簡易檢索 / 詳目顯示

研究生: 林泰甫
Lin, Tai-Fu
論文名稱: 雙面照光量測分析應用於混合型鈣鈦礦太陽能電池之研究
Double-sided illumination measurement for hybrid type perovskite solar cells
指導教授: 陳昭宇
Chen, Chao-Yu
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程學系
Department of Photonics
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 61
中文關鍵詞: 背接觸式多孔電極雙面鈣鈦礦太陽能電池
外文關鍵詞: back-­contact, porous electrode, bifacial, perovskite solar cells
相關次數: 點閱:84下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 近年來,許多不同類型的鈣鈦礦太陽能電池設計都嘗試提高兩側入光面的穿透度,其中包含了背接觸式以及夾層結構,為了比較其雙面與單面照射時的情境,本研究中模擬了雙面同時照光的情境量測,以夾層結構作為標準元件進行量測,其中,標準元件是利用FTO作為底電極,經由噴塗製程製備TiO2緻密層,接著,以SnO2奈米顆粒作為支架層後沈積一層鈣鈦礦以及電洞傳輸層(Spiro),其電洞傳輸層上方的電極則是利用金或是MoO3/IZO,電池元件在上電極以金和MoO3/IZO分別在玻璃入光面之逆向掃描時得到了15.92%與13.04%的轉換效率,最後,比較以金屬與透明導電膜作為電極在雙面以不同光強度照射下之元件性能。
    研究過程中,設計了一項不同於夾層與背接觸式結構的混合型結構,結構中之載子特性同時包含了背接觸式及夾層結構的載子移動路徑,主要是利用素玻璃作為基板,以多孔二氧化鈦作為基底,塗佈聚苯乙烯微球於多孔二氧化鈦上方,經由反應離子蝕刻的方式控制球形大小,再用真空濺鍍的方式濺鍍半透明膜層,最後去除聚苯乙烯球,形成半透明多孔電極,接著,利用此結構之電極製成電池元件,分別以金或是MoO3/IZO作為上電極,在金作為上電極時,於逆向掃描得到了4.35%的轉換效率,以MoO3/IZO作為電極時,在逆向掃描時的玻璃面及IZO面分別得到了2.84%及3.18%之轉換效率,最後將混合型結構之鈣鈦礦太陽能電池以雙面照光進行量測並討論。

    Bifacial semi-transparent perovskite solar cells (PSCs) are a popular research project.
    Currently, there has not been much discussion over simultaneous illumination on both sides of solar cells. These types of solar cells have lower performance than the device with metal electrode when irradiating on one side. For the purpose of this study, we designed a double-sided lighting environment to measure the sandwich and hybrid structure. Gold and indium zinc oxide (IZO) were used as counter electrodes to observe responses of the components under different light intensities on both sides. Thus, in this work, we simulated a double-sided lighting environment and compared the performance of devices based on electrodes using gold and indium zinc oxide (IZO).

    摘要 i 英文延伸摘要 ii 誌謝 viii 目錄 ix 表目錄 xi 圖目錄 xii 第一章 緒論 1 第二章 文獻回顧 12 第三章 實驗方法與儀器分析 25 第四章 結果與討論 34 第五章 結論與未來展望 57 參考文獻 59

    [1] J. Perlin, “Silicon solar cell turns 50,” tech. rep., National Renewable Energy Lab., Golden, CO.(US), 2004.
    [2] R. S. Ohl, “Light¬sensitive electric device,” June 25 1946. US Patent 2,402,662.
    [3] D. M. Chapin, C. Fuller, and G. Pearson, “A new silicon p¬n junction photocell for converting solar radiation into electrical power,” Journal of Applied Physics, vol. 25, no. 5, pp. 676–677, 1954.
    [4]B.M.Kayes,H.Nie,R.Twist,S.G.Spruytte,F.Reinhardt,I.C.Kizilyalli,andG.S.Hi¬ gashi, “27.6% conversion efficiency, a new record for single¬junction solar cells under 1 sun illumination,” in 2011 37th IEEE Photovoltaic Specialists Conference, pp. 000004– 000008, IEEE, 2011.
    [5] P. G. V. Sampaio and M. O. A. González, “Photovoltaic solar energy: Conceptual framework,” Renewable and Sustainable Energy Reviews, vol. 74, pp. 590–601, 2017.
    [6] U. Gangopadhyay, S. Jana, and S. Das, “State of art of solar photovoltaic technology,” in Conference Papers in Energy, vol. 2013, Hindawi, 2013.
    [7] N. R. E. Laboratory, “Best research¬cell efficiency chart,” 2020.
    [8] B. O’regan and M. Grätzel, “A low¬cost, high¬efficiency solar cell based on dye¬ sensitized colloidal tio2 films,” Nature, vol. 353, no. 6346, pp. 737–740, 1991.
    [9] A. Kojima, K. Teshima, Y. Shirai, and T. Miyasaka, “Organometal halide perovskites as visible¬light sensitizers for photovoltaic cells,” Journal of the American Chemical Society, vol. 131, no. 17, pp. 6050–6051, 2009.
    [10] S. R. Maps, “Gis data for 200+ countries,” 2016.
    [11] L. Schmidt¬Mende and J. Weickert, Organic and hybrid solar cells: an introduction. Walter de Gruyter GmbH & Co KG, 2016.
    [12] H. S. Kim, C. R. Lee, J. H. Im, K. B. Lee, T. Moehl, A. Marchioro, S. J. Moon, R. Humphry Baker, J. H. Yum, and J. E. Moser, “Lead iodide perovskite sensitized all¬ solid¬state submicron thin film mesoscopic solar cell with efficiency exceeding 9%,” Scientific Reports, vol. 2, no. 1, pp. 1–7, 2012.
    [13] N. J. Jeon, J. H. Noh, Y. C. Kim, W. S. Yang, S. Ryu, and S. I. Seok, “Solvent engi¬ neering for high¬performance inorganic–organic hybrid perovskite solar cells,” Nature materials, vol. 13, no. 9, pp. 897–903, 2014.
    [14]G.E.Eperon,S.D.Stranks,C.Menelaou,M.B.Johnston,L.M.Herz,andH.J.Snaith, “Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar het¬ erojunction solar cells,” Energy & Environmental Science, vol. 7, no. 3, pp. 982–988, 2014. [15] Y.Yu,C.Wang,C.R.Grice,N.Shrestha,J.Chen,D.Zhao,W.Liao,A.J.Cimaroli,P.J. Roland, and R. J. Ellingson, “Improving the performance of formamidinium and cesium lead triiodide perovskite solar cells using lead thiocyanate additives,” ChemSusChem, vol. 9, no. 23, pp. 3288–3297, 2016.
    [16] M. Saliba, T. Matsui, J. Y. Seo, K. Domanski, J. P. Correa Baena, M. K. Nazeerud¬ din, S. M. Zakeeruddin, W. Tress, A. Abate, A. Hagfeldt, and M. Grätzel, “Cesium¬ containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency,” Energy & Environmental science, vol. 9, no. 6, pp. 1989–1997, 2016.
    [17] R.SchwartzandM.Lammert,“Siliconsolarcellsforhighconcentrationapplications,” in 1975 International Electron Devices Meeting, pp. 350–352, IEEE, 1975.
    [18] T. M. Brenner, D. A. Egger, L. Kronik, G. Hodes, and D. Cahen, “Hybrid organic— inorganic perovskites: low¬cost semiconductors with intriguing charge¬transport prop¬ erties,” Nature Reviews Materials, vol. 1, no. 1, pp. 1–16, 2016.
    [19] T. Ma, Q. Song, D. Tadaki, M. Niwano, and A. Hirano¬Iwata, “Unveil the full poten¬ tial of integrated¬back¬contact perovskite solar cells using numerical simulation,” ACS Applied Energy Materials, vol. 1, no. 3, pp. 970–975, 2018.
    [20] C.Goh,S.R.Scully,andM.D.McGehee,“Effectsofmolecularinterfacemodification in hybrid organic¬inorganic photovoltaic cells,” Journal of Applied Physics, vol. 101, no. 11, p. 114503, 2007.
    [21] M. Bruening, R. Cohen, J. F. Guillemoles, T. Moav, J. Libman, A. Shanzer, and D. Ca¬ hen, “Simultaneous control of surface potential and wetting of solids with chemisorbed multifunctional ligands,” Journal of the American Chemical Society, vol. 119, no. 24, pp. 5720–5728, 1997.
    [22]S.Kobayashi,T.Nishikawa,T.Takenobu,S.Mori,T.Shimoda,T.Mitani,H.Shimotani, N. Yoshimoto, S. Ogawa, and Y. Iwasa, “Control of carrier density by self¬assembled monolayers in organic field¬effect transistors,” Nature Materials, vol. 3, no. 5, pp. 317– 322, 2004.
    [23] X. Lin, A. N. Jumabekov, N. N. Lal, A. R. Pascoe, D. E. Gómez, N. W. Duffy, A. S. Chesman, K. Sears, M. Fournier, and Y. Zhang, “Dipole¬field-assisted charge extrac¬ tion in metal¬perovskite¬metal back¬contact solar cells,” Nature communications, vol. 8, no. 1, pp. 1–8, 2017.
    [24] X. Lin, A. S. Chesman, S. R. Raga, A. D. Scully, L. Jiang, B. Tan, J. Lu, Y.¬B. Cheng, and U. Bach, “Effect of grain cluster size on back¬contact perovskite solar cells,” Ad¬ vanced Functional Materials, vol. 28, no. 45, p. 1805098, 2018.
    [25] M. Wong¬Stringer, T. J. Routledge, T. McArdle, C. J. Wood, O. S. Game, J. A. Smith, J. E. Bishop, N. Vaenas, D. M. Coles, and A. R. Buckley, “A flexible back¬contact perovskite solar micro¬module,” Energy & Environmental Science, vol. 12, no. 6, pp. 1928–1937, 2019.
    [26] A. Jumabekov, E. Della Gaspera, Z. Q. Xu, A. Chesman, J. Van Embden, S. Bonke, Q. Bao, D. Vak, and U. Bach, “Back¬contacted hybrid organic–inorganic perovskite solar cells,” Journal of Materials Chemistry C, vol. 4, no. 15, pp. 3125–3130, 2016.
    [27] G. DeLuca, A. N. Jumabekov, Y. Hu, A. N. Simonov, J. Lu, B. Tan, G. W. Adhyaksa, E. C. Garnett, E. Reichmanis, and A. S. Chesman, “Transparent quasi¬interdigitated electrodes for semitransparent perovskite back¬contact solar cells,” ACS Applied Energy Materials, vol. 1, no. 9, pp. 4473–4478, 2018.
    [28] G. D. Tainter, M. T. Hörantner, L. M. Pazos Outón, R. D. Lamboll, H. Āboliņš, T. Lei¬ jtens, S. Mahesh, R. H. Friend, H. J. Snaith, and H. J. Joyce, “Long¬range charge ex¬ traction in back¬contact perovskite architectures via suppressed recombination,” Joule, vol. 3, no. 5, pp. 1301–1313, 2019.
    [29] A. N. Jumabekov, J. A. Lloyd, D. M. Bacal, U. Bach, and A. S. Chesman, “Fabrication of back¬contact electrodes using modified natural lithography,” ACS Applied Energy Materials, vol. 1, no. 3, pp. 1077–1082, 2018.
    [30] Q. Hou, D. Bacal, A. N. Jumabekov, W. Li, Z. Wang, X. Lin, S. H. Ng, B. Tan, Q. Bao, and A. S. Chesman, “Back¬contact perovskite solar cells with honeycomb¬like charge collecting electrodes,” Nano Energy, vol. 50, pp. 710–716, 2018.
    [31] X. Lin, S. R. Raga, A. S. Chesman, Q. Ou, L. Jiang, Q. Bao, J. Lu, Y.¬B. Cheng, and U. Bach, “Honeycomb¬shaped charge collecting electrodes for dipole¬assisted back¬ contact perovskite solar cells,” Nano Energy, vol. 67, p. 104223, 2020.

    下載圖示
    2026-03-02公開
    QR CODE