| 研究生: |
陳冠廷 Chen, Kuan-ting |
|---|---|
| 論文名稱: |
古亭坑層泥岩合成群青之研究 A study on the synthesis of ultramarine from mudstones of Kuting-Keng formation |
| 指導教授: |
雷大同
Ray, Dah-Tong |
| 學位類別: |
博士 Doctor |
| 系所名稱: |
工學院 - 資源工程學系 Department of Resources Engineering |
| 論文出版年: | 2015 |
| 畢業學年度: | 103 |
| 語文別: | 中文 |
| 論文頁數: | 117 |
| 中文關鍵詞: | 古亭坑層 、泥岩 、鈣霞石 、田口法 、群青 |
| 外文關鍵詞: | KutingKeng formation, mudstone, cancrinite, Taguchi method, ultramarine |
| 相關次數: | 點閱:119 下載:8 |
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台灣南部台南、高雄麓山帶為上新世至早更新世地層出露地區,由一巨厚的灰色泥岩地層構成,總厚度將近五千公尺,稱為古亭坑層,呈現稱為「月世界」的惡地地形。古亭坑層的組成礦物以極細粒之石英為主,約達40 ~ 60%,及微量的長石(<5%),其它為黏土礦物,黏土礦物則以伊萊石(約45-65%)、綠泥石(約35-40%)及微量膨脹性黏土(約10%)為主。古亭坑層泥岩的土地利用方式以蔬果農業及養殖業活動等為主,以礦物資源為主題之研究不多。
本研究以古亭坑層泥岩水熱合成沸石之研究為基礎,將泥岩原樣、自泥岩分級的<2㎛樣及由泥岩合成之鈣霞石三種樣品,分別與硫、碳酸鈉及活性碳混合,在高溫煅燒,並採用田口式實驗設計法,探討起始原料、反應溫度、持溫時間、鈉/硫莫耳比及活性碳重量比對群青的產量、色相及彩度之影響。結果顯示古亭坑層泥岩、其分級樣及鈣霞石樣經由高溫合成反應,均可合成藍色群青。
In southern Taiwan, the western foothill in Tainan-Kaohsiung county is the exposed area of Pliocene (5.3 million years ago) to early Pleistocene (1.6 million years ago) strata composed of a thick grey mudstone series which is 5000 metres in depth, named as Kutingkeng Formation. The appearance of its typical badlands is specifically called “Moon World.”
The mineral compositions of Kutingkeng Formation are extremely fine quartz, which takes 40%~60% , clay minerals and a small amount of feldspar (<5%). The clay minerals consist of illite (45-65% of total clay), clinochlore (35-40 %) and a small amount of swelling clays (5-10%). Generally, the mudstone of Kutingkeng Formation does not have important economic applications.
This study was based on the research of synthetic zeolite and designed by Taguchi method. Three starting materials were used: the in-situ sample (as received), the <2 ㎛ part and the synthetic cancrinite. Each were mixed separately with sulfur, sodium carbonate and activated carbon and then calcinated at assigned temperatures.
This study investigates the influences of starting material, reaction temperature, retention time, sodium / sulfur molar ratio and the weight ratio of activated carbon on hue, chrome and brightness of the ultramarine obtained. In this results show that ultramarine blue can be synthesized by in-situ sample (as received), the <2 ㎛ part and the synthetic cancrinite after calcination.
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