於2050 年，全球各國都在努力實現淨零排放目標，以應對氣候變化。對於紙和紙板包裝材料方面，在台灣目前並未准許使用再生紙用於食品接觸材料。再生紙的來源可以由消費者使用的紙張、造紙廠的廢紙、紙屑和可能含有原生纖維的廢紙之混合物製成，在加工製造過程中，業者會使用到加工助劑，這些有意添加物質(Intentionally Add Substances，IAS)包括增塑劑、抗氧化劑、熱穩定劑和非有意添加物(Non-Intentionally Add Substances，NIAS)，如螢光增白劑、全氟烷基化合物和印刷油墨等，可能會隨著接觸時間和溫度的不同遷移到食品中，使消費者逐漸累積這些化合物於體內進而造成健康上的疑慮。本研究擬建立再生紙接觸材料的遷移試驗(Migration Test)，目的是了解再生紙中 IAS和 NIAS於食品模擬物和真實食品的遷移情況，並估算其所造成之健康風險。在紙類樣本的採集，分別自臺灣與中國方的紙器廠商中收集五種回收紙類樣本（包含回收紙漿製成之披薩盒）以進行遷移試驗。在遷移試驗開始前會將紙類樣本裁切成 3×3 cm大小，並依據「食品器具容器包裝衛生標準」規定中的四種食品模擬液水、4%醋酸、正庚烷和 20%乙醇進行遷移試驗，此外，採用真實食物地瓜、炸雞和披薩等食物進行遷移實驗，於遷移試驗結束後，分析食品模擬液和真實食品之七種金屬與五種鄰苯二甲酸酯類濃度，金屬濃度使用感應耦合電漿質譜儀(Inductively Coupled Plasma Mass Spectrometry, ICP-MS)與鄰苯二甲酸酯類使用氣相層析質譜儀(Gas Chromatography-Mass Spectrometry, GC-MS)進行定量分析。於七種金屬的遷移試驗與定量分析後，在五種的回收紙類樣本於食品模擬液水、4%醋酸之遷移結果皆符合法規基準值，在地瓜、炸雞與披薩的分析結果，金屬遷移含量普遍較低，但個別樣本中仍檢測到高濃度的銅(Copper, Cu)和鋅(Zinc,Zn)。在定量分析鄰苯二甲酸酯類於食品模擬液之遷移結果，遷移率範圍介於0.026%至 1.30%，由於遷移試驗屬於動態平衡，所以包材接觸食品模擬液或真實食品皆會有雙向遷移之影響。另為了解回收紙漿製程之回收紙與一般原生紙漿製程的紙張在表面纖維上有無差異，利用分析型場發掃描式電子顯微鏡(Analytical field emission scanning electron microscope, FE-SEM)，在不同的倍率下掃描紙類樣本觀察出回收紙張纖維呈破損與斷裂較原生紙漿明顯。以食品模擬液與真實食物之分析結果進行健康風險評估，依據一般國人攝食量推估暴露劑量皆低於產生不良健康效應閾值（致癌風險小於 10-6，非致癌風險小於 1），表示於設定之情境下使用紙類回收材作為食品接觸材不會造成不良健康影響。

Recycled paper are derived from variety of papers, including paper containing virgin fibers, and may contain substances such as fluorescent agents and phthalates, which can migrate over time and temperature and cause health problems. The study conducted migration tests using standard food simulants and real foods commonly packaged with paper in Taiwan. Metal and phthalate concentrations were analyzed using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Gas Chromatography-Mass Spectrometry (GC-MS) respectively, with surface differences between recycled and virgin paper observed via an analytical field emission scanning electron microscope (FE-SEM). The results showed that the metal migration concentrations in the simulated food (water and 4% acetic acid) were within the requirements, while the metal migration concentrations in the real food were generally low. Phthalates migration ranged from 0.026% to 1.30%, influenced by dynamic equilibrium during testing. For assessing the health risks associated with the consumption of food simulants and real foods, the estimated exposure doses based on typical dietary intake were all below the threshold for adverse health effects.

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