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研究生: 陳祐瑱
Chen, Yu-Tien
論文名稱: 以電漿改質奈米碳管應用於扭轉向列型液晶顯示器改善其光電響應之研究
Studies on modified carbon nanotubes by plasma treatment to improve the electro-optical responses of twisted nematic liquid crystal displays
指導教授: 陳志勇
Chen, Chuh-Yung
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 89
中文關鍵詞: 奈米碳管聚亞醯胺電漿改質扭轉向列型液晶盒光電響應
外文關鍵詞: Carbon nanotubes, Polyimide, Plasma-treatment, Twisted Nematic Liquid crystal cell, Eletro-optical response
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  • 本研究利用電漿改質技術將馬來酸酐分子分別接枝於單壁及多壁碳管表面;接著,單壁碳管再利用酸酐和胺基反應;最後,利用表面的胺基與液晶小分子4-己基苯甲酸進行接枝反應,用以提升單壁奈米碳管在群創公司液晶中的分散性。奈米碳管上的接枝量經ESCA分析儀器結果顯示量測,單壁奈米碳管表面的液晶小分子接枝量達36.83wt%。將奈米碳管以不同濃度混摻於群創液晶中,未改質的單壁奈米碳管只能維持3天的穩定性,改質後的單壁奈米碳管可以穩定維持達14天。當添加濃度為0.03wt%的改質單壁奈米碳管至液晶溶液時,液晶溶液中的離子濃度下降率達98.32%。光電響應實驗顯示將碳管混摻於液晶中可促使臨界電壓下降,液晶分子反應速度加快,可將液晶反應上升時間由17.28ms降低至14.03ms,下降時間由10.02ms下降至6.132ms。另一方面,將接枝馬來酸酐的多壁碳管分散於NMP溶劑中,加入聚亞醯胺(polyimide, PI)製成具離子吸附功能的配向膜。由AFM掃描,可證明碳管分散於高分子薄膜表面 。將聚亞醯胺-碳管溶液塗佈於ITO玻璃上,並經過摩擦配向組成扭轉向列型液晶盒,並量測其光電性質,可以發現添加碳管之後的確使離子濃度下降,達到液晶分子反應速度加快,降低反應時間的效果。

    Single-wall (SWCNT) and multi-walled (MWCNT) carbon nanotubes functionalized with maleic anhydride (MA) by plasma treatment and well dispersed within the Innolux-LC were investigated in this study. In order to improve the dispersion of SWCNT in the liquid crystal solution, the MA modified SWCNT (SWCNT-MA) were further reacted with 4-hexylbenzoic acid. ESCA shows the quantitative analysis about the grafting percent of 4-hexylbenzoic acid on the surface of SWCNTs giving 36.83wt%. The 4-hexylbenzoic acid modified SWCNT-MA (SWCNT-MA-LC) was dispersed well in the Innolux-LC in different concentrations after the stability test. Compare to the pristine SWCNTs which had only 3 days, SWCNT-MA-LC could disperse stable in the solution for 14 days. The results of the electro-optical measurements showed that the ion density of the Innolux-LC was decreased 98.32% when SWCNT-MA-LC was dispersed within the Innolux-LC. Not only the threshold voltage of the Innolux-LC was descended, but the response time of LC was also decreased. The rise-time response of the Innolux-LC was descended from 17.28ms down to 14.03ms and the fall-time response of the Innolux-LC was decreased from 10.02 ms down to 6.132 ms. Moreover, the MWCNTs-MA were directly immobilized in the polyimide to absorbed the ions in the Innolux-LC. After MWCNT was modified by MA (MWCNT-MA), MWCNT-MA was added into the polyimide solution (PI-CNT). PI-CNT solutions were coated on the ITO then rubbed by the alignment machine to construct TN cell. AFM analysis shows that the MWCNT-MA was dispersed on the surface of the polyimide film. By the electro-optical measurement, both the ion density and response time of Innolux-LC were deceased when modified-MWCNT was in the PI.

    摘 要 i Abstract ii 誌 謝 iv 目 錄 vi 圖目錄 x 表目錄 xiv 第一章 緒論 1 1.1 前言 1 1.2 研究動機與目的 2 第二章 文獻回顧 3 2.1 奈米碳管 3 2.1.1奈米碳管的簡介 4 2.1.2奈米碳管的表面改質 6 2.2 液晶顯示器 9 2.3 液晶 11 2.3.1 液晶的發現 11 2.3.2 何謂液晶 11 2.3.3 液晶的分類 12 2.3.3.1 向列型液晶(Nematic liquid crystal) 13 2.3.3.2 膽固醇型液晶(Choelsterics liquid crystal) 14 2.3.3.3 層列型液晶 14 2.3.3.4 圓盤型液晶 15 2.3.3.5 圓盤向列型液晶 16 2.3.4 液晶的物理特性 16 2.3.4.1 秩序參數(Order parameter, S) 16 2.3.4.2 雙折射率性(Birefringence, Δn) 18 2.3.4.3 介電異向性(Dielectric anisotropy, Δε) 18 2.3.4.4 磁化率異向性(Magnetic Anisotropy, Δχ) 19 2.3.4.5 彈性黏性體理論 20 2.4 扭轉向列型液晶盒(Twisted namatic, TN) 21 2.5 扭轉向列型液晶盒的光電性質 24 2.5.1 液晶的反應時間(Response time) 24 2.5.2 液晶的臨界電壓(Threshold voltage, Vth) 26 2.5.3 液晶中的離子效應 27 2.6奈米碳管於液晶顯示器的應用 28 第三章 實驗內容 33 3.1 實驗藥品 33 3.2 實驗設備 34 3.3 分析儀器 35 3.4 實驗步驟 35 3.4.1單壁奈米碳管混摻於液晶 35 3.4.2MWCNT混摻於PI溶液 38 3.5 儀器分析方式 39 3.5.1傅立葉轉換紅外線光譜儀(FTIR) 39 3.5.2光學顯微鏡(OM) 39 3.5.3紫外光-可見光光譜儀(UV-Vis) 40 3.5.4原子力顯微鏡(AFM) 40 3.5.5穿透式電子顯微鏡(TEM) 40 3.5.6掃描式電子顯微鏡(SEM) 40 3.5.7化學分析電子儀(ESCA) 40 3.5.8示差掃描量熱儀(DSC) 40 3.5.9熱重分析儀(TGA) 41 3.6 液晶光電效應實驗 41 3.6.1液晶盒樣品製作 41 3.6.2液晶基本參數的量測 41 3.6.3液晶臨界電壓的量測 42 3.6.4液晶反應時間的量測 43 第四章 奈米碳管改質結果分析 44 4.1 SWCNT混摻於液晶系統 44 4.1.1 SWCNT酸處理及電漿改質處理 44 4.1.2 利用ESCA量測SWCNT之表面接枝率 45 4.1.3 SWCNT混摻於液晶之DSC分析 51 4.1.4 SWCNT混摻液晶之穩定性試驗 53 4.1.5液晶分子影像觀察 57 4.2 MWCNT的改質 62 第五章 奈米碳管應用於液晶盒之光電效應研究 64 5.1 SWCNT混摻於液晶系統 64 5.1.1 液晶的基本參數 64 5.1.2 液晶的臨界電壓(Vth) 68 5.1.3 液晶的反應時間 71 5.2 MWCNT混摻於PI配向膜系統 73 第六章 結論 85 6.1 SWCNT混摻於液晶層系統 85 6.2 MWCNT混摻於PI配向膜系統 86 參考文獻 87

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