金屬有機骨架（Metal−organic frameworks, MOFs），由規律排列的金屬節點與有機連接器組合而成，是一種具有高度孔洞性及高比表面積的奈米孔洞材料，除此之外其結構具有高可調控性，且可透過官能基修飾改變其性質。得益於上述特性，MOF的發展備受關注，並應用於許多領域。本文內容將會討論MOF於光領域的應用，首先使用以六鋯金屬團簇為節點的鋯基金屬有機骨架（Zirconium-based MOF, Zr-MOF），並選擇具有二維結構的MOF，ZrBTB（BTB = 1,3,5-tri(4-carboxyphenyl)benzene），其水穩定性、良好分散性及二維結構使其特別適合在水溶液中進行光感測。ZrBTB在此做為固定化的平台，將具備獨特發光性質的鑭系金屬，鋱（Tb），與其光敏化劑兩階段地後修飾在ZrBTB上。以鑭系金屬做為發光中心，光敏化劑能夠幫助鑭系金屬吸光並傳遞能量至鑭系金屬，提升鑭系金屬的放光，此做法有望取代以Tb作為節點的Tb-MOF，並突破Zr-MOF的建構單元限制，其發光效率及吸光波長等可以不像以往被MOF的有機連接器限制，而可以挑選適合鋱金屬的有機配體做為光敏化劑，提升兩者間的能量傳遞效率或是使用對人體較友善的波長激發。最終，本文所合成的材料可以進行水中鐵離子（Fe3+）的光感測，並具有良好的選擇性及靈敏度。

In this thesis, the structural and functional tunability of metal−organic frameworks (MOFs) is demonstrated and their applications in photoluminescent sensors would be explored.
A two-dimensional (2D) zirconium-based metal–organic framework (Zr-MOF) with abundant terminal -OH/-OH2 groups on its nodes, ZrBTB (BTB = 1,3,5-tri(4-carboxyphenyl)benzene), is utilized as a platform for dual post-synthetic modifications (PSM) to immobilize both the benzophenone-based photosensitizer (benzophenone‐4,4’‐dicarboxylate, bzpdc) and terbium ions onto the 2D Zr-MOF molecular sheets. The loading of terbium ions on the Zr-MOF can be adjusted while preserving the loading of the photosensitizer. Since the installed bzpdc ligand can induce a highly efficient energy transfer to the neighbouring terbium ion upon excitation, the obtained material after dual PSM (ZrBTB-bzpdc-Tb-120) can show strong photoluminescent (PL) emissions of terbium ions upon the excitation of the bzpdc ligand at 355 nm, with a PL quantum yield of 5.04%. It is more advantageous than the 2D Zr-MOF solely functionalized with terbium ions, which can only exhibit similar emissions upon the excitation of the BTB linker at a less friendly wavelength of 310 nm, with a lower PL quantum yield of 2.94%. Owing to the high chemical stability as well as good dispersity of the ZrBTB-bzpdc-Tb-120 in water, its performances in selective PL sensing Fe(III) ions present in aqueous solutions are investigated.

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