本研究分為兩部分進行，第一部分以不同的黏著劑搭配活性碳材塗佈於鋁集電器上，分別為聚丙烯腈共聚高分子PN-MA搭配有機溶劑DMAc、以及水系黏著劑CMC/SBR搭配DI water作為溶劑，並透過最適化的測試，使黏著劑與電解質及碳電極表面有較佳的搭配性。而後以鋁塑複合軟包的形式組裝成1F超級電容器，經過20,000圈的長效循環後可以保持80%的電容維持率。
本研究第二部分以開發膠固態電解質為首要目標，在膠固態電解質中，透過高分子間的作用力，藉以形成主鏈架構，進而成為離子有效的傳輸通道。本研究採用聚丙烯腈共聚高分子PN-MA以及PEG作為主鏈架構，
因為此二種高分子屬非結晶高分子，能有效降低離子移動阻力。而PN-MA的酯類側鏈因具有較強的極性，對於活性碳材表面的親水含氧官能基能夠形成強作用力，形成離子通道，促進離子的傳遞能力。最後以GPE-ANEG作為膠固態電解質，搭配以水系黏著劑製備而成的活性碳電極，組裝成對稱性二極式電容器，工作電位在0-2.7 V，其最大的比能量為40 Wh kg-1、比功率高達85 kW kg-1，且在低放電速率(0.5 A g-1)時，電容值較LE高，可達138 F g-1，；在高放電速率 (100 A g-1) 下的電容維持率可達84%。本研究證實了黏著劑對於電容維持率的增加、以及膠固態電解質對於電容器整體效能有明顯的提升。

This research is divided into two parts. The first part is coated on the aluminum current collector with different binders and activated carbon materials, namely, polyacrylonitrile copolymer PN-MA with organic solvent DMAc, and water-based binder CMC/SBR with DI water as the solvent, and through the most suitable test, the binder has a better compatibility with the electrolyte and the surface of the carbon electrode. Then it is assembled into a 1F supercapacitor in the form of an pouch cell. After a long-term cycle of 20,000 cycles, it can maintain 80% retention of initial capacitance.
The second part of this research takes the development of a gel polymer electrolyte as the primary goal. In the gel polymer electrolyte, through the interaction between polymers, a backbone structure is formed, which then becomes an effective ion transport channel. This study take PN-MA and PEG polymer as the framework, due to these two kinds of polymers are non-crystalline polymers, they can effectively reduce ion movement resistance. The ester side chain of PN-MA has strong polarity, leading to a strong force on the hydrophilic oxygen-containing functional groups on the surface of the activated carbon material to form ion channels and promote ion transportation. Finally, GPE-ANEG is used as a gel polymer electrolyte, combined with an activated carbon electrode prepared with a water-based binder, to assemble a symmetrical two-electrode capacitor with an operating voltage window of 0-2.7 V, it can reach a maximum specific energy density of 40 Wh kg-1 and a specific power density is as high as 85 kW kg-1. This study confirmed that the binder increases the capacitance retention rate and the gel polymer electrolyte significantly improves the overall performance of the supercapacitor.

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