| 研究生: |
林義鈞 Lin, Yin-Jiun |
|---|---|
| 論文名稱: |
燃料電池雙極板射出成型纖維排向模擬分析 Simulation and Analysis of Fiber Orientation in Injection Molded Bipolar Plates for Fuel Cell |
| 指導教授: |
黃聖杰
Hwang, Sheng-Jye |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 機械工程學系碩士在職專班 Department of Mechanical Engineering (on the job class) |
| 論文出版年: | 2008 |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 72 |
| 中文關鍵詞: | 射出成型 、纖維排向 、直交表 、田口方法 、Moldex3D 、燃料電池 、雙極板 |
| 外文關鍵詞: | Fiber Orientation, Moldex3D, Fuel Cell, Injection Molding, Bipolar Plate, Taguchi Methods, Orthogonal Arrays |
| 相關次數: | 點閱:140 下載:6 |
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本研究以質子交換膜燃料電池 ( Proton Exchange Membrane Fuel Cell, PEMFC ) 之雙極板為例,使用Moldex3D模流分析軟體作含纖維材料流動分析,應用射出成型製程製作雙極板,並以掃描式電子顯微鏡( Scanning Electron Microscopy, SEM )觀察纖維排向。
研究中以複合材料 PA6( Polyamide, Nylon6 )+ 40%CF和30%CF碳纖維( Carbon Fiber ),纖維(長度200μm/直徑10μm),運用田口方法分析實驗,流道採用圓角設計,成品尺寸為100mmX100mmX3.6mm,流道寬度及深度均為1.2mm,並以直交表不同射出製程條件:流道配置方向(分別垂直與平行充填方向)、材料溫度、模具溫度、射出壓力、保壓壓力、背壓、充填速度、螺桿轉速,實驗因子並加以量測所成型的試片。
研究結果顯示製程參數,當流道垂直於充填方向時,會使纖維產生翻滾而糾結在一起,而降低電阻值;流道平行於充填方向時,具有提升電阻均勻性。
This research took bipolar plate of Proton Exchange Membrane Fuel Cell (or PEMFC) as the study case, and used Moldex3D mold flow analysis software to analyze the flow of fiber material. The bipolar plate was fabricated through injection molding process, and observed the fiber orientation with Scanning Electron Microscopy (or SEM).
This research used PA6 (Polyamide, Nylon6) and +40% or 30% carbon fiber. Fiber (Length 200μm / Diameter 10μm). Taguchi methods was utilized to analyze the experiment. It adopted fillet (round corner) design on the channel, and the finished product had a size of 100mmX100mmX3.6mm, and the channel was 1.2mm in its width and depth. Different injection process conditions were used: channel configuration direction (parallel and vertical to filling direction respectively), melt temperature, mold temperature, injection pressure, hold pressure, back pressure, injection rate and screw speed. Experimental factors were applied to mold test pieces and measured.
The results of this research showed that the fiber would turn around and entangle together, and thus decreased the electrical resistance when the channel was vertical to the filling direction. The uniformity of resistance would be increased when the channel was parallel to the filling direction.
[1]黃鎮江編著,“燃料電池”,全華科技圖書,2007年。
[2]衣寶廉、黃朝榮、林修正,“燃料電池-原理與應用”,五南圖書出版,2005年。
[3]台灣燃料電池資訊網http://www.tfci.org.tw
[4]鄭耀宗等著,現場型磷酸燃料應用於大用戶之可行性研究,1995年。
[5]Fuel Cell Handbook,fifth edition ,2000年。
[6]左峻德,燃料電池之特性與運用,2001年。
[7]彭信舒,“光學產品射壓成型製程特性之研究”,中原大學碩士論文。(1999)
[8]施銘奕,“PEM 燃料電池導電性極板射出成型製程條件對導電性品質提升之研究”,中原大學機械工程學系碩士論文。(2005)
[9]彭秉峰,“導電性複和材料於射出成型之EMI屏蔽效應研究”,中原大學碩士論文。(2002)
[10]F. Folgar and C. L. Tucker III, Orientaion Behavior of Fibers in Concentrated Suspensions, Journal of Reinforced Plastics and Composites, Vo1.3,p98~118,(1984)
[11]S. G. Advani and C. L. Tucker III, The Use of Tensors to Describe and Predict Fiber Orientation in Short Fiber Composites, Journal of Rheology,Vo1.31,p751~784,(1987)
[12]R. H. J. Blunk, D. J. Lisi, Y. E. Yoo and C. L. Tucker III, “Enhanced Conductivity of Fuel Cell Plates through Controlled Fiber Orientation”, AIChE Journal, Vol. 49, pp.18-29. (2003)
[13]F. Mighri, M. A. Hunealt, and M. F. Champage, “Electrically Conductive Thermoplastic Blends for Injection and Compression Molding of Bipolar Plates in the Fuel Cell Application”, Polymer Engineering and Science, 2004.
[14]M. Gupta,K. K. Wang, Fiber Orientation and Mechanical Properties of Short-Fiber-Reinforced Injection-Molded Composites : Simulated and Experimental Results, Polymer Composites, Vo1.14, No.5, p367~382, 1993.
[15]張榮語,“射出成型模具設計-材料特性”,高立圖書,2001年。
[16]科盛科技,CAE模流分析技術入門與應用,全華科技圖書,2002年。
[17]張朝誠,“纖維含量對短纖維射出成型複合材收縮及翹曲之影響”,碩士論文,國立成功大學。(1994)
[18]李輝煌,“田口方法-品質設計的原理與實務”,高立圖書有限公司(2004)。
[19]豐新國際科技股份有限公司http://www.fonstargroup.com