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研究生: 張嘉真
Chang, Chia Chen
論文名稱: 選擇性發酵技術用於蔗糖酒精共生系統之產率模擬
Productivity simulation of combined sugar and ethanol production with selective fermentation technology
指導教授: 福島康裕
Yasuhiro Fukushima
學位類別: 碩士
Master
系所名稱: 工學院 - 環境工程學系
Department of Environmental Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 英文
論文頁數: 87
中文關鍵詞: 選擇性發酵技術產率蔗糖酒精最佳化情境模擬
外文關鍵詞: selective fermentation technology, productivity enhancement, sugar, ethanol, optimization, scenario development
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  • 現今許多國家致力於發展生質酒精以降低對原油的需求。然而,生質酒精的生產卻造成能源與糧食競爭的現象加劇。為了解決競爭的問題,選擇性發酵技術首創以高純度以及低純度的糖漿為原料,從中析出蔗糖以提高蔗糖的產量;選擇性發酵技術的原理為:在蔗糖結晶程序之前,選擇性地發酵存在在糖漿中的還原糖,如此可減少糖漿的黏滯性,先分離發酵液與糖漿以提高糖漿的純度,增加原糖的萃取效率。因此,當高還原糖比率及高產量特性的品種為甘蔗工場之原料並與選擇性發酵技術並用時,糖與酒精生產率之穩定與提升的可能性則提高。
    為了推廣選擇性發酵技術用於甘蔗工場全系統,本研究模擬選擇性發酵技術導入的情況下,加上改變甘蔗品種與收穫時間,探討上述變數對於糖與酒精產率之影響。在此研究中開發一個原型模型,此原型的目的是強調選擇性發酵技術的導入,藉由最佳化技術以及設定情境模擬,以分析改變甘蔗品種與收穫時間對於糖與酒精產量之影響。此示範性情境模擬之結果顯示,選擇性發酵法技術與高產量、高生物質及高還原糖含量的品種相組合具有潛在優勢。
    除此之外,本研究也指出幾項關於甘蔗種植面的新的數據需求,譬如說更廣泛的生長曲線(蔗莖重量、組成分)、宿根兩年至四年的觀測以及依照月份分配之受颱風影響物理損傷的比率。 本研究亦有納入未來研究方向包括模型和數據庫強化之討論。

    Selective fermentation realized by invertase-defective yeasts that convert only the reducing sugars in a mixed saccharide (e.g. sugarcane juice) into ethanol is an emerging process technology in sugarcane industry. This technology opens possibilities in stabilization and enhancement of total productivity of sugar and ethanol, as productive and stronger cultivars that have higher content of reducing sugar becomes a potential raw material in sugar mills. To trigger the system-wide innovation of this technology, the changes in stability and enhancement of productivity must be described by changes in cultivars and cropping schedules. Here, a descriptive model developed in this study highlights consequences of introduction of selective fermentation technology considering a given scenario on choice of cultivars and cropping schedules. Moreover, utilizing a prototype database, design of scenarios based on optimization techniques are demonstrated. The results from demonstrative scenario design indicate the potential advantages of selective fermentation technology in combination with a cane cultivar with high yield, high biomass and reducing sugar content on Tanegashima Island of Japan. The study also indicates the new requirement on data from sugarcane cultivation, such as a wider range of growth profiles (stalk weight, composition), growth and harvest observations of perennial ratoon and rate of physical damage by typhoon by varied rationing months. Future directions of study including directions in enhancement of the model and database are discussed.

    Table of Contents Abstract I 摘要 II 致謝 III Table of Contents V Figure Index VII Table Index X Chapter 1 Introduction 1 1.1 Preface 1 1.2 Motivation 3 1.3 Objective 4 Chapter 2 Literature Review 5 2.1 Definition of sugarcane 5 2.2 Cultivar information 5 2.3 Conventional processes in cane mill 8 2.4 Selective fermentation application in cane mill process 9 2.5 Sugarcane related model 12 Chapter 3 Methodology 13 3.1 Development of model 13 3.1.1 Process inventories 14 3.1.2 Requirements and instructions 18 3.1.3 Limitations 21 3.1.4 Mathematical expression 23 3.2 Scenario analysis 40 3.2.1 Scenario design 40 3.2.2 Mathematical expression 45 3.3 Optimization for cane mill 46 3.3.1 Objectives 46 3.3.2 Mathematical expression 47 3.4 Sensitivity analysis 50 Chapter 4 Results and Discussion 51 4.1 Scope of model application 51 4.2 Scenario analysis 52 4.2.1 Referenced condition-harvest NiF8 in five months with conventional fermentation 52 4.2.2 Extended condition-harvest NiF8 in seven months with selective fermentation 58 4.2.3 Extended condition-harvest KY01-2044 in seven months with selective fermentation 63 4.2.4 Comparison between scenarios 69 4.3 Optimization for production 73 4.3.1 Description of productivity 73 4.3.2 Recommendation for managers and farmers 77 4.4 Sensitivity analysis 80 Chapter 5 Conclusion 83 Reference 85 Figure Index Figure 2 1 Growth condition of NiF8 and KY01-2044 in new spring planting (left) and in ratoon (right) [7] 6 Figure 2 2 Sugarcane cropping system in Taiwan. [9, 11] 7 Figure 2 3 Conventional processes in cane mill including sugar and ethanol production. The figure was organized in this study according to the literatures. [12-14] 10 Figure 2 4 Schematic for selective fermentation application in cane mill, especially 11 Figure 3 1 Process inventories of the proposed model and goal of the proposed model 17 Figure 3 2 Stalk weight simulation of NiF8 in new spring planting and ratoon 28 Figure 3 3 Stalk weight simulation of KY01-2044 in new spring planting and ratoon 28 Figure 3 4 Brix and purity of NiF8 in new spring planting along with days after planting 30 Figure 3 5 Brix (left) and purity (right) of NiF8 in ratoon planting along with days after planting. Different starting month of ratoon is described in R_month. 30 Figure 3 6 Brix and purity of KY01-2044 in new spring planting along with days after planting 31 Figure 3 7 Brix (left) and purity (right) of KY01-2044 in ratoon planting along with days after planting. Different starting month of ratoon is described in R_month. 31 Figure 3 8 Flowchart of crystallization and centrifugation 34 Figure 3 9 Raw sugar yield of crystallization with conventional fermentation (CF) 34 Figure 3 10 Raw sugar yield of crystallization with conventional fermentation (CF) + selective fermentation (SF) 35 Figure 3 11 Scheme of overall scenario design 44 Figure 4 1 Scenario A1, sugar production in new spring planting (left) and in ratoon1 (right) 54 Figure 4 2 Scenario A1, ethanol production in new spring planting (left) and in ratoon1 (right) 54 Figure 4 3 Scenario A2, ethanol production in new spring planting (left) and in ratoon1 (right) 56 Figure 4 4 Scenario B1, sugar production in new spring planting (left) and in ratoon1 (right) 59 Figure 4 5 Scenario B1, ethanol production in new spring planting (left) and in ratoon1 (right) 59 Figure 4 6 Scenario B2, ethanol production in new spring planting (left) and in ratoon1 (right) 61 Figure 4 7 Scenario C1, sugar production in new spring planting (left) and in ratoon1 (right) 64 Figure 4 8 Scenario C1, ethanol production in new spring planting (left) and in ratoon1 (right) 64 Figure 4 9 Scenario C2, ethanol production in new spring planting (left) and in ratoon1 (right) 67 Figure 4 10 Sugar production in two year cycle for A1, B1 and C1 scenario 70 Figure 4 11 Ethanol production in two year cycle for A1, B1 and C1 scenario 71 Figure 4 12 Ethanol production in two year cycle for A2, B2, and C2 scenario 72 Figure 4 13 Sugar production distribution 75 Figure 4 14 Ethanol production distribution 76 Figure 4 15 Bagasse production distribution 76 Figure 4 16 Result of sensitivity analysis for sugar production with conventional fermentation 81 Figure 4 17 Result of sensitivity analysis for ethanol production with conventional fermentation 81 Figure 4 18 Result of sensitivity analysis for sugar production with conventional and selective fermentation. 82 Figure 4 19 Result of sensitivity analysis for ethanol production with conventional and selective fermentation. 82 Table Index Table 3 1 Days after planting for new spring planting and ratoon1 20 Table 3 2 Measured stalk population data 25 Table 3 3 Cultivar data and growth assumptions for simulating sugarcane stalk population 25 Table 3 4 Assumptions in sugar and ethanol production simulation 38 Table 3 5 Allocation of harvested area for scenario A 42 Table 3 6 Allocation of harvested area for scenario B and C 42 Table 3 7 Overview of scenario design 43 Table 4 1 Scenario A1, data of sugar production for figure 4-1. 55 Table 4 2 Scenario A1, data of ethanol production for figure 4-2. 55 Table 4 3 Scenario A2, data of ethanol production for figure 4-3. 57 Table 4 4 Scenario B1, data of sugar production for figure 4-4 60 Table 4 5 Scenario B1, data of ethanol production for figure 4-5. 60 Table 4 6 Scenario B2, data of ethanol production for figure 4-6. 62 Table 4 7 Scenario C1, data of sugar production in figure 4-7. 65 Table 4 8 scenario C1, data of ethanol production in figure 4-8 66 Table 4 9 scenario C2, data of ethanol production for figure 4-9. 68 Table 4 10 Sugar production in sugar maximized case 70 Table 4 11 Ethanol production in sugar maximized case 71 Table 4 12 Ethanol production in ethanol maximized case 72 Table 4 13 Sugarcane production allocated in harvest schedule 74 Table 4 14 Total sugar, ethanol and bagasse production in two year cycle 75 Table 4 15 Harvest area along with harvest schedule for optimized sugar production 79

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