    (30)Noda, A.; Susan, A. B.; Kudo, K.; Mitsushima, S.; Hayamizu, K.; Watanabe, M. Journal of Physical Chemistry B 2003, 107, 4024.
    (31)Hsiu, S. I.; Huang, J. F.; Sun, I. W.; Yuan, C. H.; Shiea, J. Electrochimica Acta 2002, 47, 4367.
    (32)Chen, P. Y.; Sun, I. W. Electrochimica Acta 2001, 46, 1169.
    (33)Lin, M. C.; Chen, P. Y.; Sun, I. W. Journal of the Electrochemical Society 2001, 148, C653.
    (34)Huang, J. F.; Sun, I. W. Journal of the Electrochemical Society 2002, 149, E348.
    (35)Huang, J. F.; Sun, I. W. Journal of the Electrochemical Society 2004, 151, C8.
    (36)Huang, J. F.; Sun, I. W. Journal of the Electrochemical Society 2003, 150, E299.
    (37)Lin, Y. W.; Tai, C. C.; Sun, I. W. Journal of the Electrochemical Society 2007, 154, D316.
    (38)Yeh, F. H.; Tai, C. C.; Huang, J. F.; Sun, I. W. Journal of Physical Chemistry B 2006, 110, 5215.
    (39)Huang, J. F.; Sun, I. W. Advanced Functional Materials 2005, 15, 989.
    (40)Huang, J. F.; Sun, I. W. Electrochimica Acta 2004, 49, 3251.
    (41)Huang, J. F.; Sun, I. W. Chemistry of Materials 2004, 16, 1829.
    (42)Abbott, A. P.; McKenzie, K. J. Physical Chemistry Chemical Physics 2006, 8, 4265.
    (43)Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Mayton, R.; Sheff, S.; Wierzbicki, A.; Davis, J. H.; Rogers, R. D. Environmental Science & Technology 2002, 36, 2523-2529.
    (44)Holbrey, J. D.; Visser, A. E.; Spear, S. K.; Reichert, W. M.; Swatloski, R. P.; Broker, G. A.; Rogers, R. D. Green Chemistry 2003, 5, 129-135.
    (45)Luo, H. M.; Dai, S.; Bonnesen, P. V.; Buchanan, A. C.; Holbrey, J. D.; Bridges, N. J.; Rogers, R. D. Analytical Chemistry 2004, 76, 3078-3083.
    (46)Bosmann, A.; Datsevich, L.; Jess, A.; Lauter, A.; Schmitz, C.; Wasserscheid, P. Chemical Communications 2001, 2494-2495.
    (47)Buzzeo, M. C.; Klymenko, O. V.; Wadhawan, J. D.; Hardacre, C.; Seddon, K. R.; Compton, R. G. Journal of Physical Chemistry A 2003, 107, 8872-8878.
    (48)AlNashef, I. M.; Leonard, M. L.; Matthews, M. A.; Weidner, J. W. Industrial & Engineering Chemistry Research 2002, 41, 4475-4478.
    (49)Buhrman, R. A.; Granqvist, C. G. Journal of Applied Physics 1976, 47, 2220-2222.
    (50)Li, J. C.; Nan, S. H.; Jiang, Q. Surface & Coatings Technology 1998, 106, 135-139.
    (51)Endres, F.; Bukowski, M.; Hempelmann, R.; Natter, H. Angewandte Chemie-International Edition 2003, 42, 3428-3430.
    (52)Hurley, F. H.; Wire, T. P. Jouranl of the Electrochemical Society 1951, 98, 203.
    (53)Carpio, R. A.; King, L. A.; Lindstrom, R. E.; Nardi, J. C.; Hussey, C. L. Jouranl of the Electrochemical Society 1979, 126, 1644.
    (54)Gale, R. J.; Gilbert, B.; Osteryoung, R. A. Inorganic Chemistry 1978, 17, 2728-2729.
    (55)Robinson, J.; Osteryoung, R. A. Jouranl of the American Chemical Society 1979, 101, 323.
    (56)Gale, R. J.; Osteryoung, R. A. Inorganic Chemistry 1980, 19, 2240-2242.
    (57)Gray, J. L.; Maciel, G. E. Journal of the American Chemical Society 1981, 103, 7147-7151.
    (58)Wilkes, J. S.; Frye, J. S.; Reynolds, G. F. Inorganic Chemistry 1983, 22, 3870-3872.
    (59)Fannin, A. A.; Floreani, D. A.; King, L. A.; Landers, J. S.; Piersma, B. J.; Stech, D. J.; Vaughn, R. L.; Wilkes, J. S.; Williams, J. L. Journal of Physical Chemistry 1984, 88, 2614-2621.
    (60)Chen, P. Y.; Lin, Y. F.; Sun, I. W. Journal of The Electrochemical Society 1999, 146, 3290-3294.
    (61)Jeng, E. G. S.; Sun, I. W. Journal of The Electrochemical Society 1998, 145, 1196-1201.
    (62)Stafford, G. R.; Hussey, C. L.; Alkire, R. C.; Kolb, D. M. Advances in Electrochemical Science and Engineering 2001, 7, 275.
    (63)Moens, L.; Blake, D. M.; Rudnicki, D. L.; Hale, M. J. Journal of Solar Energy Engineering-Transactions of the Asme 2003, 125, 112-116.
    (64)Perissi, I.; Bardi, U.; Caporali, S.; Fossati, A.; Lavacchi, A. Solar Energy Materials and Solar Cells 2008, 92, 510-517.
    (65)Davis, J. H.; Fox, P. A. Chemical Communications 2003, 1209-1212.
    (66)Weyershausen, B.; Hell, K.; Hesse, U. Green Chemistry 2005, 7, 283-287.
    (67)Mun, J.; Yim, T.; Choi, C. Y.; Ryu, J. H.; Kim, Y. G.; Oh, S. M. Electrochemical and Solid State Letters 2010, 13, A109-A111.
    (68)Trombetta, F.; de Souza, R. F.; de Souza, M. O.; Borges, C. B.; Panno, N. F.; Martini, E. M. A. Corrosion Science 2011, 53, 51-58.
    (69)Bard, A. J.; Faulkner, L. R. In Electrochemical Methods: Fundamentals and Applications; Jon Wiley & Sons, Inc., 2000; pp 386.
    (70)J.S.Wilkes; J.A.Levisky; R.A.Wilson; C.L.Hussey Inorganic Chemistry 1982, 21, 1263.
    (71)J.R.Sanders, The University of Mississippi, 1987.
    (72)Cáceres, L.; Vargas, T.; Herrera, L. Corrosion Science 2009, 51, 971.
    (73)Xia, Z.; Chou, K. C.; Szklarskasmialowska, Z. Corrosion 1989, 45, 636-642.
    (74)Wang, J. H.; Su, C. C.; Szklarskasmialowska, Z. Corrosion 1988, 44, 732-737.
    (75)Frankel, G. S. Journal of The Electrochemical Society 1998, 145, 2186-2198.
    (76)Caprani, A.; Frayret, J. Electrochimica Acta 1979, 24, 835.
    (77)Schutz, R. W.; Thomas, D. E. ASM Handbook 1987, 13, 669.
    (78)Liu, L.; Li, Y.; Wang, F. Electrochimica Acta 2007, 52, 7193.
    (79)Trompette, J. L.; Massot, L.; Arurault, L.; Fontorbes, S. Corrosion Science 2011, 53, 1262.

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