為了了解Y市PCDD/Fs污染源對周遭環境之影響，本研究選定Y市主要PCDD/Fs污染源，包括二座事業廢棄物焚化爐(IWI)、一座醫療廢棄物焚化爐(MWI)、五座碳鋼電弧爐(EAF)、四座燒結爐(SINTER)、一座鋁二級冶煉廠(ALS)、鋅二級冶煉廠(ZN)、水泥窯(CEM)及火葬場(CRE)，執行30根次之煙道採樣分析，並於Y市周界選定五個採樣點進行環境中大氣、植物及土壤之採樣分析。藉由對各類污染源分布及排放特性之研究與周界環境中PCDD/Fs流佈相比對，可釐清當地PCDD/Fs污染源對周遭環境之影響。研究之成果除可提供政府做為PCDD/Fs相關政策及法令參考外，亦提供Y市PCDD/Fs風險評估所需資訊。
Y市事業廢棄物焚化爐(IWI)、醫療廢棄物焚化爐(MWI)、電弧爐(EAF)、燒結爐(SINTER)、二次鋁精煉廠(ALS)、二次鋅精煉廠(ZN)、水泥窯(CEM)及火葬場(CRE)煙道廢氣中總PCDD/Fs I-TEQ濃度平均值分別為0.0299、0.202、0.238、0.311、0.0868、0.0118、0.0207及0.251 ng I-TEQ/Nm3，其中EAF2超過法規排放標準0.5 ng I-TEQ/Nm3。計畫推估所得之97年Y市固定污染源戴奧辛毒性年排放總量為13.4 g I-TEQ/yr，各類污染源佔總貢獻量分別為大型都市垃圾焚化爐(0.86 %)、中小型廢棄物焚化爐(0.0026 %)、醫療廢棄物焚化爐(0.017 %)、事業廢棄物焚化爐(0.077 %)、煉焦爐(0.35 %)、燒結爐(37.0 %)、電弧爐(60.8 %)、鋁二級冶煉廠(0.62 %)、鋅二級冶煉廠(0.019%)、銅二級冶煉廠(0.090 %)、水泥窯(0.048 %)及火葬場(0.28%)，若將Y市污染源分類為廢棄物焚化爐、金屬冶煉業及其他類別，其各佔PCDD/Fs總排放量的0.95%、98.9%及1.8%。故金屬冶煉業為Y市最大之PCDD/Fs排放源。Y市工業區周界大氣總I-TEQ濃度介於0.0436~ 0.123 pg I-TEQ/Nm3之間，總I-TEQ濃度平均值為0.0873 pg I-TEQ/Nm3。Y市工業區周界植物總I-TEQ濃度介於3.80 ~ 9.34 ng I-TEQ/kg之間，總I-TEQ濃度平均值為5.98 ng I-TEQ/kg。Y市工業區周界土壤總I-TEQ濃度介於1.29~ 3.10 ng I-TEQ/kg之間，總I-TEQ濃度平均值分別為2.29 ng I-TEQ/kg。由Y市工業區周界環境介質之等位濃度軌跡圖，可知位於電弧爐及燒結爐等固定污染源下風處環境介質PCDD/Fs濃度較高，故推測Y市工業區環境介質中PCDD/Fs濃度受到電弧爐及燒結爐等固定污染源之影響。

This study examined the characteristics of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in emissions, ambient air‚ leaves and soil at the Y city. The following PCDD/Fs emmision sources were investigated: two small-scale industrial waste incinerator (IWIs); one medical waste incinerator (MWI); four sinter planes (SINTERs); five electric furnaces (EAFs); one secondary aluminum smelter (ALS); one secondary zinc smelter (ZN); one cement kiln (CEM); and, one crematorium (CRE). The emission factors of PCDD/Fs in the stack flue gases were determined‚ and the overall emission quantity of PCDD/Fs from the Y city was estimated. Finally, the influence of these emission sources on the surrounding environment was assessed. The mean PCDD/F concentrations in the stack flue gases were as follows: IWIs, 0.0299ng I-TEQ/Nm3; MWI, 0.202ng I-TEQ/Nm3; EAFs, 0.238ng I-TEQ/Nm3; SINTERs, 0.311ng I-TEQ/Nm3; CEM, 0.0207ng I-TEQ/Nm3; ALSs, 0.0868ng I-TEQ/Nm3; CRE 0.251ng I-TEQ/Nm3; and, ZN 0.0118ng I-TEQ/Nm3. The estimated total annual emission of PCDD/Fs from these emission sources in the industrial zone was 13.4 g I-TEQ/yr (large-scale MSWIs, 0.86%; small-scale MSWIs, 0.0026%; industrial waste incinerators, 0.077%; medical waste incinerators, 0.017%; electric furnaces, 60.8%; sinter planes, 37.0%; coke oven planes, 0.35%; cement kilns, 0.048%; secondary aluminum smelters, 0.62%; secondary zinc smelters, 0.019%; secondary copper smelters, 0.090%; Crematorium,0.28%). The PCDD/F emissions from metallurgical processes were dominant, and comprised 98.9% of the total PCDD/F annual emissions.

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