| 研究生: |
張家瑜 Chang, Chia-Yu |
|---|---|
| 論文名稱: |
運用硝酸鉀熱分解葡萄糖製備可應用於超級電容之高純度活性碳 Utilizing the thermal degradation of potassium nitrate to prepare high-quality activated carbon from glucose for supercapacitors |
| 指導教授: |
吳志勇
Wu, Chih-Yung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 航空太空工程學系 Department of Aeronautics & Astronautics |
| 論文出版年: | 2023 |
| 畢業學年度: | 111 |
| 語文別: | 中文 |
| 論文頁數: | 65 |
| 中文關鍵詞: | 活性碳 、化學活化 、超級電容 |
| 外文關鍵詞: | Activated carbon, Chemical activation, Supercapacitor |
| 相關次數: | 點閱:132 下載:0 |
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本研究以葡萄糖為原料,並以硝酸鉀作為氧化劑以及活化劑使用,目前文獻尚未有人以硝酸鉀作為活化劑使用,本研究利用硝酸鉀熱分解進行碳化和活化過程,製備出高比表面積且高純度的活性碳,活性碳製備過程包含前處理、熱分解過程以及後處理,並且透過改變原料與氧化劑比例、後處理過程以及前處理過程來討論製備參數對於產物活性碳的影響,最終活性炭產物皆以SEM、HRTEM、XRD、UA、PA以及BET進行化學示性分析,結果顯示原料與氧化劑比例5:5組別擁有最好的比表面積2392.27m^2/g以及孔隙分布,除此之外,此製成所需配合的最佳的前處理與後處理方式分別為為加熱混和和酸洗。
將其中三組活性碳(B37、B46以及B55)製作成超級電容的對稱電極,組裝完的超級電容皆以CV、EIS以及GCD進行電化學檢測,結果也顯示以原料與氧化劑比例5:5組別製備成的超級電容擁有最高的比電容量、能量密度以及循環使用壽命,分別為153.66F/g以及9.27Wh/kg,且在10000次循環充放電後人保有將近90%的電容保留率。
This study utilizes glucose as the precursor and potassium nitrate as an activating agent. It is worth noting that there is currently no literature applying potassium nitrate as an activating agent. The thermal decomposition process of potassium nitrate is employed for the carbonization and activation method, resulting in the high- purity activated carbon with high specific surface area. The production process involves pretreatment, thermal decomposition, and post-treatment. The effects of preparation parameters on the properties of the resulting activated carbon are investigated by varying the ratios of raw material to oxidizing agent, as well as the post-treatment and pretreatment processes.
The final activated carbon samples are chemically characterized using SEM, HRTEM, XRD, UA, PA, and BET techniques. The results indicate that the 5:5 ratio of raw material to oxidizing agent group exhibits the highest specific surface area of 2392.27 m^2/g and favorable pore distribution. Additionally, the optimal pretreatment and post-treatment methods required for fabrication were heating, mixing, and acid washing respectively.
Furthermore, three types of activated carbon samples are fabricated into symmetric electrodes for supercapacitors. The assembled supercapacitors are subjected to electrochemical characterization using techniques such as CV, EIS, and GCD measurements. The results also demonstrate that the supercapacitors prepared from the 5:5 ratio of raw material to oxidizing agent group exhibit the highest specific capacitance, energy density, and cycle life. The specific capacitance exhibits 153.66 F/g, and the energy density is 9.27 Wh/kg, and nearly 90% of the capacitance is retained after 10,000 charge-discharge cycles.
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