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研究生: 蘇銘勝
Su, Ming-Sheng
論文名稱: 電子構裝材料在注模後烘烤中熱機械性質與數學模式之研究
Modeling the Thermo-Mechanical Properties of an EMC During Post-Mold Curing
指導教授: 李輝煌
Lee, Huei-Huang
學位類別: 碩士
Master
系所名稱: 工學院 - 工程科學系碩士在職專班
Department of Engineering Science (on the job class)
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 68
中文關鍵詞: EMC封裝材料應力鬆弛鬆弛模數溫度時間疊合原理線性網狀無定形高分子材料IC塑膠構裝WLF方程式
外文關鍵詞: WLF equation, The network of linear amorphous polymer, IC packaging, EMC encapsulating materials, relaxation modulus, Time-temperature Superposition principle, stress relaxation
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  • IC塑膠構裝的注模膠封製程(Encapsulating Processes of IC Packaging)中,EMC在模具裡僅初凝固成形,其殘留應力相當大也造成EMC初成形後尺寸相當不穩定,更易於影響後續IC功能測試與可靠度測試,所以必須進行注模後烘烤製程,促使交連反應更趨近於穩定完整,發揮EMC被設計賦予的功能目的和適當的機械性質,而能夠保護IC晶片且構建電子構裝體(IC Packaging)達到穩定的結構。本論文主要針對EMC在注模後烘烤作業中,探討其熱機械性質的發展變化,利用DMA/ TMA和DSC儀器實驗所觀測的熱機械性質數據建構成Maxwell Model的數學模式化,亦即構建出EMC在注模後烘烤中熱機械性質的數學模式的構建方法(Methodology),以方便在IC電子構裝體製程設計之初的工程預估及最後佳烘烤製程的設計。

    本實驗結果發現:以較低的烘烤溫度,最終卻能得到較完整較高的彈性模數,顯然欲達成較佳效益的後烘烤結果,必須先了解EMC的聚合反應溫度與材料交連擴散的速率的對應關係。

    EMC(Epoxy Molding Compound) is used to encapsulate IC on electronic packaging fields. There are some problems in the thermal process of curing EMC, such as package warpage, poor coplanarity of solder balls or lead, crack damages resulted from residual stress, delamination result from thermal stress… and so on. It is necessary for quality to minimize the warpage and deformation and improve potential damages. By the experiments of curing EMC to get the variants of thermal mechanical properties, we can modeling them by the mathematics equation of viscoelasticity and build up the methodology of modeling EMC. This study is to develop a methodology to calculate the modulus profiles during post-mold cure process and predict the EMC warpage caused by residual stress of incomplete cure and viscous stress during molding.

    摘 要 3 Abstract 4 誌 謝 5 目 錄 6 圖表目錄 9 符號說明 11 縮寫說明 12 第一章 緒論 13 1-1 前言: 13 1-2 EMC在IC構裝製程的運用 14 1-2-1 IC構裝之PBGA構裝製程簡介 14 1-2-2 電子構裝材料EMC之簡介 15 1-2-3 商業化的EMC配方之簡介 16 1-2-4 EMC的化學交連反應的簡介 17 1-3 EMC材料的聚合固化特性及其對機械性質的影響 18 1-4 EMC殘留應力的形成之簡介 19 1-4-1 製程加工高分子流變過程產生殘留應力 19 1-4-2 高分子聚合固化反應過程產生殘留應力 21 1-4-3 複合材料結構匹配著不同物性產生殘留應力 22 1-5 EMC應力鬆弛問題之簡介 23 1-6 研究目的 24 1-7 文獻回顧 24 1-7-1 聚合體材料機械行為受內外在因素之影響 24 1-7-1-1 應變速率之影響 25 1-7-1-2 溫度之影響 25 1-7-1-3 轉化率之影響 25 1-7-1-4 填充物之影響 26 1-7-2 聚合體材料的黏彈性回應 26 1-7-3 線性網狀無定形聚合體材料之時間—溫度疊合原理 27 1-7-4 時間—轉化率疊合原理 28 1-7-5 WLF公式 29 1-7-6 網狀組織的橡膠彈性的應用 30 1-8 本文架構 32 第二章 理論分析 35 2-1 聚合體黏彈模式 35 2-1-1 EMC黏彈模式參數求取過程 36 2-2 殘留應力鬆弛實驗概念 37 2-3 研究方法及步驟 38 第三章 實驗方法與步驟 39 3-1 實驗目的 39 3-2 實驗流程步驟與規劃 39 3-3 實驗設備與裝置 44 3-3-1 EMC材料 45 3-3-2 EMC試片製作之相關機台設備 45 3-3-3 烘烤箱設備 45 3-3-4 EMC材料與試片的貯存設備 46 3-3-5 DSC熱分析儀 46 3-3-6 DMA熱動態機械分析儀 46 3-4 實驗步驟與方法 47 第四章 實驗結果與討論 49 4-1 PMC製程中EMC的熱機械性質之發展 49 4-2 EMC之熱機械性質之數學模式建立 50 4-2-1溫度與轉化率之相關數學式 50 4-2-2 時間與溫度之相關數學式 51 4-2-3 EMC的彈性模數之數學模式化 53 第五章 綜合討論與未來發展 60 5-1 實驗規劃部份 60 5-2 實驗系統部份 60 5-3 彈性模數之相關數學模式部份 61 參考文獻 63 自 述 68

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