金屬有機骨架(Metal-organic framework, MOF) 材料由金屬 離 子 或 金 屬 離 子 簇 所 構 成 的 節 點 (Node) 和有機分子連接器 (Organic linker)構成奈米孔洞材料。由於高度結構可調性、規律均一的孔洞尺寸與形狀、完全互相連通的孔洞結構、永久孔洞性、孔洞尺寸範圍廣(幾個埃到將近十奈米)、及具備極高的比表面積等， MOF 在多種應用中具有巨大的潛力。但在應用於電化學系統會碰到兩個問題，一是大多數的MOF缺乏化學穩定性，二是MOF通常為電的不良導體。
因此本篇採用以鈰為基底的MOF (Cerium-based MOF, Ce-MOF) Ce-MOF-808作為MOF材 料。Ce-MOF與以鋯為基底的Zr- MOF(Zirconium-based MOF)結構相似，在水中具穩定性，且Ce具備氧化還原活性。再藉由將MOF直接長 在導電聚合物聚吡咯PPy (Polypyrrole)上，透過與導電聚合物的串連來改善MOF晶體與晶體之間的電荷傳遞，增進導電率，並將其應用於電化學感測多巴胺。

Since Ce-MOF-808(Cerium-based MOFs) is water-stable MOF and possess hexa- cerium nodes to get redox reaction between Ce(IV) and Ce(III), it became an attractive candidates to use in electrochemical application last few years. But it has a great challenge to conquer, which is its low conductivity. To resolve this problem, there is a strategy which is combining MOFs to conducting polymers in series.
In this work, Ce-MOF-808 are directly grown on the surface of polypyrrole (PPy) by a facile one-step solvothermal synthesis method. And all the Ce-MOF, PPy, and nanocomposites are used as electrocatalyst for the electrochemical sensor detecting dopamine in aqueous electrolytes.

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