現階段國內對於含重金屬污泥之中間處理技術選擇基於經濟性與操作方便性，以固化/穩定化為主。而污泥中存在許多金屬、鹽類與有機物，可能於固化處理過程中對水泥水化產生干擾。
　　本研究透過高溫熱處理、添加Ca(OH)2及添加不同濃度的H2O2三種不同調質程序對含銅污泥進行調質，並設計不同水泥/污泥配比製作水泥固化體。探討污泥調質對後續固化程序之影響，檢討含銅重金屬污泥合適之污泥固化前處理程序與水泥添加配比。
　　研究結果發現，污泥中有機物的破壞去除，有助於提昇後續固化處理成效，而且原污泥與三種調質污泥固化體之抗壓強度均隨水泥添加量增加而增加。3天齡期之抗壓強度依序為：經高溫熱處理污泥固化體＞添加6000 mg/L H2O2污泥固化體＞添加3000 mg/L H2O2污泥固化體＞原污泥固化體＞添加Ca(OH)2污泥固化體。此外，由固化體重金屬溶出試驗發現，固化體抗壓強度越低者，其水泥固化體之TCLP銅離子溶出量較高，顯示透過污泥調質程序，確實能去除部份干擾水泥水化因子，增益固化效能。

　　In the present stage, the choice for intermediate treatment technique of the sludge containing heavy metals is always according to the economic and operating convenience. Solidification/stabilization processes are the major technologies to handle these disposed sludges. However, the existence of metals, salts and organic matters in the sludge may lead to the disturbance of hydration of cement during solidification process.
　　The main purpose of this work was to study the effect of high temperature treatments, the addition of Ca(OH)2 and various concentrations of H2O2 on conditioning copper-containing sludges. In addition, the different cement/sludge ratios were designed to manufacture cement matrix. The influence of follow-up solidification process by conditioning sludges, the appropriate procedures before solidification and amounts of cements added in the sludges were also investigated.
　　The results indicated that the efficiency of solidification processes may be increased by the breakage of organic matters. The compressive strength of the raw sludge and three kinds of treated sludge matrix can be enhanced by increased quality of cement. The compressive resistance of the age period of three days is increased by the following order: high temperature treatment of sludge matrix> addition of the 6000 mgs/L H2O2 in sludge matrix > addition of the 3000 mgs/L H2O2 in sludge matrix > the raw sludge matrix > addition of Ca(OH)2 in sludge matrix. In the TCLP test experiments, it was found that the TCLP concentration of copper ion dissolved greatly while the compressive strength of matrix in decreased, which suggesting the interference of hydration of cement factors really can be removed and thus enhance the solidification effect by conditioning sludges.

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