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研究生: 鄭文菁
Cheng, Wen-Ching
論文名稱: 地震前兆地下水溶解氣現地揮發機制佐證 – 2008年Mw 5.4安通地震氡與甲烷濃度異常下降
Corroboration of in-situ volatilization :Simultaneous declines in radon and methane precursory to 2008 Mw5.4 Antung earthquake
指導教授: 郭明錦
Kuo, Ming-Ching Tom
學位類別: 博士
Doctor
系所名稱: 工學院 - 資源工程學系
Department of Resources Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 82
中文關鍵詞: 地震甲烷地下水
外文關鍵詞: Earthquake, Methane, Radon, Groundwater
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  • 地下水氡氣揮發機制首次被提出以解釋2003 MW 6.8成功地震地下水氡濃度異常下降之前兆。本研究從2007 年11 月起在安通溫泉監測井(D1)開始同時監測氡及甲烷濃度變化。2008年成功的在2008 MW 5.4安通地震捕獲地下水氡與甲烷濃度同時下降之前兆。2003 MW 6.8成功地震的地下水氡異常下降及2008 MW 5.4安通地震地下水氡及甲烷同時異常下降,皆支持地下水溶解氣揮發機制。

    2008 MW 5.4安通地震發生前,地下水氡氣和甲烷背景濃度由平均735 ± 48 pCi/L及6.1 ± 0.5 mg/L分別下降到了最低濃度的480 pCi/L及1.9 mg/L。根據以上地下水氡氣及甲烷濃度異常下降數據,由地下水溶解氣體揮發機制之數學模式推算2008 MW 5.4安通地震發生前安通溫泉含水層最大氣體飽和度分別為6.72 %及5.88 %。根據氡及甲烷濃度異常下降現象,分別計算之氣體飽和度值接近,顯示地下水溶解氣揮發機制,可以合理解釋安通溫泉地震前兆地下水氡及甲烷濃度之異常下降。

    Radon volatilization mechanism into the gas phase was hypothesized to explain the anomalous decline in groundwater radon precursory to the 2003 MW 6.8 Chengkung earthquake in Taiwan. We initiated the monitoring of both radon and methane in the groundwater since November 2007 at well D1 in the Antung hot spring. The mechanism of in-situ radon volatilization has been corroborated by the simultaneous anomalous declines in groundwater-dissolved radon and methane precursory to the 2008 Mw 5.4 Antung earthquake.

    Specifically, radon and methane decreased from background levels of 735 ± 48 pCi/L and 6.1 ± 0.5 mg/L to minima of 480 pCi/L and 1.9 mg/L prior to the 2008 Mw 5.4 Antung earthquake, respectively. The maximum gas saturation developed in newly created cracks preceding the 2008 Mw 5.4 Antung earthquake was estimated at 6.72 % and 5.88 % based on the anomalous declines of groundwater-dissolved radon and methane, respectively. The close agreement of gas saturation values estimated independently from the decline data of radon and methane supports the validity of the mathematical model of in-situ volatilization.

    中文摘要 I 英文摘要 II 誌謝 III 目錄 IV 圖目錄 VI 表目錄 VII 第一章 緒論 1 1-1 研究動機及目的 1 1-2 研究方法 4 第二章 文獻回顧 5 2-1 研究區域概況 5 2-1-1 地質背景 5 2-1-2 海岸山脈及池上斷層 9 2-2 區域地質地震背景 11 2-3 地下水體化學成分的監測 14 2-3-1 地層中流體化學 14 2-3-2 流體化學應用 16 2-3-3 成功地震氡相行為試驗 17 2-3-4 地下水不溶解氣體監測 22 第三章 實驗材料與分析方法 24 3-1 供試水樣及氣樣處理 24 3-2 水氡分析 25 3-3 甲烷與氮氣的分析 26 3-3-1 氣相層析儀(GC-FID)分析方法與設備 27 3-3-2 氣相層析儀(GC-TCD)分析方法與設備 29 3-3-3 檢量線之製作 31 3-4 品保與品管(QA/QC) 32 3-4-1 檢量線 32 3-4-2 檢量線斜率品保管理 33 3-4-3 檢量線空白分析 36 3-4-4 檢量線重複分析 36 3-4-5 樣品分析 36 第四章 2008年MW 5.4地震前甲烷濃度異常變化 37 4-1 實驗材料與方法 37 4-1-1 監測井現況 37 4-1-2 氡的量測 40 4-1-3 甲烷的量測 41 4-1-4 氮氣的量測 43 4-2 量測結果 45 4-2-1 水氡量測結果 47 4-2-2 甲烷量測結果 49 4-3 氣體飽和度行為數學模式 51 4-4 小結 53 第五章 溶解氣體監測 54 5-1 地下水中的溶解氣體 55 5-1-1 甲烷氣體來源 55 5-1-2 氮氣體來源 56 5-2 長期監測 57 5-2-1 甲烷監測結果 58 5-2-2 氮監測結果 60 5-2-3 甲烷及氮氣比較 62 5-3 水中溶解氣體積 64 5-3-1 氣體體積與甲烷 66 5-3-2 氣體體積與氮氣 68 第六章 結論與建議 70 6-1 結論 70 6-2 建議 72 參考文獻: 74

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