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研究生: 林津裕
Lin, Chin-Yu
論文名稱: 銀鈀合金型/銀鈀金合金型打線在可靠度測試下之介面反應
The Interfacial Reactions in Pd-alloyed/Au-Pd-alloyed Ag wire bonds under reliability tests
指導教授: 呂國彰
Lu, Kuo-Chang
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2014
畢業學年度: 102
語文別: 中文
論文頁數: 60
中文關鍵詞: 銀鈀合金型打線銀鈀金合金型打線可靠度測試介面反應
外文關鍵詞: Ag-Pd alloyed wire, Ag-Pd-Au alloyed wire, Reliability Test, Interfacial Reaction
相關次數: 點閱:60下載:0
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  • 本研究主要藉由SEM-EDS與SEM-EBSD分析觀察銀鈀合金(97%Ag-3%Pd)/銀鈀金合金 (89%Ag-3%Pd-8%Au)打線在可靠度測試過後之界面反應及微觀組織。研究結果顯示,當進行高溫儲存試驗(HTST)、高加速溫濕試驗(HAST)後,銀鈀合金線會形成Ag3Al2、Ag2Al、Ag3Al等相,而銀鈀金合金線形成(Ag,Au)3Al2、(Ag,Au)2Al、(Ag,Au)3Al、(Ag,Au)4Al等相,且銀鈀金合金打線在介面處的介金屬化合物(Intermetallic Compound, IMC)生長速率、鋁墊隨時間消耗程度會快過合金型銀鈀打線。在HTST持溫500小時後,可以發現在銀鈀金合金型(Ag-3Pd-8Au)打線下的鋁墊已經反應耗盡,並且在介金屬化合物中出現裂縫(Crack),而銀鈀合金型(Ag-3Pd)打線則在持溫1000小時,才有明顯的裂縫生成,但兩者裂縫生長速度均為緩慢。另外,較慢的銀-鋁間介金屬化合物生長速率及特定的介金屬相生成都有助於接點性質提升,而較複雜的介金屬化合物,將使可靠性質較為不佳,故銀鈀合金型(Ag-3Pd)打線的開發對於改善打線接合處的可靠度性質有正面幫助,未來或許可以成為合金型打線的主流材料之一。

    In this research, we focused on the Ag-alloyed wire bonding reliability in interface. Owing to copper wires induced a higher stress to the bond pad and high oxidation voltage, these disadvantage implies the issue of reliability with copper wires. Thus, seeking a newly alternative materials is needed. Being similar with gold, silver has emerged as the first choice. When it comes to silver wires, the low tensile stress of pure silver, sulfuration and oxidation would lead to a decreasing reliability, so pure silver were not ideal for wire bonding. Alloying silver with gold and palladium can not only increase the tensile stress but also prevent the sulfuration and oxidation. As a result, we compared the interfacial reaction and microstructure in Ag-3Pd/Ag-3Pd-8Au bonding wires after HAST and HTST reliability tests by SEM-EDS and SEM-EBSD. Ag-3Pd-8Au has higher consumption of aluminum pad and growth rate of IMCs than Ag-3Pd under HAST and HTST. We suggested this phenomenon is probably owing to the gold addition. Ferurthmore, the Ag-3Pd-8Au wire came with multi-layer IMCs may cause the decreasing in reliability. Finally, the lower growth rate of IMCs and certain IMCs growth would provide a stable property of wire bonding. The Ag-3Pd bonding wires maybe become a main choice of material in wire bonding.

    中文摘要 I Extended Abstract II 誌謝 XIII 總目錄 XIV 表目錄 XVI 圖目錄 XVII 第一章 前言 1 第二章 理論基礎及文獻回顧 3 2-1 打線製程原理 3 2-1-1 放電結球製程(Electrical Flame-Off process,EFO) 7 2-1-2 熱音波振動接合 8 2-2 打線材料 11 2-2-1打線替代材料─銀(Ag) 12 2-2-2 純銀打線 13 2-2-3合金型銀打線 16 2-3 銀鋁間介金屬化合物 20 2-4 銀線接點的可靠度測試 22 2-5 界面反應行為 24 第三章 實驗方法與步驟 26 3-1 實驗構想 26 3-2 打線製程 27 3-3 環境可靠度測試條件 30 3-4橫截面試片製備 31 3-5 微觀組織觀察與分析 33 3-6 界面反應相與成份分析 36 第四章 實驗結果與討論 38 4-1 銀鋁界面微觀組織觀察 38 4-1-1 HAST可靠度測試觀察 40 4-1-2 HTST可靠度測試觀察 41 4-2 銀鋁間介金屬化合物相鑑定 44 4-3 介金屬化合物成長動力學探討 51 第五章 結論 56 參考文獻 57

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