| 研究生: |
孫銘弘 Sun, Ming-Hung |
|---|---|
| 論文名稱: |
表面處理對碳/碳複合材料性質研究 Study on properties of carbon/carbon composites with surface treatment |
| 指導教授: |
朱建平
Ju, Chien-Ping 陳瑾惠 Chern Lin, Jiin-Huey |
| 共同指導: |
李國榮
Lee, Kuo-Jung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2011 |
| 畢業學年度: | 99 |
| 語文別: | 中文 |
| 論文頁數: | 121 |
| 中文關鍵詞: | 碳/碳複合材料 、表面處理 、密封層 |
| 外文關鍵詞: | carbon/carbon composites, surface treatment, hermetic layer |
| 相關次數: | 點閱:129 下載:7 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本實驗針對快速碳化的碳/碳複合材料進行表面處理,來增進碳/碳複合材料的密封性。此外,在預浸與含浸的過程中,使用酚醛樹脂與煤塔瀝青做為碳前驅體,探討此類碳/碳複合材料的密度、孔隙率、機械性質等。並評估此類碳/碳複合材料應用於熱交換器的可行性。
由實驗結果顯示,碳/碳複合材料的表面處理可大幅提高碳/碳複合材料的密封性,並提高碳/碳複合材料的韌性,唯有密度、機械強度略為下降,孔隙率略為增加。酚醛樹脂基材的碳/碳複合材料具有較高的機械強度,呈現脆性的破斷面;煤塔瀝青基材的碳/碳複合材料具有較高的韌性,呈現延性的破斷面。
綜合實驗結果發現,預浸材與含浸材使用酚醛樹脂的碳/碳複合材料具有最高的機械強度,經過表面處理的碳/碳複合材料均可通過Flinak的密封性測試,極具應用於熱交換器的潛力。
In this study, hermetic properties of carbon/carbon composites fabricated by fast-carbonization with surface treatment on the carbon/carbon composites have been promoted. Besides, the properties of carbon/carbon composites by processing in pre-preg and impregnation with phenolic resin and coal-tar pitch as carbon precursors are investigated, such as density, porosity, and flexural strength. Moreover, the purpose of this study is to evalute the potential of the carbon / carbon composites to apply the heat exchanger tube.
The results indicate that carbon/carbon composites with surface treatment could largely promote the hermetic properties and possess higher toughness than without surface treatment. However, density and flexural strength properties are slightly decreasing. Resin-based carbon/carbon composites show higher flexural strength and brittle fracture surface. Pitch-based carbon/carbon composites show higher toughness and ductility fracture surface.
Consequently, carbon/carbon composites with pre-preg of resin and impregnation of resin show the highest flexural strength, and carbon/carbon composites with surface treatment can pass the hermetic test in Flinak. It shows the potential to apply heat exchanger tube.
Briggs R. B., "Molten Salt Reactor Program Semiannual Progress Report
for Period Ending", ORNL-3282, Oak Ridge National Laboratory,
Oak Ridge, TN, 1962.
Bruckmann H. and Huttinger K.J., "Carbon, a Proomising material in Endoprosthetics, Part I", Biomaterials, Vol.1, pp.67-72, 1980.
Buckley J.D. and Edie D.D., in "Carbon-Carbon Materials and Composites ", Noyes, New Jersey, pp.1-281, 1993.
Bernardet V. and Gomes S., et al., "Protection of nuclear graphite toward fluoride molten salt by glassy carbon deposit ", Journal of Nuclear Materials, pp.292-302, 2009.
Chawla K.K., in "Composite Materials Science and Engineering", Springer-Verlag, New York, pp.6-228, 1987.
Chen J.D. and Ju C.P., "Effect of Sliding Speed on the Tribological Behavior of a PAN-pitch Carbon-Carbon Composite ", Materials Chemistry and Physics, Vol.39, No.3, pp.174-179, 1995.
Chen L.H., "Deformation, Transfer and Debris for Mation During Sliding Wear of Metals", Scripta Metallurgica et Materialia, Vol.24, pp.827-832, 1990.
Clark W.T., and Lancaster J.K., "Breakdown and Sliding", Wear, Vol.6, pp.467-482, 1963.
David J. Diamond, Generation IV Nuclear Energy Systems: "How They Got Here And Where They Are Going", Brookhaven National Laboratory, (2003)
Dhami T.L., Bahl O.P., et al., "Carbon-Carbon Composites Made With Oxidized Pan (Panex) Fibers", Carbon, Vol.33, No.11, pp.1517-1524, 1995.
Dresher W.H., "The Age of Fibers ", Journal of Metals, Vol.21, No.4, pp.17-26, 1969.
Fisher R., "Carbon-Carbon Brakes for Aircraft" in "Composite Materials in Aircraft Structures ", D.H.Middleton ed., John Wiley & Sons, New York, pp.336-340, 1990.
Fitzer E., "The Future of Carbon-Carbon composites", Carbon, Vol.25, pp.163-190, 1987.
Fitzer E. and Manocha L.M., "Carbon reinforcement and Carbon/Carbon composites", Springer, Berlin, 1998.
Franklin R.E., "The structure of graphitic carbons" Acta crystallographica, Vol.4, pp.253-261, 1951.
Grimes W. R. et al., “Chemical Aspects of Molten Fluoride Salt Reactor
Fuels in Fluid-Fueled Reactors”, ed. J. A. Lane et al., Addison-Wesley, NY, Chap. 12 ,1958.
Hsu S.E. and Chen C.I., "The Processing and Properties of Some C/C Systems" in "Superalloys, Supercomposites and superceramics", J.K.Tien and T.Caulfield eds., Academic Press, San Diego, CA, USA, pp.721-744, 1989.
Hutton T. J., McEnaney B. and Crelling J.C., "Structural studies of wear debris from carbon-carbon composite aircraft brakes", Carbon, Vol.37, No.6, pp.907-916, 1999.
John D.B. and Dan D.E., "Carbon-Carbon Materials and Composites", Noyes Publications, USA, pp.200-201, 1993.
Jens S., and Matthias S., et al., "Design, Fabrication, and Testing of
Ceramic Plate-Type Heat Exchangers with Integrated Flow Channel
Design", Int. J. Appl. Ceram. Technol, Germany,2010.
Kimura S., Yasuda E. and Narita N., "Friction and Wear of Carbon/Carbon Composite", Journal of Japanese Society of Lubrication Engineers, Vol.28, No.3, pp.185-191, 1983.
Ko T.H. and Ma T.S., "Effect of post-curing on the mechanical properties of carbonized phenolic resins", Polymer Composites, Vol.19, No.4, pp.456-462, 1998.
Lancaster J.K., "Transitions in the Friction and Wear of Carbons and Graphites Sliding Against Themselves", ASLE Transactions, Vol.183, pp.187-201, 1975.
Laušević Z., Marinković S., "Mechanical properties and chemistry of carbonization of phenol formaldehyde resin", Carbon, Vol.24, No.5, pp.575-580, 1986.
Michael C.Y., "Composite airframe structure", pp.62-65, 1992.
Moore D.F., in "Principles and Application of Tribology", Pergamon, Oxford, pp.1-388, 1975.
Oh S.M. and Lee J.Y., "Effect of Matrix Structure on Mechanical Properties of Carbon/Carbon Composites", Carbon, Vol.26, pp.769-776, 1988.
Park J.B., "Ceramic Implant Materials" in "Biomaterials Science and Engineering", Plenum Press, New York, pp.235-263, 1980.
Pierson H.O., in "Handbook of Carbon, Graphite, Diamond and Fullerenes", Noyes, New Jersey, pp.1-69, 1993.
Ruppe J.P., "Today and the Future in AirCraft wheel and Brake Development", Canadian Aeronautics and Space Journal, Vol.26, No.3, pp.209-216, 1980.
Savage G., in "Carbon-Carbon Composites", Chapman & Hall, London, pp.323-346, 1993.
Thoma R.E., " Phase Diagrams of Nuclear Reactor Materials",
ORNL-2548, Oak Ridge National Laboratory, Oak Ridge, TN ,1959.
Tzeng S.S. and Pan H.H., "Densification of two-dimensional carbon/carbon composites by pitch impregnation", Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing, Vol.316, No.1-2, pp.127-134, 2001.
Weeton J.W., Peters D.M. and Thomas K.L., "Introduction to Composite Materials" in "Engineers' Guide to Composite Materials", American Society for Metals, Ohio, Section1, pp.1-16, 1987.
Wielage B., Odeshi A.G., et al., "A cost effective route for the densification of carbon-carbon composites", Journal of Materials Processing Technology, Vol.132, No.1-3, pp.313-322, 2003.
Xiong X. and Huang B.Y. and Li J.H. and Xu H.J., "Friction behaviors of Carbon/Carbon composites with different pyrolytic carbon textures", Carbon, Vol.44, pp.463-467, 2006.
Yamashita Y. and Ouchi K., "A Study on Carbonization of Phenol-Formaldehyde Resin Labeled with Deuterium and C-13", Carbon, Vol.19, No.2, pp.89-94, 1981.
Yen B.K. and Ishihara and Tadashi, "An investigation of friction and wear mechanisms of carbon-carbon composites in nitrogen and air at elevated temperatures", Carbon, Vol.34, No.4, pp.489-498, 1996.
陳金多, "碳/碳複合材料等速磨潤性質研究", 國立成功大學材料科學及工程研究所博士論文, 1995.
許明發, "碳、碳纖維、碳/碳複合材料之加工技術及應用", 滄海書局, 1997.
許明發, 郭文雄, "複合材料", 高立圖書有限公司, 1988.
張福勒, "航空剎車用C/C複合材料石墨化度的研究", 中南大學博士學位論文, 2002.
郭華軒, "碳化速率對碳/碳複合材料機械及磨潤性質影響之研究", 國立成功大學材料科學及工程研究所博士論文, 2004.
高偉珉, "石墨化處理對碳/碳複合材料機械及磨潤性質之影響", 國立成功大學材料科學及工程研究所碩士論文, 2007.
黃伯云, 熊翔, "高性能碳/碳航空制動材料的製備技術", 湖南科學技術出版社, 2007.
陳彥銘, "石墨化溫度對碳/碳複合材料機械及磨潤性質之影響", 國立成功大學材料科學及工程研究所碩士論文, 2008.
朱傳裕, "石墨化順序對碳/碳複合材料機械及磨潤性質之影響", 國立成功大學材料科學及工程研究所碩士論文, 2009.
紀奕宏, "熱壓壓力及持溫時間對快速碳化製作碳/碳複合材料機械性質之影響", 國立成功大學材料科學及工程研究所碩士論文, 2010.
游柏堅, "鎳基合金於Flinak熔鹽之腐蝕行為研究",國立清華大學工程與系統科學研究所碩士論文,2010.