共軛高分子近來在光電產業的應用相當的廣泛，本論文中以聚苯胺衍生物在電致變色元件與發光元件中作應用。利用聚(2,5-二甲氧基苯胺)來製作電致電色元件，比起聚苯胺有較低的操作電位與較快速的應答時間。在有機發光元件領域中，最重要的挑戰在於：如何使載子注入達到平衡，進而提升亮度以及電流的效率值，在OLED中常用來做電洞傳輸層的材料為TPD，本實驗室利用結構類似TPD的導電高分子，磺酸化聚二苯胺(SPDPA)，用來作有機發光元件的電洞注入層。
(1)聚(2,5-二甲氧基苯胺)的電致變色行為
　　PDMA利用摻雜不同結構酸作電化學合成，分別使用硫酸、甲基磺酸、聚苯乙烯磺酸的水溶液中，利用循環伏安法在-0.2V~0.8V的電位區間，掃描速率20mV/s 的條件下聚合而成。再利用電化學與光譜電化學的方式進行評估，是否在不同結構的酸摻雜對電致變色的行為會有所改善，並配合掃描式電子顯微鏡觀察高分子膜表面的結構。在PDMA-PSS的高分子複合膜中，將有高對比、較穩定的電致變色特性。

　　PDMA-PSS與WO3以及高分子電解質(B-PEI-H3PO4)進行電致變色元件的製作與特性探討。本元件特性相較之前的研究，大幅的改善了元件穩定性與高度的光學對比，連續操作10000次的穩定度測試，還保有50%左右的光學對比值。
(2)磺酸化聚二苯胺作電洞注入層的特性
　　利用SPDPA當作電洞注入層，並選擇不同能障(band gap)的發光層的有機發光元件，來探討SPDPA對於元件特性的影響。除此之外，我們還製作單純傳遞電洞的元件，探討SPDPA對於電洞傳遞的影響，並作電激發光光譜與原子力顯微鏡，嘗試探討其對元件行為的影響。

　Recently, conjugated polymers have been used extensively in electro -optical industry. The main objective of the present is to study polyaniline derivatives in electrochromic and light-emitting device. In further study, it presented that poly(2,5-dimethoxy aniline) (PDMA) exhibits lower operating voltage from reduced state to oxidized state than PANI. And PDMA also showed a response time (9 s), which is smaller than that of PANI (22 s). In the study of PLED, one of the most important challenges is overcoming balance charge and recombination in order to enhance the life time and luminous efficiency. TPD (N, N’-diphenyl- N, N’-bis(3-methylphenyl)-[1,1’-biphenyl] -4,4’-diamine) owing arlyamine structure is a suitable candidate for hole transport layer in OLED. We use sulfonated poly(diphenylamine) (SPDPA) with similar TPD structure as an extra hole injection material ultilized in PLED device.
(1) Electrochromic properties of PDMA
　We synthesized conducting polymer by electrochemical way in different structural acid as electrolyte: Sulphuric acid, methane sulfonic acid, and polystyrene sulfuric acid. Electrochemical polymerization of (2, 5-dimethoxy -aniline) was performed via cyclic voltammetry method at a scan rate of 20 mV/s. We proceeded to estimate the electrochromic characteristics of PDMA deposited on ITO with different dopants by spetroelectrochemical methods. Then, we selected a suitable dopant in the process of polymerization for modifying electrochromic behaviors of PDMA.
　PDMA-PSS composite shows higher optical contrast and better stability behaviors. For fabricating the electrochromic device, PDMA-PSS was deposited on indium tin oxide (ITO) coated glass and used as an electrode. Film of tungsten oxide (WO3) on ITO glass was used as the other electrode with H3PO4 doped branched poly(ethyleneimine ) as polymer electrolyte. The optical contrast of the device was improved by incorporating PSS into PDMA matrix. The device retained nearly 50 % of their optical contrast after 10,000 double steps informing the superior performance of PDMA/PSS in the EC device.
(2) Sulfonated poly(diphenylamine) as hole injecting material
　The PLED was fabricated using SPDPA as a hole-injection layer for studying the performance and simultaneously comparing with PLED using PEDOT-PSS as hole-injection layer. And then, we fabricate hole-only device and measured EL spectral, AFM image to identify its mechanism.

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