為追求舒適健康之室內生活環境，本研究藉由以小型環控箱系統對我國常用塗料之VOCs指標污染物選定與歷時逸散之檢測，提供我國建材VOCs基礎研究資料建立與相關健康建材檢測機制之參考。經由一階衰減模式與我國清漆逸散修正式對不同溶劑型塗料逸散行為敘述能力之比較，討論其個別適用性並加以探討建立我國塗料逸散預測式之可能。

本研究主要可歸納以下結論：
一、由本研究對我國具代表性塗料之檢測結果可知，溶劑型塗料之逸散物質比水溶性塗料更具人體危害性，其逸散量也相對較高。由檢測結果，依據本研究指標污染物選定標準水溶性塗料之定性結果並未檢測出指標污染物，而溶劑型塗料之指標污染物選定結果如下：二度底漆選定甲苯、乙酸丁酯、乙苯、二甲苯等4種指標污染物，調和漆則選定乙苯、二甲苯等2種指標污染物。
二、藉由兩種溶劑型塗料於25℃、50%RH、ACH：0.5-1下其歷時逸散定量結果與不同模式之迴歸擬合，證實我國清漆逸散經驗式具有極佳逸散行為敘述能力，加以與前人之研究成果比較（陳丁于，2003），本研究認為其可作為我國溶劑型塗料之環控箱逸散經驗模式。經由改變負荷率之討論，證實我國塗料逸散經驗式轉化為逸散預測式之可行性，並初步建立我國清漆其TVOC及各指標污染物之逸散預測式。透過塗料逸散檢測機制獲得逸散預測式後，可將其應用於不同條件下施作環境VOCs逸散風險預測，更可透過各指標污染物之預測提供更詳細評估。
三、藉由預測式對清漆應用於家具裝修之討論，得知溶劑型塗料使用所產生會對人體造成健康危害之VOCs有大量初始以及長期穩定逸散情形，因此大量溶劑型塗料使用將對人員造成相當程度之危害風險。觀察我國室內裝修行為塗料使用，溶劑型塗料主要應用於現場家具製作，因此為求安全居家環境，建議盡可能以現成品取代；若行現場施作，建議於一工作天欲結束時始進行溶劑型塗料施作，並於施作完畢後人員儘速撤離，維持現場之良好通風，以獲得較為健康安全之工作環境。
四、由於塗料對室內人員之VOCs危害除了初期施作時因大量初始逸散所帶來較急切之危害外，亦有達「指觸乾燥」後之長期穩定逸散，對人員可能造成慢性之健康危害；因此，除藉由建材認證管理機制來保障初期施工階段之逸散標準以外，如何藉由維持良好的通風條件引入新鮮外氣，以達到省能環保與健康舒適之生活環境，是值得建築從業者與民眾思考與實踐之設計和生活哲學。

For the seeking of better and healthier indoor living environment, this study was aimed to establish the database of the VOCs emitted from the local paints in Taiwan, while the small scale VOC test chamber (following ASTM D5116-97) was used as the test system. With the results of emission test of the paints, the experience model for solvent-based paints in Taiwan was confirmed, and the emission prediction models for TVOC and VOCs emitted from those were established.

The follows are the main conclusions of this study:
1.According to comparison among the qualitative and quantitative solvent-based paints and water-based ones, the solvent-based paints emitted much more VOCs and were more harmful to human than the water-based ones. The target compounds selected from sanding sealer were Toluene, Butyl acetate, Ethyl benzene, Xylene, and Ethyl benzene, Xylene from the ready-mixed paint.
2.By fitting the test data of the emission from solvent-based paints with different models, the “amended model of Taiwan varnish” was showed the excellent ability for describing the paint emission behavior, and was considered as the experience model for solvent-based paint emission in the small scale chamber in this study. With test of changing the loading factor in the model, prediction models for TVOC and VOCs form solvent-based paints were established.
3.Since the solvent-based paints can do great harm to human using as the materials in furniture decoration, it is suggested that using the made-up furniture instead of site-made one will be the better way for the health of the people in the indoor space.
4.For the long term threat from the application of solvent-based paints, how to strike to the energy-saving and health life style will be a philosophy worthy of thinking for the architects and everyone.

一、中文部分
1.CNS 9725，「塗料一般檢驗法—取樣及試驗一般條件」，經濟部中央標準局，1996。
2.朱興華，「溶劑與塗裝之關係」，塗料與塗裝技術，1996。
3.江哲銘、李俊璋，「室內建材揮發性有機物質標準檢測方法及程序之研究」，內政部建研所，2001。
4.江哲銘、李俊璋，「室內環境品質及性能研究計畫4.-塗料類建材有機逸散物資料庫之建立」，內政部建研所，2002。
5.李芝珊，「居家環境和辦公大樓室內空氣品質調查評估」，環保署，1998。
6.周伯丞、江哲銘，「建築軀殼開口部自然通風效果之研究」，成大建築博士論文，2000。
7.邵文政、江哲銘、陳丁于，「台灣地區室內氣溫對建材中揮發性有機物質逸散行為影響之研究-以清漆為例」，第十四屆中華民國建築學會建築研究成果發表會論文集，2002。
8.張志成、周淑梅，「建築室內逸散物質檢測分析研究（一）」，1999。
9.郭俊良，「塗料製造業揮發性有機物類（VOC）減量及逸散防制」，塗料與塗裝技術，1998。
10.陳丁于、江哲銘，「台灣地區室內環境因子對建材揮發性有機物質逸散行為影響之研究-以清漆為例」，成大建研所碩士論文，2002。
11.陳東榮、江哲銘，「住宅室內空氣品質（CO、CO2、PM10）現場測定與評估探討」，成大建研所碩士論文，1993。
12.陳新智，「室內木質建材揮發性有機物逸散之研究」，台大環工所碩士論文，2000。
13.陳劉旺、董欽文，「塗料製造化學」，高利圖書有限公司，1997。
14.陳震宇，「室內木質建材甲醛逸散之研究」，台大環工所碩士論文，2001。
15.彭定吉，「集合住宅室內空氣環境（CO2、CO、粉塵）現場量測方法之探討」，成大碩論，1992。
16.黃冠仁，「室內建材逸散揮發性有機物之研究－黏著劑之揮發性有機物逸散因子」，台大環工所碩士論文，1999。
17.楊廣苓、羅俊光，「環境中微量氣態有機污染物採樣方法之探討」，科儀新知第十七卷五期，1996。
18.盧昆宗，「維護室內健康安全的塗裝設計與施工要點」，塗料與塗裝技術Vol.75，2002。
19.鍾美華、黃思篿、張淑芬，「有機性有害空氣污染物列管名單篩選方法之探討」，第十屆空氣污染控制技術研討會論文集，p.193-200，1993。
二、英文部分
1.ASTM D5116-97, “Standard Guide for Small-Scale Environmental Chamber Determinations of Organic Emissions From Indoor Materials/Products”, 1997.
2.Brooks, B.O., G.M. Utter, J.A. Debory and R.D. Schimke, “Indoor Air Pollution: An Edifice Complex”, Clinical Toxicology, 1991.
3.Colombo, A., De Bortoli, M., Schauenburg, H., and Vissers, H., Chamber Testing of Organic Emission from Building and Furnishing Material, The Science of the Total Environment Vol.91., p.237-249, 1990.
4.Dr. Dagmar Schmidt Etkin, IEQ Strategies, 1996.
5.Huey-Jen Su, Pei-Chih Wu, et al., “Exposure Assessment of Indoor Allergens, Endotoxin, and Airborne Fungi for Homes in Southern Taiwan”, Environmental Research Section A 85, p.135-144, 2001.
6.J.P. Zhu, R.J. Magee, J.S. Zhang and C.Y. Shaw, “A Small Scale Chamber Test Method for Measuring Volatile Organic Compound Emissions from Wet Building Materials”, CMEIAQ Final report 1.3, 1999.
7.Johnsson, I., “Determination of organic compound in indoor air with potential reference to air quality”, Atmospheric Environment, 12, p.1371-1377.
8.Jones A.P., “Indoor Air Quality and Health,” Atmospheric Environment, 33, p.4535-4564, 1999.
9.L. Molhave, “Organic compounds as indicators of air pollution”, Indoor Air, Vol. 13, Sup. 6, p.12-19, 2003.
10.M. Maroni et al., “Indoor Air Quality”, p.443-444, 1995.
11.Maroni, M., B. Seifert and T. Lindvall, “Indoor Air Quality - a Comprehensive Reference Book”, Elsevier, Amsetrdam, 1995.
12.Matthews, T.G., Wilson D.L., Thompson, A.J., Mason, M.A., Bailey, S.N., and Nelms, L.H., Inter-laboratory Comparison of Formaldehyde Emission from Particle Board Underlayment in Small Scale Environment Chambers, Journal of the Air Pollution Control Association, Vol. 37, p.1320, 1987.
13.Molhave L., 1982, “Indoor Air Pollution Due To Organic Gases and Vapors of Solvents in Building Materials”, Environment International, Vol.8, p.117-127.
14.Molhave, L., Moller, J., “The atmospheric environment in modern Danish dwellings-measurement in 39 flats, indoor climate”, (eds.) P.O. Fanger, O. Valbjorn, Danish Building Research Institute, Horsholm, Denmark, p.171-186, 1978.
15.Nielsen, The importance of building materials and building construction to SBS, 1988.
16.Richard A. Wadden, Peter A. Scheff, “Indoor Air Pollution”, p.105-107, 1982.
17.Seifert, B. and Abraham, H.J., “Indoor air concentrations of benzene and some other aromatic hydrocarbons”, Ecotoxicology and Environmental safety 6, p.190-192, 1982.
18.Seifert, B., “Organic Indoor Pollutant: Source, Species and Concentrations”, Chemical and Environment Science Volume 4: Chemical, Microbiological, Health and Comfort Aspects of Indoor Air Quality—State of the Art in SBS, Ed. Knoppel H. and Wolkoff, p.25-36.
19.Spengler, J.D., and K.Sexton, Indoor Air Pollution: A public health perspective, Science Vol. 121, p.9-17, 1983.
20.Tichenor, B. A. and Guo, Z., “The Effects of Ventilation on Emission Rate of Wood Finishing Materias”, Environment International, Vol.17, p.317-323, 1991.
21.Tichenor, B. A., Guo, Z., and Sparks, L. E., “Fundamental Mass Transfer Model for Indoor Air Emission from Surface Coating”, Indoor Air, Vol.3, p.263-268, 1993.
22.Tichenor, B. A., “Measurement of Organic Compound Emissions Using Small Scale Chamber”, Environment International, Vol.15, p.389-396, 1989.
23.Ven Der Wal and Hoogeveen and Wouda, “The Influence of Temperature on the Emission of Volatile Organic Compound”, Indoor Air, Vol7, p.215-221, 1997.
24.Wen Cheng Shao, Zhe Ming Chiang, Ting Yu Chen, and Ying Ching Chen, “Integrated Impacts of the Indoor Temperature on the Characteristics of VOC Emissions from Local Paints in TAIWAN – Solvent-based Paints for Example”, submitted paper of Health Building conference in Singapore, 2003.
25.Ying Zhang and Fariborz Haghighat, “The Impact of Surface Air Movement on Material Emission”, Build Environ., 32（6）, 551-556, 1997.
三、日文部分
1.設備と管理編輯部編，ビル設備. 衛生管理チエツクリスト，オ一ム社，1992。
2.社團法人，日本塗料工業會 室內環境對策研究會，塗裝と塗料，Vol.582，p.62-66，1998。
3.橋本 光正，塗裝技術，28（12），p.105-117，1989。