簡易檢索 / 詳目顯示

研究生: 張哲維
Chang, Che-Wei
論文名稱: 吸附濃縮焚化系統處理揮發性有機物之特性分析研究
Characteristic Analysis of Adsorption Concentration Combustion System Treating Volatile Organic Compounds
指導教授: 李旺龍
Li, Wang-Long
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 91
中文關鍵詞: 多孔氧化鋁揮發性有機分子吸附脫附濃縮槽燃燒室
外文關鍵詞: porous alumina, volatile organic compounds, adsorption and desorption concentration tank, combustion chamber
相關次數: 點閱:53下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究使用的多孔氧化鋁在吸附脫附濃縮槽與燃燒室中扮演十分重要的角色,前者作為擔任吸附與脫附揮發性有機分子 (Volatile Organic Compounds, VOCs)的媒介,於後者為去除VOCs的關鍵。同時將建立相應的數值模型去進行氣體特性分析,透過氣體分析的結果,希望優化吸附與脫附的效果。
    本研究於吸附脫附濃縮槽與燃燒室中皆會放置多孔氧化鋁,在建立的數值模型中,當流體經過多孔氧化鋁時,需要進一步進行修正計算的方程式,例如:基於達西定律來修正傳輸過程中的動量及能量守恆方程式,以此來求得數值解結果。
    根據吸附脫附濃縮槽數值模型結果顯示,從中發現添加石棉比較符合使用效益,並根據不同邊界條件的特性分析結果可以給出較佳的優化方法。於燃燒室數值模型中可得出上下為不同疏密程度的多孔氧化鋁時可以有較高的蓄熱效果,並根據蓄熱效果與特性分析結果可得不同的雙層孔洞設計與燃燒效率。
    本研究除了可以了解氣體在吸附脫附濃縮槽與燃燒室中所發生之物理現象,並藉由氣體特性分析結果,提出優化模型的方法,期望達到最符合工業利益的設計,未來亦可透過此模型之概念用於其他工業技術上之改良。

    關鍵字: 多孔氧化鋁、揮發性有機分子、吸附脫附濃縮槽、燃燒室

    The porous alumina used in this study plays a very important role in both the adsorption and desorption concentration tank and the combustion chamber. The porous alumina is used as a medium for adsorption, desorption, and removal of volatile organic compounds (VOCs). Meanwhile, corresponding numerical models will be established to analyze gas characteristics. In the numerical models, the equations for simulations need to be modified when the fluid goes through the porous alumina. For example: Navier-Stokes equation should be modified by Darcy's law, then can obtain the more accurate numerical solution results.
    In addition to understanding the physical phenomena of the fluid in both models, this study provides few methods for optimizing the model,which based on the analysis results of the gas characteristics, hoping to achieve a design that is most in line with the interests of the industry. In the future, it will also be possible to improve other industrial technologies through this study.

    Keywords: porous alumina, volatile organic compounds, adsorption and desorption concentration tank, combustion chamber

    目錄 摘要I Extended AbstractII 目錄XX 表目錄XXIII 圖目錄XXIV 符號總表XXVI 第一章 緒論1 1.1前言1 1.2文獻回顧6 1.2.1多孔氧化鋁的特性6 1.2.2吸附脫附濃縮槽7 1.2.3燃燒室8 1.3研究動機與目的10 1.4論文架構11 第二章 研究理論13 2.1質量守恆方程式13 2.2動量守恆方程式14 2.2.1納維爾-史托克斯方程式17 2.3能量守恆方程式18 2.3.1熱傳導19 2.3.2熱對流19 2.3.3固體的能量守恆方程式20 2.3.4流體的能量守恆方程式21 2.4濃度擴散方程式22 2.4 1化學反應式23 2.5貫穿曲線24 2.6多孔氧化鋁中的理論修正25 2.6.1達西定律25 2.6.2 Darcy-Forchheimer方程式25 2.6.3哈根-泊肅葉方程式26 2.6.4 Kozeny-Carman方程式28 2.6.5修正納維爾-史托克斯方程式29 2.6.6修正能量守恆方程式29 第三章 數值分析31 3.1有限元素法31 3.1.1伽遼金法32 3.1.2離散化32 3.1.3牛頓-拉弗森法32 3.2幾何模型的建立與材料參數34 3.3邊界條件的設定37 3.3.1溫度場的邊界條件設定37 3.3.2流場的邊界條件設定38 3.3.3濃度場的邊界條件設定38 3.4模擬分析流程圖40 3.5網格靈敏度測試42 第四章 結果與討論45 4.1模型驗證45 4.1.1浸鍍45 4.1.2氣體製備46 4.1.3吸附試驗模組47 4.1.4吸附試驗結果與討論50 4.1.5模型驗證結果53 4.2運作原理與分析位置55 4.3石棉添加後的影響59 4.4吸附脫附濃縮槽結果與討論65 4.3.1較密的多孔氧化鋁-60 PPI65 4.3.2較疏的多孔氧化鋁-30 PPI69 4.3.3不同疏密程度的結果比較71 4.5燃燒室結果與討論74 4.4.1雙層孔洞設計比較75 4.4.2燃燒室氣流特性分析78 第五章 結論85 參考文獻86

    [1] W.-C. Lin, C.-H. Tsai, D.-N. Zhang, S.-S. Syu, and Y.-M. Kuo, "Recycling of aluminum dross for producing calcinated alumina by microwave plasma," Sustainable Environment Research, vol. 32, no. 1, pp. 1-17, 2022.
    [2] E. David and J. Kopac, "TOXIC COMPOUNDS GENERATED BY METALWORKING FLUIDS AND ALUMINUM SLAG LANDFILL AND THEIR EFFECTS ON ENVIRONMENT AND PEOPLE," Environmental Engineering & Management Journal (EEMJ), vol. 17, no. 3, 2018.
    [3] B. Das, B. Dash, B. Tripathy, I. Bhattacharya, and S. Das, "Production of η-alumina from waste aluminium dross," Minerals engineering, vol. 20, no. 3, pp. 252-258, 2007.
    [4] B. Dash, B. Das, B. Tripathy, I. Bhattacharya, and S. Das, "Acid dissolution of alumina from waste aluminium dross," Hydrometallurgy, vol. 92, no. 1-2, pp. 48-53, 2008.
    [5] J. Y. Park, J. H. Yi, and Y. H. Choa, "Ppb‐level ethanol gas sensor of porous anodic aluminum oxide at room temperature," Journal of the American Ceramic Society, 2023.
    [6] R. S. Liu et al., "Advances in post‐combustion CO2 capture by physical adsorption: from materials innovation to separation practice," ChemSusChem, vol. 14, no. 6, pp. 1428-1471, 2021.
    [7] 王多美, 陳俊良, 徐啟振, 楊昇府, 黃財富, and 李恆毅, "純化煉鋁集塵灰製作多孔陶瓷除濕輪應用於大蒜乾燥," 鑛冶: 中國鑛冶工程學會會刊, vol. 64, no. 3, pp. 50-61, 2020.
    [8] Y. H. Yoon and J. H. Nelson, "Breakthrough time and adsorption capacity of respirator cartridges," American Industrial Hygiene Association Journal, vol. 53, no. 5, pp. 303-316, 1992.
    [9] L. Mølhave, "Organic compounds as indicators of air pollution," Indoor air, vol. 13, pp. 12-19, 2003.
    [10] B.-S. Choi and J. Yi, "Simulation and optimization on the regenerative thermal oxidation of volatile organic compounds," Chemical Engineering Journal, vol. 76, no. 2, pp. 103-114, 2000.
    [11] A. Mohamad, "Combustion in porous media: fundamentals and applications," in Transport phenomena in porous media III: Elsevier, 2005, pp. 287-304.
    [12] L. Zhu, D. Shen, and K. H. Luo, "A critical review on VOCs adsorption by different porous materials: Species, mechanisms and modification methods," Journal of hazardous materials, vol. 389, p. 122102, 2020.
    [13] S.-W. Huang, J.-C. Lou, and Y.-C. Lin, "Treatment of VOCs with molecular sieve catalysts in regenerative catalytic oxidizer," Journal of hazardous materials, vol. 183, no. 1-3, pp. 641-647, 2010.
    [14] M. Bannai et al., "Development of efficiency-enhanced cogeneration system utilizing high-temperature exhaust-gas from a regenerative thermal oxidizer for waste volatile-organic-compound gases," Applied Energy, vol. 83, no. 9, pp. 929-942, 2006.
    [15] F. Jamshidi et al., "A 3D computational method for determination of pores per inch (PPI) of porous structures," Materials Today Communications, p. 105413, 2023.
    [16] J.-Y. Lin, B. Ding, J.-Y. Yu, G.-C. Wu, J.-M. Yang, and G. Sun, "Effect of porous structure of electrospun fibers on their specific surface area: theoretical analysis and experimental verification," International Journal of Nonlinear Sciences and Numerical Simulation, vol. 11, no. 7, pp. 523-528, 2010.
    [17] X. Wei, W. Wang, J. Xiao, L. Zhang, H. Chen, and J. Ding, "Hierarchically porous aluminosilicates as the water vapor adsorbents for dehumidification," Chemical Engineering Journal, vol. 228, pp. 1133-1139, 2013.
    [18] G.-G. Park, T.-H. Yang, Y.-G. Yoon, W.-Y. Lee, and C.-S. Kim, "Pore size effect of the DMFC catalyst supported on porous materials," International Journal of Hydrogen Energy, vol. 28, no. 6, pp. 645-650, 2003.
    [19] E. C. Hammel, O.-R. Ighodaro, and O. I. Okoli, "Processing and properties of advanced porous ceramics: An application based review," Ceramics International, vol. 40, no. 10, pp. 15351-15370, 2014.
    [20] H. Xu, C. Zhang, J. Cai, J. Wang, K. Liu, and X. Cheng, "Synthesis and characterization of activated alumina with high thermal stability by a low-heat solid-phase precursor method," Microporous and Mesoporous Materials, vol. 337, p. 111921, 2022.
    [21] A. M. Hamed, "Theoretical and experimental study on the transient adsorption characteristics of a vertical packed porous bed," Renewable Energy, vol. 27, no. 4, pp. 525-541, 2002.
    [22] M. Tatlıer and A. Erdem-Şenatalar, "Estimation of the effective diffusion coefficients in open zeolite coatings," Chemical Engineering Journal, vol. 102, no. 3, pp. 209-216, 2004.
    [23] T. n. Dobre, O. C. Pârvulescu, G. Iavorschi, M. Stroescu, and A. a. Stoica, "Volatile organic compounds removal from gas streams by adsorption onto activated carbon," Industrial & Engineering Chemistry Research, vol. 53, no. 9, pp. 3622-3628, 2014.
    [24] K. N. Gupta, N. J. Rao, and G. K. Agarwal, "Gaseous phase adsorption of volatile organic compounds on granular activated carbon," Chemical Engineering Communications, vol. 202, no. 3, pp. 384-401, 2015.
    [25] H. Darcy, Les fontaines publiques de la ville de Dijon: exposition et application des principes à suivre et des formules à employer dans les questions de distribution d'eau... un appendice relatif aux fournitures d'eau de plusieurs villes au filtrage des eaux. Victor Dalmont, éditeur, 1856.
    [26] S. P. Sutera and R. Skalak, "The history of Poiseuille's law," Annual review of fluid mechanics, vol. 25, no. 1, pp. 1-20, 1993.
    [27] P. Forchheimer, "Wasserbewegung durch boden," Zeitschrift des Vereines Deutscher Ingenieure, vol. 45, no. 50, pp. 1781-1788, 1901.
    [28] H. C. Brinkman, "A calculation of the viscous force exerted by a flowing fluid on a dense swarm of particles," Flow, Turbulence and Combustion, vol. 1, pp. 27-34, 1949.
    [29] D. Nield, "The limitations of the Brinkman-Forchheimer equation in modeling flow in a saturated porous medium and at an interface," International Journal of Heat and Fluid Flow, vol. 12, no. 3, pp. 269-272, 1991.
    [30] S. Y. Kim, B. H. Kang, and J. M. Hyun, "Heat transfer from pulsating flow in a channel filled with porous media," International journal of heat and mass transfer, vol. 37, no. 14, pp. 2025-2033, 1994.
    [31] K. Vafai and C. L. Tien, "Boundary and inertia effects on flow and heat transfer in porous media," International Journal of Heat and Mass Transfer, vol. 24, no. 2, pp. 195-203, 1981.
    [32] C. Ruivo, J. Costa, and A. Figueiredo, "Validity of pseudo-gas-side-controlled models to predict the behaviour of desiccant matrices," International journal of thermal sciences, vol. 48, no. 11, pp. 2171-2178, 2009.
    [33] D. Cheng, E. F. Peters, and J. H. Kuipers, "Performance study of heat and mass transfer in an adsorption process by numerical simulation," Chemical Engineering Science, vol. 160, pp. 335-345, 2017.
    [34] Z. Luo and H. Xu, "Numerical simulation of heat and mass transfer through microporous media with lattice Boltzmann method," Thermal Science and Engineering Progress, vol. 9, pp. 44-51, 2019.
    [35] J. Biggemann, M. Stumpf, and T. Fey, "Porous alumina ceramics with multimodal pore size distributions," Materials, vol. 14, no. 12, p. 3294, 2021.
    [36] D. Hotza, M. Di Luccio, M. Wilhelm, Y. Iwamoto, S. Bernard, and J. C. D. da Costa, "Silicon carbide filters and porous membranes: A review of processing, properties, performance and application," Journal of Membrane Science, vol. 610, p. 118193, 2020.
    [37] T. Shimonosono, H. Imada, H. Maeda, and Y. Hirata, "Separation of hydrogen from carbon dioxide through porous ceramics," Materials, vol. 9, no. 11, p. 930, 2016.
    [38] J. Howell, M. Hall, and J. Ellzey, "Combustion of hydrocarbon fuels within porous inert media," Progress in Energy and Combustion Science, vol. 22, no. 2, pp. 121-145, 1996.
    [39] M. Kamal and A. Mohamad, "Combustion in porous media," Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy, vol. 220, no. 5, pp. 487-508, 2006.
    [40] D. Trimis and F. Durst, "Combustion in a porous medium-advances and applications," Combustion science and technology, vol. 121, no. 1-6, pp. 153-168, 1996.
    [41] V. Pantangi and S. C. Mishra, "Combustion of gaseous hydrocarbon fuels within porous media–a review," Advances in Energy Research, vol. 8, pp. 455-461, 2006.
    [42] A. Oliveira and M. Kaviany, "Nonequilibrium in the transport of heat and reactants in combustion in porous media," Progress in Energy and Combustion Science, vol. 27, no. 5, pp. 523-545, 2001.
    [43] J. Malchi, R. Yetter, S. Son, and G. Risha, "Nano-aluminum flame spread with fingering combustion instabilities," Proceedings of the Combustion Institute, vol. 31, no. 2, pp. 2617-2624, 2007.
    [44] H. Pedersen-Mjaanes, L. Chan, and E. Mastorakos, "Hydrogen production from rich combustion in porous media," International journal of hydrogen energy, vol. 30, no. 6, pp. 579-592, 2005.
    [45] V. Bubnovich, M. Toledo, L. Henríquez, C. Rosas, and J. Romero, "Flame stabilization between two beds of alumina balls in a porous burner," Applied Thermal Engineering, vol. 30, no. 2-3, pp. 92-95, 2010.
    [46] K. Xu, M. Liu, and P. Zhao, "Stability of lean combustion in mini-scale porous media combustor with heat recuperation," Chemical Engineering and Processing: Process Intensification, vol. 50, no. 7, pp. 608-613, 2011.

    無法下載圖示 校內:2028-06-21公開
    校外:2028-06-21公開
    電子論文尚未授權公開,紙本請查館藏目錄
    QR CODE