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研究生: 孫銘弘
Sun, Ming-Hung
論文名稱: 表面處理對碳/碳複合材料性質研究
Study on properties of carbon/carbon composites with surface treatment
指導教授: 朱建平
Ju, Chien-Ping
陳瑾惠
Chern Lin, Jiin-Huey
共同指導: 李國榮
Lee, Kuo-Jung
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 121
中文關鍵詞: 碳/碳複合材料表面處理密封層
外文關鍵詞: carbon/carbon composites, surface treatment, hermetic layer
相關次數: 點閱:129下載:7
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  • 本實驗針對快速碳化的碳/碳複合材料進行表面處理,來增進碳/碳複合材料的密封性。此外,在預浸與含浸的過程中,使用酚醛樹脂與煤塔瀝青做為碳前驅體,探討此類碳/碳複合材料的密度、孔隙率、機械性質等。並評估此類碳/碳複合材料應用於熱交換器的可行性。
    由實驗結果顯示,碳/碳複合材料的表面處理可大幅提高碳/碳複合材料的密封性,並提高碳/碳複合材料的韌性,唯有密度、機械強度略為下降,孔隙率略為增加。酚醛樹脂基材的碳/碳複合材料具有較高的機械強度,呈現脆性的破斷面;煤塔瀝青基材的碳/碳複合材料具有較高的韌性,呈現延性的破斷面。
    綜合實驗結果發現,預浸材與含浸材使用酚醛樹脂的碳/碳複合材料具有最高的機械強度,經過表面處理的碳/碳複合材料均可通過Flinak的密封性測試,極具應用於熱交換器的潛力。

    In this study, hermetic properties of carbon/carbon composites fabricated by fast-carbonization with surface treatment on the carbon/carbon composites have been promoted. Besides, the properties of carbon/carbon composites by processing in pre-preg and impregnation with phenolic resin and coal-tar pitch as carbon precursors are investigated, such as density, porosity, and flexural strength. Moreover, the purpose of this study is to evalute the potential of the carbon / carbon composites to apply the heat exchanger tube.
    The results indicate that carbon/carbon composites with surface treatment could largely promote the hermetic properties and possess higher toughness than without surface treatment. However, density and flexural strength properties are slightly decreasing. Resin-based carbon/carbon composites show higher flexural strength and brittle fracture surface. Pitch-based carbon/carbon composites show higher toughness and ductility fracture surface.
    Consequently, carbon/carbon composites with pre-preg of resin and impregnation of resin show the highest flexural strength, and carbon/carbon composites with surface treatment can pass the hermetic test in Flinak. It shows the potential to apply heat exchanger tube.

    中文摘要 I Abstract II 誌謝 III 總目錄 V 表目錄 X 圖目錄 XII 第一章 前言 1 第二章 文獻回顧 3 2.1 碳/碳複合材料之發展 3 2.2 碳/碳複合材料之製程 4 2.2.1 預型材(preform) 4 2.2.1.1 碳纖維之介紹 4 2.2.1.2 基材種類及性質 6 2.2.1.3 碳纖維與基材間交互作用 9 2.2.2 穩定化(post-curing) 10 2.2.3 碳化(carbonization) 11 2.2.4 石墨化(graphitization) 13 2.2.5 緻密化(densification) 16 2.3 碳/碳複合材料之性質 17 2.3.1 碳/碳複合材料之熱物理性質 18 2.3.2 碳/碳複合材料之機械性質 20 2.3.2.1 密度對機械性質的影響 21 2.3.2.2 熱解碳微結構對機械性質的影響 21 2.3.2.3 碳纖維含量對機械性質的影響 23 2.3.2.4 製程對機械性質的影響 23 2.3.3 碳/碳複合材料之氧化及其防護 24 2.4 碳/碳複合材料之應用 24 2.4.1 碳/碳複合材料在航太工業之應用 24 2.4.2 碳/碳複合材料在運輸工具煞車之應用 25 2.4.3 碳/碳複合材料在高溫熱壓模具與高溫爐之應用 25 2.4.4 碳/碳複合材料在生醫材料之應用 26 2.4.5 碳/碳複合材料在核能材料之應用 26 第三章 實驗方法 47 3.1 實驗材料 47 3.1.1 基材 47 3.1.1.1 液態酚醛樹脂 47 3.1.1.2 煤塔瀝青 47 3.1.2 強化材-碳纖維布 47 3.1.3 含浸液 48 3.1.3.1 液態酚醛樹脂 48 3.1.3.2 煤塔瀝青 48 3.2 試片製備 48 3.2.1 預型材製備 49 3.2.2 真空熱壓成型 49 3.2.3 試片裁切 50 3.2.4 穩定化 50 3.2.5 預碳化 50 3.2.6 慢速碳化 51 3.2.7 石墨化 51 3.2.8 真空緻密化含浸 51 3.2.8.1 酚醛樹脂緻密化 51 3.2.8.2 煤塔瀝青緻密化 52 3.3 性質量測及分析 53 3.3.1 體密度及孔隙率量測 53 3.3.2 厚度量測 54 3.3.3 抗彎試驗 54 3.3.4 熔鹽Flinak密封測試 55 3.3.4.1 熔鹽Flinak的純化 55 3.3.4.2 熔鹽Flinak的密封測試 56 3.3.5 掃描式電子顯微鏡觀察 57 3.3.6 親疏水性接觸角量測 57 第四章 結果與討論 67 4.1 碳/碳複合材料密度性質之比較 67 4.1.1 不同預型材對碳/碳複合材料密度性質之影響 67 4.1.2 不同含浸液對碳/碳複合材料密度性質之影響 68 4.1.3 表面處理對碳/碳複合材料密度性質之影響 69 4.1.4 碳/碳複合材料密度性質的綜合比較 70 4.2 碳/碳複合材料孔隙率性質之比較 71 4.2.1 不同預型材對碳/碳複合材料孔隙率性質之影響 71 4.2.2 不同含浸液對碳/碳複合材料孔隙率性質之影響 72 4.2.3 表面處理對碳/碳複合材料孔隙率性質之影響 73 4.2.4 碳/碳複合材料孔隙率性質的綜合比較 74 4.3 碳/碳複合材料含浸效率之比較 75 4.3.1 不同預型材對碳/碳複合材料含浸效率之影響 75 4.3.2 不同含浸液對碳/碳複合材料含浸效率之影響 76 4.3.3 密封層對碳/碳複合材料含浸效率之影響 77 4.3.4 碳/碳複合材料含浸效率的綜合比較 77 4.4 碳/碳複合材料各成分體積分率之比較 78 4.4.1 G/NW系列各成分體積分率之比較 78 4.4.2 NW系列各成分體積分率之比較 79 4.4.3 綜合比較各成分體積分率之比較 80 4.5 碳/碳複合材料抗彎強度測試之綜合比較 80 4.5.1 碳/碳複合材料抗彎強度值之綜合比較 81 4.5.2 碳/碳複合材料抗彎強度曲線之綜合比較 82 4.6 碳/碳複合材料顯微結構分析 83 4.6.1 抗彎測試之顯微結構 83 4.6.1.1 破斷橫截面 83 4.6.2 氟化鹽類測試 84 第五章 結論 115 第六章 參考文獻 117

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