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| 研究生： |
曾耀弘 Tseng, Yao-Hung |
|---|---|
| 論文名稱： |
銀鈀合金奈米粒子的製備與金奈米粒子的表面修飾 Preparation of Ag/Pd alloy nanoparticles and surface modification on Au nanoparticles |
| 指導教授： |
葉晨聖
Yeh, Chen-Sheng |
| 學位類別： |
碩士 Master |
| 系所名稱： |
理學院 - 化學系 Department of Chemistry |
| 論文出版年： | 2002 |
| 畢業學年度： | 90 |
| 語文別： | 中文 |
| 論文頁數： | 103 |
| 中文關鍵詞： | 奈米粒子 、合金 、鈀 、銀 |
| 外文關鍵詞： | Ag, Pd, alloy, nanoparticles |
| 相關次數： | 點閱：61 下載：2 |
| 分享至: |
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由於奈米材料隨著其大小及組成的不同也展現出不同的物理、化學性質而引起廣泛的研究興趣。我們做了兩個關於奈米粒子的實驗包括了(1)銀鈀合金奈米粒子的合成(2)金奈米粒子的修飾。
(1) 以雷射照射製備銀鈀合金奈米粒子的研究：
我們將銀、鈀奈米粒子混合液以雷射照射而合成組成比例為1:1
與2:1的銀鈀合金奈米粒子；除此之外，我們觀察所形成奈米粒子的大小、形狀，並分析其組成；在雷射照射的過程中，所合成出的銀鈀奈米粒子大小為7.3 ± 2.0 nm (銀：鈀為1:1) 及 5.4 ±2.0 nm (銀：鈀為2:1) ；除了以能量散佈光譜儀( EDX )來分析奈米粒子組成外，X光粉末繞射儀(XRD) 的鑑定，也得知合成出的奈米粒子為合金奈米粒子。
(2) 以鋅紫質修飾金奈米粒子的研究：
將金奈米粒子與鋅紫質以莫耳比1:1 、1:3、1:6與1:10 混合(DMF溶液水含量為18.2%)，由X光光電子光譜(XPS)分析得知已成功修飾鋅紫質於金奈米粒子上，根據紅外線光譜儀(FT-IR)的分析結果，推測金奈米粒子與鋅紫質的作用是以靜電吸引力為主；由穿透式電子顯微鏡(TEM)觀察到，修飾鋅紫質的金奈米粒子由分散變成聚集，有趣的是，在莫耳比為1:3 (金 : 鋅紫質) 時，我們觀察到奈米粒子形成樹枝狀的聚集，然而，在1: 6及1: 10 (金 : 鋅紫質) 時，奈米粒子出現了線狀排列；其形成的原因，可能是由於鋅紫質於含水溶液中形成，將在論文中討論。
Nanomaterials has attracted wide spread interest due to their size and composition dependent chemical and physical properties. Two exper- iments have been performed including (1) the synthesis of Ag / Pd alloy nanoparticles and (2) the modification of gold nanoparticles.
(1) Preparation of Ag / Pd alloy nanoparticles by laser irradiation：
Laser irradiation of colloidal mixtures of Ag / Pd was conducted to synthesize Ag / Pd alloy nanoparticles. Compositional ratios of 1:1 and 2:1 were prepared in Ag / Pd system. The compositions , the particle sizes , and the morphology were measured as a function of laser irradiation period in order to monitor the changes from two component mixtures into the alloy colloids. The average particle sizes of Ag / Pd with the 1:1 and 2:1 metal ratios were 7.3 ± 2.0 nm and 5.4 ± 2.0 nm . In addition to EDX analysis, X-ray diffraction measurements were carried out to confirm the formation of the alloy nanoparticles.
(2) Modification of Protoporphyrin Ⅸ Zinc (Ⅱ) on Au nanoparticles：
Gold nanoparticles and protoporphyrin Ⅸ zinc (Ⅱ) (ZnPP) mixtures(18.2 % H2O and 81.8% DMF) with molar ratios of 1 : 1 , 1 : 3 , 1: 6 and 1: 10 were prepared. The XPS analysis displayed the ZnPP successfully attached on the gold nanoparticles. On the basis of the FT-IR results , it is possible that the electrostatic attraction is dominant between the Au colloids and porphyrins. Self – organization was observed for the porphyrins functionalized Au particles from the TEM images. Interestingly , the radial structures were developed with the molar ratio of 1: 3 (Au：ZnPP). However , the linear arrangements appeared for the molar ratios of 1: 6 and 1: 10 (Au：ZnPP). Formation of porphyrins H- aggregation resulting in the self-organization of the Au nanoparticles has been proposed and discussed.
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