摘要
有機發光二極體材料近年來成為一種非常重要的電激發光材料，在相關文獻報導中，具1,3,4-(口咢)二唑環與(口卡)唑環衍生物，具有良好傳輸電子及阻擋洞子傳輸的功能，且其相關的衍生物也常被運用於發藍光的電激發光材料中。
本論文以3-(口比)啶甲酸乙酯及α-氯醯基芳香(月井)‧氯化氫為原料，經由一連串的反應，合成出具1,3,4-(口咢)二唑環、1,2,4-三唑及(口卡)唑環的多雜環化合物。並將所得的產物透過UV-Vis、PL及CV的測試來探討其光電性質。
希望藉由光電性質的探討，拓展α-氯醯基芳香(月井)‧氯化氫在合成小分子有機電激發光材料上的應用。

Abstract
Organic compounds, which can be used to make organic
light-emitting diodes, have recently become an interesting and
important material. Research on looking for potential target
compounds has been studied intensively. Compounds derived from
1,3,4-oxadiazoles and carbazoles had been reported having good
electron-transporting and hole-transporting properties and
had been applied as blue light-emitting materials.
In this thesis, polyheterocyclic compounds containing the moiety of 1,3,4-oxadiazole,carbazole, or 1,2,4-triazole were synthesized through series reactions. The electroluminiecent properties for the obtained products were studied by analyzing UV-VIS, PL,and CV spectra.
In this study we have shown that it is possible to synthesize potential target compounds, polyheterocyclic compounds, by starting from α-chloroformylarylhydrazine‧hydrochochloride to make OLED device.

參考文獻
1. C. Adachi, T. Tsutsui and S. Saito, Appl. Phys. Lett. 1989, 55, 1489
2. Y. Hamada, C. Adachi, T. Tsusui and S. Saito, Jpn. J. Appl.Phys. 1991, 1540.
3. Y. Hamada, C. Adachi, T. Tsusui and S. Saito, Jpn. J.Appl. Phys. 1992, 31, 1812.
4. D. O’Bradley and T. Tsutsui, J. Appl. Phys. 1997, 82, 2662.
5. K. Kawate, K. –I. Ohkura, M. Yamazaki, M. Kuroda and O. Nabeta, Proc.SPIE Int. Soc. Opt. Eng. 1994, 2174, 200.
6. H. Ueda, T. Kitahora, K. Furukawa and Y. Terasaka, Synth. Met. 1997, 91,257.
7. J. Bettenhausen, P. Strohriegl, W. Brutting, H. Tokuhisa and T. Tsutsui,J. Appl. Phys. 1997, 82, 4957.
8. Y. Shirota, Y. Kuwabara, D. Okuda, R. Okuda, H. Ogawa, H. Inada, T. Wakimoto, H. Nakada, Y. Yonemoto, S. Kawami and K. Imai, J. Luminesc. 1997, 72-74, 985.
9. S. Tokito, H. Tanaka, K. Noda, A. Okada and Y. Taga, Macromol. Symp. 1997,125, 181.
10. 張志仲 國立成功大學化學研究所碩士論文1997.
11. C. Zhang , H. von Seggern , K. Pakbaz , B. Kraabel , H.W.Schmidt , and A. Heeger , J. Synth. Met. , 1994 ,62 , 35
12. B.Hu , Z. Yang and F. E.Karasz , J. Appl. Phys. , 1994 ,76 , 2419
13. Z. Zhu ; J. S. Moore. J. Org. Chem. , 2000 , 65 , 116
14.J.A.Joule,Heterocycl.Chem.,1984,35,83
15.柯畢嘉,林建村,化學,2002.,60,1,85

16.林宗賢 國立成功大學化學研究所碩士論文2002.
17. M.Y.Yeh,J.H.Tien ,Y.L.Haung,H.M.Chen,J.Chin.Chem.Soc., 1983,30,29
18.P.S.N.Reddy,P.P.Reddy,Indian J.Chem.Sect B ,1987,26B ,890
19.李盈儒 國立成功大學化學研究所碩士論文2003.
20.Thelakkat, M.; Schmidt, H.W. Adv. Mater. 1998, 10, 219.
21.邱俊彥國立成功大學化學研究所博士論文2003