| 研究生: |
陳俊仁 Chen, Chun-Jen |
|---|---|
| 論文名稱: |
銀修飾奈米二氧化鈦增強可見光吸收度之研究 Studies on the Silver Modified TiO2 Nanoparticles for Enhancing Absorption of Visible Light |
| 指導教授: |
黃守仁
Whang, Thou-Jen |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 化學系碩士在職專班 Department of Chemistry (on the job class) |
| 論文出版年: | 2005 |
| 畢業學年度: | 93 |
| 語文別: | 中文 |
| 論文頁數: | 83 |
| 中文關鍵詞: | 二氧化鈦 、光觸媒 |
| 外文關鍵詞: | Titanium Dioxide, photocatalyst |
| 相關次數: | 點閱:209 下載:13 |
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摘要
二氧化鈦光觸媒具有光催化、無毒及化學穩定度高的特性,且是一種極為傑出的環保的光觸媒材料。
銀於文獻上的報載具有抑菌及殺菌的功能。本研究的目的在於使用銀修飾奈米二氧化鈦光觸媒,使其於可見光光譜有吸收峰。與其他文獻報載較不同處乃在於本研究利用Nd–YAG雷射為二氧化鈦光觸媒之激發源,並配合光降解實驗來探討銀修飾奈米二氧化鈦的結果。
由最後的結果得知以Nano Ag 2.0 wt % : TiO2 98.0 wt % 與 AgNO3 2.0 wt % : TiO2 98.0 wt % 之比例修飾奈米二氧化鈦光觸媒在可見光光譜區(380~780 nm)不僅有明顯的吸收峰,在光催化特性上亦明顯較未改質的奈米二氧化鈦光觸媒有較出色的表現。
Abstract
Titanium Dioxide photocatalyst has the characteristics of photo- catalysis, non toxicity and high stability of chemistry. It is also an outstanding photocatalyst material of environmental protection.
According to the literature, silver has the function of bacteriostasis and disinfection. Thus, the purpose of this study is to use silver to modify nanometer Titanium Dioxide photocatalyst and to make it reach a absorbing peak under visible light spectrum. This study is very different from the records of other literature because this study adopts Nd-YAG laser to be the energy of titanium dioxide photocatalyst and combine photodegradation experiment to investigate the result of nanometer Titanium Dioxide.
The results of the study showed that nanometer Titanium Dioxide photocatalyst, which is modified by the proportion of Nano Ag 2.0 wt % : TiO2 98.0 wt % and AgNO3 2.0 wt % : TiO2 98.0 wt %, has not only an obvious absorbing peak under visible light spectrum, but also a better result in photocatalysis compared with the original Titanium Dioxide photocatalyst.
參考文獻
1.A. Fujishima, K. Hashimoto and T. Watanabe, TiO2 Photocatalysis : Fundamentals and Application, BKC, Tokyo, 235(1999).
2.http://www.bnext.com.tw/mag/1999_08/1999_08_184.html
3.張志誠,奈米技術,全面報到,就業情報,319, 43(2002).
4.A. Fujishima, K. Honda, Nature, 238, 37 (1972).
5.H. M. Sung-Suh, J. R. Choi, H. J. Hah, S. M. Koo, and Y. C. Bae, J. Photochem. Photobiol. A: Chem. 163,37(2004).
6.S. M. Modak and C. L. J. Fox, Biochem Pharamacol. 22, 2371 (1973).
7.T. J. Berger, J. A. Spadaro, S. E. Chapin, and R. O Becker, Agents
Chemother. 9, 357 (1976).
8.M. M. Kondo and W. F. Jardim, Wat. Res. 25, 823 (1991).
9.A. Sclafani, M. N. Mozzanega, and P. Pichat, J. Photochem. Photobiol. A: Chem. 59, 181 (1991).
10.J. M. Herrmann, H. Tahiri, Y. Ait-Ichon, G. Lassaletta, A. ( Gonzalez Elipe, and A. Femandez, App. Catal. B: Environ. 13, 219 (1997).
11.M. Lal and V. Chhabra, J.Mater. Res. 13, 1249 (1998).
12.A. Fujishima, T. N. Rao, and D. A. Tryk, J. Photochem. Photobiol. C:Photochem. Rev. 1, 1-21(2000).
13.A. Hagfeldt and M. Gratzel, Chem. Rev. 95, 735 (1995).
14.M. R. Hoffmann, S. T. Martin, W. Choi, and D. W. Bahnemann, Chem. Rav. 95, 69-96(1995).
15.J. K. Budett, T. Hughbanks, G. J. Miller, and J. W. Richardson, J. Am. Chem .Soc. 109, 3639 (1987).
16.G. Binnig and H. Rohrer, In Touch with Atoms. 71, S324 (1999).
17.M. Tadashi, Applied and Environmental microbiology. 1330 (1988).
18. A. Fujishime, K. Hashimoto and T. Watanabe, BKC, Tokyo (1999).
19.P. Vettiger, G. Cross, M. Despont, U. Drechsler, U. Dig, B. Gotsmann, W. Herle, M. A. Lantz. H. E. Rothuizen, R. Stutz, and G. Binnig,
The“Millipede”-Nanotechnology Entering Data Storage. 1(1), 39 (2002).
20. S. T. Purcell, P. Vincent, C., Journet, and Vu T. Binh, Physical Review Letter. 11 (2002).
21.A. J. Bard and L. R. Faulker, Electrochemical Methods Fundamentals and Application, John Wiley & Sons, New York (1980).
22. H. Arnim, Chem. Ren. 89, 1861 (1989).
23. A. J. Bard, H. Science. 207, 139 (1980).
24. A. Sclafani and J. M. Herrmann, J. Photochem. Photobiol. A 113, 181 (1998).
25.A. Word, Chem. Master. 5, 280 (1993).
26.V. Subramanian, E. Wolf, and P. Kamat, J. Phys. Chem. B 105, 11439 (2001).
27.C. Y. Wang, C. Y. Liu, X. Zheng, J. Chen, and T. Shen, Colloid. Surf. A. 131, 271 (1998).
28.A. L. Linsebigler, G. Lu, and J. Yates, Chem. Rev. 95, 735 (1995).
29.K. Hirano, H. Asayama, A. Hoshino, and H. Wakatsuki, J. Photochem. Photobiol. A. 110, 307 (1997).
30.A. Sclafani and J.M. Herrmann, J. Photochem. Photobiol. A. 113, 181 (1998).
31.J. N. Chen, Y.C. Chan and M.C. Lu, Wat. Sci. Tech. 39, 225 (1999).
32.H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl, and R. E. Smally, Nature, 318, 162 (1985).
33.牟中原 物理雙月刊 二十三卷六期,67 (1999).
34. A. M. Morales, C. M. Lieber, Science, 279, 208 (1998).
35.T. Guo, P. Nikolaev, A. Thress, D. T. Colbert, and R. E. Smalley, Chem. Phys.Lett. 243, 49 (1995).
36. A. Fojik, A. Henglein and B. Bunsenges, Phys. Chem. 97, 1993 (252).
37. J. Neddersen, G. Chumanov, T. M. Cotton, Appl. Spectrosc. 47, 1993 (1959).
38. J. S. Jeon and C. S. Yeh, J. Chin. Chem. Soc. 45, 721 (1998).
39. (a) Y. H. Yeh, M. S. Yeh, Y. P. Lee, and C. S. Yeh, Chem. Lett. 1183 (1998).
(b) M. S. Yeh,Y. S. Yang, Y. P. Lee, H. F. Lee. Y. H.Yeh, and C. S. Yeh, J. Phys. Chem. B, 103, 6851 (1999).
40.F. Mafune, J. Y. Kohno, Y. Takeda, T.Kondow, and H. Sawabe, J. Phys
Chem.B, 104, 9111 (2000).
41.W. Hoheisel, U. Schulte, M.Vollmer, and F. Trager, Appl. phys. A51, 271 (1990).
42.A. Henglein, J. Phys Chem. 97, 5457 (1993).
43.T. M. Cotton, John Neddersen and George Choumanov, Appl.
Spectrosc. 47, 1959 (1993).
44.Y. Ta keuchi, T. Ida, and K. Kimura, J. Phys. Chem. B. 101, 1322(1997).
45.Y. Murakami, T. Matsumoto and Y. Takasu, J. Phy. Chem. B. 103, 1836 (1999).
46.呂宗昕,圖解奈米科技與光觸媒。商周出版,148 (2003).
47.丁勝懋,雷射工程導論,第四版。中央出版社出版,243(1995).
48.W. D. Callister Jr., Materials Science and Engineering, An introduction, John Wiley & Sons, New York. 54 (1994).
49. D. B. Willams and C. B. Carter, Plenum Press New York. 11 (1996).
50. J. I. Goldstein, D. E. Newbury, P. Echlin, D. C. Joy, A. D. Romig, Jr, C. E. Lymen, C. Fiori and E. Lifshin, Wiley. London. 69 (1992).
51. D. E. Newbury, D. C. Joy, P. Echlin, C. Fiori and J. I. Goldstein, Plenum. Press. New York. 211 (1986).
52.楊哲人,儀器總覽材料分析儀器,國科會精密儀器發展中心出版
53.張立德、牟季美,奈米材料和奈米結構。滄海書局,124 (2002).
54. M. Anpo, Y. Ichihashi, M. Takeuchi, and H. Yamashita, Res. Chem. Interned. 24, 143 (1998).
55. B. Ohtani, K. Iwai, Sei-ichi Nishimoto, and S. Sato, J. Phys. Chem. B. 101, 3349 (1997).
56.R. S. Magliozzo and A.I. Krasna, J. Photochem. Photobiol. A: Chem. 38, 15(1983).
57.T. Kawai and T. Sakata, J. C. S. Chem. Comm. 694, 23 (1980).
58.S. Sato and J. M. White, Chem. Phy. Lett. 72, 83 (1980).
59.K. Yamaguti and S. Sato, J. Chem. Soc. Faraday Trans. 81, 1237 (1985).
60. K. Watanabe, K. Ichimura, and N. Inoue, Chem. Phy. Lett. 124, 196 (1986).
61.Y. Sakata, T. Yamamoto, T. Okazaki, H. Imamuma, and S. Tsuchiya,
Chem. Lett. 1253 (1998).