聚乙烯吡咯烷酮( poly(N-vinylpyrrolidone)，PVP )與聚甲基丙烯酸( poly(methacrylic acid)，PMA )會藉由氫鍵作用力形成高分子複合物。本研究主要探討非離子型界面活性劑Tergitol 15-S-9及Tergitol 15-S-30對PMA/PVP高分子複合物之影響。
本研究將依界面活性劑種類分類，第一部分為Tergitol 15-S-9系統，第二部分為Tergitol 15-S-30系統。利用螢光光譜、穿透度、酸鹼度及平均叢集數來了解界面活性劑分別與PVP、不同pH值環境的PMA及不同pH值環境的PMA/PVP高分子複合物之間的交互作用。
在Tergitol 15-S-30系統中，因EO鏈段較Tergitol 15-S-9長，可與PMA高分子鏈形成氫鍵的數目增加， PMA及PMA/PVP高分子複合物間受到氫鍵作用力的影響較Tergitol 15-S-9系統明顯，在酸性溶液環境中氫鍵作用力對溶液性質的影響會大於中性及鹼性溶液環境。

Poly(N-vinylpyrrolidone) ( PVP ) form complexes with poly(methacrylic acid) ( PMA ) by hydrogen bonding. The main purpose of the study is the influence of nonionic surfactant Tergitol 15-S-9 and Tergitol 15-S-30 on the complexes of PMA and PVP.
This investigation is classified according to surfactant. The first section is Tergitol 15-S-9 system, and the second section is Tergitol 15-S-30 system. The interaction between surfactant and PVP, PMA in different pH respectively, and PMA/PVP complexes in different pH were investigated by fluorescence, transmittance, pH measurements and aggregation number.
In Tergitol 15-S-30 system, its EO chain length is longer than Tergitol 15-S-9, so the number of hydrogen bonding formed with PMA increases, that the influence of hydrogen bond on PMA and PMA/PVP complexes is more marked than Tergitol 15-S-9 system. Hydrogen bonding affects the solution properties obviously in acidic solution.

[1] Saito, S., Colloid and Polymer Science 1982, 260, 613.
[2] Rosen, M. J., SURFACTANTS and INTERFACIAL PHENOMENA, John Wiley & Sons, Inc., Hoboken, New Jersey, 2004.
[3] Tadros, T. F., Introduction, Wiely-VCH Verlag GmbH & Co. KGaA:2005
[4] Salager, J. L., AMPHIPHILES AND SURFACTANTS, Universidad De Los Andes, 2002.
[5] Holmberg, K., Surfactants and Polymers in Aqueous Solution., John Wiley & Sons, Ltd, 2002.
[6] Stokes, R. J., Evans, D. F., Fundamentals of Interfacial Engineering. Canada, John Wiley & Sons, Inc, 1997.
[7] Evans, D. F., Wennerstrom, H., The Colloidal Domain: Where Physics, Chemistry, Biology, and Technology Meet. New York, VCH, 1994.
[8] Lindman, B., Surfactant. New York, Academic Press, 1984.
[9] Nikas, Y. J., Blankschtein, D. Langmuir 1994, 10, 3512.
[10] Anthony, O., Zana, R. Langmuir 1994, 10, 4048.
[11] Pandit, N. K., Kanjia, J. International Journal of Pharmaceutics 1996, 141, 197.
[12] Mu, J., Li, G., Wang, Z., Zheng, L. Journal of Dispersion Science and Technology 2000, 21, 999.
[13] Saito, S., Matsui, Y. Journal of Colloid and Interface Science 1978, 67, 483.
[14] Saito, S. Colloid and Polymer Science 1979, 257, 266.
[15] Saito, S. Journal of Colloid and Interface Science 1994, 165, 505.
[16] Chu, D. Y., Thomas, J. K. Journal of American Chemical Society 1986, 108, 6270.
[17] Kiefer, J., Somasundaran, P., Ananthapadmanabhan, K.P. Langmuir 1993, 9, 1187.
[18] Katsuura, H., Kawamura, H., Manabe, M., Maeda, H. Colloid and Polymer Science 2002, 280, 30.
[19] Anghel, D. F., Colloid and Polymer Science 2007, 285, 771.
[20] Anghel, D. F., Saito, S., Iovescu, A., Baran, A. Colloids and Surfaces A: Physicochemical and Engineering Aspects 1994, 89, 90.
[21] Vasilescu, M., Anghel, D. F., Almgren, M., Hansson, P., Saito, S. Langmuir 1997, 6951, 13.
[22] Vlachy, N., Journal of Colloid and Interface Science 2007, 315, 445.
[23] Baranovsky, V. Y. Eur.Polym. J. 1993, 29, 1137.
[24] Bailey, F. E., Lundberg, R. D., Callard, R. W. Journal of Polymer Science: Part A: General Papers 1964, 2, 845.
[25] Ikawa, T., Abe, K., Honda, K., Tsuchida, E. Journal of polymer Science: Polymer Chemistry Edition 1975, 13, 1505.
[26] Maunu, S. L., Korpi, T., Lindberg, J.J. Polymer Bulletin 1988, 19, 171.
[27] Khutoryanskiy, V. V., Dubolazov, A. V., Nurkeeva, Z. S., Mun, G. A. Langmuir 2004, 20, 3785.
[28] Liu, S., Journal of Applied Polymer Science 2001, 82, 620.
[29] Nurkeeva, Z. S., The European physical journal. 2003, 10, 65.
[30] Pradip, M., C., Somasundaran, P.,Kulkarni, R. A., Gundiah, S. Langmuir 1991, 7, 2108.
[31] Shuping, J., European Polymer Journal 2005, 41, 2406.
[32] Durai Murugan, K. and P. Natarajan European Polymer Journal 2011, 47, 1664.
[33] Bimendina, L. A., Roganov, V. V., Bekturov, E. A. Journal of Polymer Science 1974, 44, 65.
[34] Saito, S., Sakamoto, T. Colloids and Surfaces 1987, 23, 99.
[35] Skoog, D. A., Holler, F. J., Crouch, S. R. Principles of Instrumental Analysis. Canada, David Harris, 2007.
[36] Winnik, F. M. Chemical Reviews 1993, 93, 587.
[37] Turro, N. J., Yekta, A. Journal of the American Chemical Society 1978, 100, 5951.
[38] Galster, H., pH measurement : fundamentals, methods, applications, instrumentation. New York, VCH 1991.
[39] Pradip, Langmuir 1991, 7, 2108.