| 研究生: |
蕭永昇 Hsiao, Yung-sheng |
|---|---|
| 論文名稱: |
利用滲透法成長超導單晶粒塊材之研究 Study of the Mechanism of Single Grain Superconductor by Infiltration Growth Method |
| 指導教授: |
陳引幹
Chen, In-Gann |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 117 |
| 中文關鍵詞: | 釔鋇銅氧 、超導體 、滲透法 |
| 外文關鍵詞: | Y-Ba-Cu-O, infiltration growth method, superconductor |
| 相關次數: | 點閱:51 下載:1 |
| 分享至: |
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由於超導塊材所能擄獲的磁場強度正比於其臨界電流密度(Jc)與單晶粒的尺寸大小。為提升其在工業應用的可能性,主要研究致力於如何提升其磁通釘扎能力(Flux pinning strength)以及成長更大此寸的單晶粒超導塊材。
本研究主要利用滲透法(Infiltration growth method)成長Y-Ba-Cu-O單晶粒超導體,並利用球磨與添加CeO2的方式,細化成長後Y-Ba-Cu-O單晶粒超導體內部Y2BaCuO5粒徑,藉以得到Jc的提升。
實驗結果顯示,利用滲透法成長的Y-Ba-Cu-O單晶粒超導體,其Jc比利用傳統頂端熔融製程方法成長(Top seed melt-texture growth)的Y-Ba-Cu-O單晶粒超導體高,且利用滲透法成長的Y-Ba-Cu-O單晶粒超導體沒有傳統頂端熔融製程的體積減縮問題,所以較易成長出較大的單晶粒超導體。
另一方面,利用球磨30分鐘細化Y2BaCuO5前驅物後,經滲透法成長的Y-Ba-Cu-O單晶粒超導體,其Jc稍稍比未球磨的提升一些;而利用添加1.5wt%的CeO2後,經滲透法成長的Y-Ba-Cu-O單晶粒超導體,其不論在低場或高場下的Jc皆有大幅的提升。
The magnitude of trapped field within bulk superconductors is proportional to the critical current density and the size of single grain. So, it is necessary to improve the flux pinning ability and produce larger size single grain RE-Ba-Cu-O, which are both key issues to practical applications.
In this study, we try to grow the Y-Ba-Cu-O single grain superconductors by the infiltration growth method (IG). The ball-milling technique and the doping CeO2 method are utilized to decrease the grain size of Y211 in the textured single grain YBCO superconductors and enhance the Jc.
The experimental results reveal that the Jc of the YBCO superconductor by the IG process is higher than that by the conventional top-seeded melt-textured growth method (TSMTG). And the outcome shows that the YBCO single grain produced by the IG process has no volume shrinkage problem. So, the YBCO superconductor could grow larger by the IG method.
In the other research, the Jc of the sample, which is after the 30 minutes ball milling decreasing Y211 precursors, increases a little bit by the IG process. And the doping CeO2 sample enhances the Jc drastic under the low and high applied magnetic field.
1.M. Tomita, M. Murakami, “High – temperature superconductor bulk magnets that can trap magnetic fields of over 17 tesla at 29K” Nature Vol.42, Jan 30 (2003) 517-520
2.M. Morita, S. Takebayashi, M. Tanaka and K. Kimura, “Quench and Melt Growth (QMG) Process for Large Bulk Superconductor Fabrication“ Adv. Supercond., 3 (1991) 733.
3.K. Sawano, M. Morita, M. Tanaka, T. Sasaki, K. Kimura, S. Takebayashi, M. Kimura and K. Miyamoto, “High Magnetic Flux Trapping by Melt-Grown YBaCuO Superconductors” Jpn. J. Appl. Phys., 30 (1991) L1157.
4.Y. L. Chen, H. M. Chen, M. P. Harmer, V. R. Todt, S. Sengupta, D. Shi, “A new method for net-shape forming of large, single domain YBa2Cu3O6+X”, Physica C 234 (1994) 232-236
5.M.K. Wu, J.R. Ashburn, C.J. Torng, P.H. Hor, R.L. Meng, L. Gao, Z.J. Huang, Y.Q. Wang and C.W. Chu, “Superconductivity at 93K in a New Mixed-phase Y-Ba-Cu-O Compound System at Ambient Pressure” Phys. Rev. Lett. 58 (1987) 908.
6.D. C. Larbalestler et al. “Strongly linked current flow in polycrystalline forms of the superconductor MgB2”, Nature 410, (2001) 186.
7.Jun Nagamatsu, Norimasa Nakagawa, Takahiro Muranaka, Yuji Zenitani and Jun Akimitsu, “Superconductivity at 39K in magnesium diboride” Nature 410, (2001) 63-64.
8.Katsuya Shimizu, Hiroto Ishikawa, Daigoroh Takao, Takehiro Yagi and kiichi Amaya. “Superconductivity in compressed lithium at 20 K” Nature 419, (2002) 597 - 599.
9.M. Cyrot and D. Pavuna, “Introduction to Superconductivity and High-Tc Materials”, World Scientific, (1992).
10.M. Tinkham, “Introduction to Superconductivity”, McGraw-Hill, Inc. 1996
11.C. P. Bean, “Magnetization of High-Field Superconductors” Rev. Mod. Phys. 36 (1964) 31
12.S. Jin, T.H. Tiefel, R.C. Sherwood, M.E. Davis, R.B. van Dover, G.W. Kammlott, R.A. Fastnacht and H.D. Keith, “High critical currents in Y-Ba-Cu-O superconductors” Appl. Phys.Lett. 52 (1988) 2074
13.H. Fang, Y. X. Zhou, K. Ravi-Chandar and K. Salama, “On the study of the liquid infiltration and seeded growth process”, Supercond. Sci. Technol. 17 (2004) 269-273
14.S. Meslin and J. G. Noudem,” Infiltration and top seeded growth mono-domain YBa2Cu3O7-X bulk superconductor”, Supercond. Sci. Technol. 17 (2004) 1324-1328
15.陳引幹 ”超導塊狀材料及其應用”, 金重勳編, 磁性技術手冊第三十章,中華民國磁性技術協會出版,民國九十一年七月。
16.H. Fujimoto, C. Cai and E. Ohtabara, “Sm-Ba-Cu-O bulk superconductors melt-processed in air” Physica C 372-376 (2002) 1111-1114.
17.Shu-Hau Hsu, In-Gann Chen and Maw-Kuen Wu, “Preparation of c-oriented Nd-Ba-Cu-O/Ag melt-growth sample in air” Supercond. Sci. Technol. 15 (2002) 653-659.
18.Y.A. Jee, G.W. Hong, C.J. Kim and T.H. Sung, “Dissolution of SmBa2Cu3O7-y seed crystals during top-seeded melt growth of YBa2Cu3O7-y” Supercond. Sci. Technol. 11 (1998) 650-658.
19.S.I. Yoo, N. Sakai, H. Kojo, S. Takebayashi, N. Hayashi, M. Takahashi, K. Sawada, T. Higuchi and M. Murakami, “Progress in melt processing of Nd-Ba-Cu-O superconductors” IEEE Transaction on Applied Superconductivity, vol.7 No.2 June 1997.
20.C. Cai, K. Tachibana and H. Fujimoti, “Study of single-domain growth of Y1.8Ba2.4Cu3.4Oy/Ag by using Nd123/MgO thin film as seed” Supercond. Sci. Technol. 13 (2000) 698-702.
21.C. Cai and H. Fujimoto, “Effects of Nd123/MgO thin film and MgO single-crystal seeds in isothermal solidification of YBaCuO/Ag” J. Mater. Res., Vol. 15, No. 8, Aug (2000).
22.C. Cai, H. Mori, H. Fujimoto, H. Liu, S. Dou, “Crystal growth patterns in MgO seeded Y1.8Ba2.4Cu3.4Oy/Ag melt-texturing process” Physica C 357-360 (2001) 734-737.
23.C. Cai and H. Fujimoto, “Stable production of large single-domain Y1.8Ba2.4Cu3.4Oy/Ag by isothermal solidification” Physica C 357-360 (2001) 709-712.
24.H. Fujimoto, H. Ozaku, E. Ohtabara, “Sm-Ba-Cu-O bulk superconductors melt processed in air using Nd123/MgO thin film cold seeding” Physica C 386 (2003) 198-201.
25.C. Cai and H. Fujimoto, “Stable production of large single-domain Y1.8Ba2.4Cu3.4Oy/Ag by isothermal solidification” Physica C 357-360 (2001) 709-712.
26.M. Kambara, Y. Watanabe, K. Miyake, A. Endo, K. Murata, Y. Shiohara, and T. Umeda, “Effect of initial composition on distribution of RE211 (422) particles in RE123 superconductors” J. Mater. Res. 12 (1997) 2873
27.W. Bieger, G. Krabbes, P. Schatzle, L. Zelenina, U. Wiesner, P. Verges, J. Klosowski, “The influence of initial composition and oxygen partial pressure on the properties of melt-textured NdBaCuO” Physica C 257 (1996) 46-52
28.A. Hu, X. Obradors, V. Gomis, T. Puig, A. Carrillo, E. Cardellach, E. Mendoza, Z. X. Zhao and J. W. Xiong, “Fabrication of Melt-Textured Nd123 Superconductors with Nd2BaO4 Addition” Appl. Supercond. 6 (1998) 129
29.T. Puig, B. Martinez, R. Yu, A. Hu, V. Gomis, F. Sandiumenge, and X. Obradors, “Critical currents in Air Processed NdBa2Cu3O7 Melt-Textured Superconductors” Appl. Supercond. 6 (1998) 119
30.X. Yao, M. Kambara, T. Umeda and Y. Shiohara, “95 K NdBCO Single Crystal Grown in Air by Controlling Liquid Composition” Jpn. J. Appl. Phys. Part 2 36 (1997) 400
31.M. Murakami, Melt Processed High-Temperature Superconductors, World Scientific, 1992.
32.J. Karpinski, E. Kaldis, E. Jilek, S. Rusiecki and B. Bucher, “Bulk synthesis of the 81-K superconductor YBa2Cu4O8 at high oxygen pressure” Nature 336, (1988) 660
33.R. Ramesh, S. Jin, S. Nakahara and T. H. Tiefel, “Phase decomposition and structural defects in a Y-Ba-Cu-O superconductor” Appl. Phys. Lett. 57, 1458 (1990)
34.C. J. Kim, Y.A. Jee, S. C. Kwon, T. H. Sing and G. W. Hong. “Control of YBCO growth at the compact/substrate interface by bottom seeding and Yb2O3 coating in seeded melt-growth processed YBCO oxides using a MgO substrate” Physica C 315 (1999) 263-270.
35.J. Mannhart, D. Anselmetti, J. G. Bednorz, Ch. Gerber, K. A. Muller and D. G. Schlom, Proc. 6th Int. Workshop on Critical Currents in High-Tc Supercond., Cambridge, UK (1991) 5242
36.M. Murakami, “Key issues for the characterization of RE-Ba-Cu-O systems (RE:Nd, Sm, Eu, Gd)” Applied Superconductivity Vol.6, No.2-5 (1998) 51-59.
37.T. Wu, T. Egi, R. Itti, K. Kuroda and N. Koshizuka, Advances in Superconductivity VIII (1996) 481
38.L. Civale, A.D. Marwick, T.K. Worthington, M.A. Kirk, J.R. Thompson, L. Krusin-Elbaum, Y. Sun, J.R. Clem, and F. Holtzberg, “Vortex confinement by columnar defects in YBa2Cu3O7 crystals: Enhanced pinning at high fields and temperatures” Phys. Rev. Lett., 67 (1991) 648
39.I. G. Chen, J. Liu, R. Weinstein, R. Shaw, Advances in Superconductivity IX, Editors, S. Nakajima, M. Murakami, (Springer-Verlag Tokyo) (1997) 657
40.R. Weinstein, R. P. Sawh, D. Parks, M. Murakami, T. Mochida, N. Chikumoto, G. Krabbes, and W. Bieger, “Very high values of Jc obtained in NdBa2Cu3Ox by use of the U/n process” Physica C 383 (2002) 214-222
41.V. Selvamanickam, M. Mironova, and K. Salama, “Enhancement of critical current density in YBa2Cu3Ox superconductor by mechanical deformation” J. Mater. Res. Vol. 8 (2) (1993) 249
42.M. Mironova, V. Selvamanickam, D. F. Lee, and K. Salama, “TEM studies of dislocations in deformed melt-textured YBa2Cu3Ox superconductors, “ J. Mater. Res. Vol. 8 (11) (1993) 2767
43.P. Yang and C. M. Lieber, “Nanorod-Superconductor Composites: A Pathway to Materials with High Critical Current Densities” Science 273 p1836 (1996)
44.Z. L. Wang, A. Goyal, and D. M. Kroeger, “Structural and chemical disorder near the Y2BaCuO5/YBa2Cu3O7- interface and its possible relation to the flux-pinning behavior in melt-textured YBa2Cu3O7-” Physical Review B Vol. 47, 5373-5382 (1993)
45.M. Mironova, D. F. Lee and K. Salama, “TEM and critical current density studies of melt-textured YBa2Cu3Ox with silver and Y2BaCuO5 additions” Physica C 211 p188 (1993)
46.S. Pinol, F. Sandiumenge, B. Martinze, V. Gomis, J. Fontcuberta, and X. Obradors, “Enhanced critical currents by CeO2 additions in directionally solidified YBa2Cu3O7” Appl. Phys. Lett. 65(1994) 1448
47.C-J. Kim, K-B. Kim, D-Y. Won, H-C. Moon, D-S. Suhr, S. H. Lai, and P. J. McGinn, “Formation of BaCeO3 and its influence on microstructure of sintered/melt-textured Y-Ba-Cu-O oxides with CeO2 addition” J. Mater. Res. 9 (1994) 1952
48.P. J. Mcginn, T. Meugnan, S. Yeung and A. Banerjee, “Improved Flux Pinning in Melt Textured YBa2Cu3O7- Through Chemical Additions” Applied Superconducitivity Vol. 4, Nos 10-11, pp. 563-575 (1996)
49.G. Karabbes, G. Fuchs, P. Schatzle, S. Grub. J. W. Park, F. Hardinghaus, G. Stover, R. Hayn, S. -L. Drechsler, T. Fahr, “Zn doping of YBa2Cu3O7 in melt textured materials: peak effect and high trapped fields” Physica C 330 (2000) 181-190
50.G. K. Bichile, D. G. Kuberkar, Smita Deshmukh, R. G. Kulkarni, M. A. Abdeigadir and P. Boolchand, “Enhanced flux pinning by Zn substitution in YBa2Cu3O7- ” Supercond. Sci. Technol. 4 (1991) 57-61
51.M. Hussain, S. Kuroda and K. Takita, “Peak effect observed in Zn doped YBCO single crystals” Physica C 297 (1998) 176-184
52.G. Kozlowski and T. Svobodny, “Stability of growing front of YBa2Cu3Ox superconductor in the presence of Pt and CeO2 additions” Appl. Phys. Lett. 67 (1995) 288
53.N. Sakai, S. I. Yoo and M. Murakami, “Control of Y2BaCuO5 size and morphology in melt-processed YBa2Cu3O7- superconductor” J. Mater. Res., Vol.10, No.7, Jul (1995)
54.N. Ogawa, I. Hirabayashi and S. Tanaka, “Preparation of a high-Jc YBCO bulk superconductor by the platinum doped melt growth method” Physica C 177 (1991) 101.
55.M. Matsui, N. Sakai, S. Sakai, S. J. Seo, and M. Murakami, “Effects of Pt and CeO2 addition on the growth of Nd4Ba2Cu2O10 particles” Supercond. Sci. Technol. 13 (2000) 660
56.M. Muralidhar, M. R. Koblischka, and M. Murakami, “(Nd, Eu, Gd)-Ba-Cu-O superconductors with combined addition of CeO2 and Pt” Supercond. Sci. Technol. 13 (2000) 693
57.L. Zhou, S. K. Chen, K. G.. Wang, X. Z. Wu, P. X. Zhang and Y. Feng, “Synthesis of ultrafine Y2BaCuO5 powder and its incorporation into YBCO bulk by powder melting process” Physica C 363 (2001) 99-106.
58.J. Wang, Y. Bugoslavsky, A. Berenov, L. Cowey, A. D. Caplin, L. F. Cohen, J. L. MacManus Driscoll, L. D. Cooley, X. Song, and D. C. Larbalestier, “High critical current density and improved irreversibility field in bulk MgB2 made by a scaleable, nanoparticle addition route” Appl. Phys. Lett. 81 (2002) 2026
59.K. Christova, A. Manov, J. Nyhus, U. Thisted, O. Herstad, S. E. Foss, K. N. Haugen, K. Fossheim, “Bi2Sr2CaCu2Ox bulk superconductor with MgO particles embedded” J. Alloys and Comp. 340 (2002) 1-5
60.L. Hua, J. Yoo, J. H. Kim, H. Chung, and G. Qiao, “Microstructure and phase evolution of ultrafine MgO doped Bi-2223/Ag tapes” Physica C 291 (1997) 149-154
61.M. Muralidhar, M. Jirsa, N. Sakai, and M. Murakami, “Progress in melt-processed (Nd-Sm-Gd)Ba2Cu3Oy superconductors” Supercond. Sci. Technol. 16 (2003) R1-R16
62.M. Muralidhar, N. Sakai, M. Nishiyama, M. Jirsa, T. Machi, and M. Murakami, “Pinning characteristics in chemically modified (Nd, Eu, Gd)-Ba-Cu-O superconductors” Appl. Phys. Lett. Vol. 82 (2003) 943
63.M. Muralidhar and M. Murakami, “Effect of Eu2BaCuO5 addition on the matrix composition and flux pinning in (Nd0.33Eu0.33Gd0.33)Ba2Cu3Oy superconductors” Supercond. Sci. Technol. 13 (2003) 1587
64.A. Das, M. R. Koblischka, N. Sakai, M. Muralidhar, S. Koishikawa, T. Fukuzaki, S. J. Seo, and M. Murakami, “Magnetic and magnetic-optic characterization of the ternary compounds (Nd0.33Eu0.33Gd0.33)Ba2Cu3Oy, (Sm0.33Eu0.33Gd0.33)Ba2Cu3Oy and (Nd0.33Sm0.33Gd0.33)Ba2Cu3Oy” Supercond. Sci. Technol. 11 (1998) 1283
65.A. Das, M. Muralidhar, M. R. Koblischka, and M. Murakami, “Magneto-optic and magnetic properties of (Nd0.33Eu0.33Gd0.33)1-xYxBa2Cu3Oy superconductors” Physica C 338 (2000) 284-290
66.W. A. Fietz and W. W. Webb, “Hysteresis in Superconducting Alloys—Temperature and Field Dependence of Dislocation Pinning in Niobium Alloys” Phys. Rev.,178 (1969) 657
67.D. Dew-Hughes, “Flux pinning mechanisms in type II superconductors” Philos. Mag. 30, (1974) 293.
68.R. P. Huebener, “Magnetic Flux Structures in Superconductors” Springer-Verlag Berlin Heidelberg New York (1979)
69.H. Yamasaki, K. Endo, S. Kosaka, M. Umoda, S. Yoshida, and K. Kajimura, “Scaling of the flux pinning force in epitaxial Bi2Sr2Ca2Cu3Ox thin films” Phys. Rev. Lett. 70, (1993) 3331
70.L. Klein, E. R. Yacoby, Y. Yeshurn, A. Erb, G. Muller-Vogt, V. Breit, and H. Wuhl, “Peak effect and scaling of irreversible properties in untwined Y-Ba-Cu-O crystals” Phys. Rev. B. 49 (1994) 4403
71.T. Izumi, Y. Nakamura, and Y. Shiohara, “Crystal growth mechanism of YBa2Cu3Oy Superconductors with Peritectic reaction” J. Cryst. Growth 128 (1993) 757-761
72.T. Hatano, A. Matsushita, K. Nakamura, Y. Sakka, T. Matsumoto and K. Ogawa, “Superconducting and Transport Properties of YBCO Compounds-Orthorhombic and Tetragonal phases” Jpn. J. Appl. Phys., 26 (1987) L721.
73.T. Wu, T. Egi, R. Itti, K. Kuroda and N. Koshizuka, Advances in Superconductivity VIII (1996) 481
74.G. Karabbes, G. Fuchs, P. Schatzle, S. Grub. J. W. Park, F. Hardinghaus, G. Stover, R. Hayn, S. -L. Drechsler, T. Fahr, “Zn doping of YBa2Cu3O7 in melt textured materials: peak effect and high trapped fields” Physica C 330 (2000) 181-190
75.E. S. Reddy and T. Rajasekharan, ”Fabrication of textured REBa2Cu3O7/RE2BaCuO5 (RE=Y, Gd) composites by infiltration and growth of RE2BaCuO5 preforms by liquid phases”, Supercond. Sci. Technol. 11 (1998) 523-534
76.A. Kursumovic, Y. S. Cheng, B. A. Glowacki, J. Madsen, J. E. Evetts, “Study of the rate-limiting processes in liquid-phase expitaxy of thick YBaCuO films”, J. Cryst. Growth 218 (2000) 45-56
77.D. William, Jr. Callister “Materials science and engineering an introduction, fifth edition” 2000
78.H. Hinai, S. Nariki, K. Ogasawara, N. Sakai, M. Murakami, M. Otsuka,” Cold seeded melt growth of RE-Ba-Cu-O superconductor (RE=Gd, Y)”, Physica C 357-360 (2001) 706-708
79.Young A Jee, Gye-Won Hong, Chen-Joong Kim and Tae-Hyun Sung,” Dissolution of SmBa2Cu3O7-X seed crystals during top-seeded melt growth of YBa2Cu3O7-X”, Supercond. Sci. Technol. 11 (1998) 650-658
80.Ch. Krauns, M. Sumida, M. Tagami, Y. Yamada, Y. Shiohara,” Solubility of RE elements into Ba-Cu-O melts and enthalpy of dissolution”, Z. Phys. B 96 (1994) 207-212
81.Masato Murakami, “MELT PROCESSED HIGH-TEMPERATURE SUPERCONDUCTORS”, World Scientific, (1992).
82.高中二年級下學期物理
83.R, Cloots, T Koutzarova, J-P Mathien and M Ausloos, “From RE211 to RE123. How to control the final microstructure of superconductoring single domains”, Supercond. Sci. Technol. 18 (2005) R9-R23
84.K. Iida, N. H. Babu, Y. Shi and D. A. Cardwell, “Seeded infiltration and growth of large, single domain Y-Ba-Cu-O bulk superconductors with very high critical current densities”, Supercond. Sci. Technol. 18 (2005) 1421-1427
85.K. Iida, N. H. Babu, T. D. Withnell, Y. Shi, S. Haindl, H. W. Webe, D. A. Cardwell, ”High-performance single grain Y-Ba-Cu-O bulk superconductor fabricated by seeded infiltration and growth”, Physica C 445-448 (2006) 277-281
86.E. S. Reddy, N. H. Babu, Y. Shi, D. A. Cardwell and G.. J. Schmitz, ”Processing of single domain Y-Ba-Cu-O with pre-defined 3D interconnected porosity for bulk reinforcement”, Supercond. Sci. Technol. 16 (2003) L40-L43
87.E. S. Reddy, N. H. Babu, Y. Shi, D. A. Cardwell and G.. J. Schmitz, ”Processing of large grain Y123 superconductors with pre-defined porous structures”, Supercond. Sci. Technol. 18 (2005) S15-S18
88.A. Kursumovic, Y. S. Cheng, B. A. Glowacki, J. Madsen, J. E. Evetts,” Study of the rate limiting processes in liquid phase expitaxy of thick YBaCuO films”, Journal of Crystal Growth, vol 218, n 1, (2000) 45-56
89.William D, Callister, Jr, Materials science and engineering an introduction, fifth edition
90.劉浩偉 大學部學士論文 (2006)
91.王俊智 碩士論文 (2005)