| 研究生: |
王延皓 Wang, Yan-Hao |
|---|---|
| 論文名稱: |
藉由摻雜及插入熱活化延遲螢光材料以改善量子點發光二極體亮度及效率 Improvement of Luminance and Efficiency of Quantum Dot Light Emitting Diodes by Doping and Inserting Thermally Activated Delayed Fluorescence Material |
| 指導教授: |
蘇炎坤
Su, Yan-Kuin |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 微電子工程研究所 Institute of Microelectronics Engineering |
| 論文出版年: | 2021 |
| 畢業學年度: | 109 |
| 語文別: | 英文 |
| 論文頁數: | 77 |
| 中文關鍵詞: | 熱活化延遲螢光材料 、福斯特能量共振轉移 、量子點發光二極體 |
| 外文關鍵詞: | CdSe/ZnS, thermally activated delayed fluorescence luminescent materials, Förster resonance energy transfer |
| 相關次數: | 點閱:194 下載:0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
量子點雖然在現今已被廣泛利用在各項產品,但是其效率仍然可以改善,故本篇
論文利用熱活化延遲螢光材料(DDczTrz)摻雜到 CdSe/ZnS 量子點發光層,以及插入一 層 DDczTrz 於電洞傳輸層及量子點發光層之間,緊接者,藉由福斯特能量共振轉移
將激子能量傳遞給量子點發光層,最後,探討在傳統結構以及在改善後的元件效率和 亮度,甚至提高光子生命週期。
由於電子以及電洞注入速率不平衡而導致電性不理想,故本研究透過熱活化延遲 螢光材料來改善量子點發光二極體。第一部分透過二次轉速得到較平滑發光層,以及
不同旋轉塗布的轉速來改變發光層厚度,更進一步使用預轉是否改變其特性,最後得 到最大亮度 164,216 cd/m2,最高電流效率為 6.99 cd/A 以及最高能量效率 2.94 lm/W。
第二部分利用 DDczTrz 摻雜不同濃度到量子點發光層,以摻雜 3wt% DDczTrz 為最佳 參數,此外,當摻雜濃度越高,其發光層表面粗造度隨之降低,由上述可知,DDczTrz
得摻雜可以填補量子點發光層之缺陷,而最大亮度及電流效率改善至 528,293 cd/m2
和 26.3 cd/A,對大能量效率則是 11.46 lm/W。然而,摻雜容易造成能量在轉移時過於 接近,故有可能產生所謂的能量碰撞。第三部分插入一層很薄的 DDczTrz 薄膜於電
洞傳輸層及發光層之間,並改變其膜厚厚度以提高能量轉移之效率,最終,得到本實 驗最佳電特性,其最大亮度為 784,843 cd/m2,最高電流效率為 29.65 cd/A,而最高能
量效率為 14.46 lm/W。
In these days, there are many quantum dot applications, yet the efficiency of quantum dot can still be improved. Besides, quantum dot materials usually are heavy metal. Using the thermally activated delayed fluorescence luminescent materials (DDczTrz) to dope into CdSe/ZnS quantum dot emission layer and inserting a DDczTrz film between the hole transport layer and the emission layer, then the excitons energy are transferred to quantum dot by Förster resonance energy transfer. Finally, discuss the efficiency and luminance of traditional structure and improved srtructure.Because injection rate of electron and hole are unbalanced, electrical characteristics does not meet the experiment. Therefore, using thermally activated delayed fluorescence luminescent materials to improve quantum dot light-emitting diodes in this study. First of all, the first part uses two-step EML and changes thickness of emission layers through different spinning rate; furthermore, use pre-rotation whether change the characteristics. Then, the maximum luminance reaches 164,216 cd/m2, and the maximum current efficiency and power efficiency reaches 6.99 cd/A and 2.94 lm/W, respectively.
The second part is using different concentration DDczTrz to dope into quantum dot emission layer, and the doping 3w% DDcztrz is the optimal parameter; on top of that, as doping concentration increase, the surface roughness of emission layers decrease. As mentioned above, it can fill up the defects of emission layer by doping DDczTrz. Its maximum luminance and maximum current efficiency are improved to 528,293 cd/m2 and 26.3 cd/A respectively, and the maximum power efficiency is 11.46 lm/W. Nevertheless, it easily causes to be too close when the energy is transferred; consequently, it possibly causes the so-called collision of energy.The third part is inserting a thin DDczTrz film between the hole transport layer and the emission layer, and changing the thickness to enhance the efficiency of energy transfer. Finally, the best electrical characteristics are achieved in this experiment. Then maximum luminance is 784.843 cd/m2, and the maximum current efficiency and power efficiency is 29.65 cd/A and 14.46 lm/W.
[1] M. S. Shur and R. Zukauskas, “Solid-State Lighting: Toward Superior Illumination,” Proc. IEEE, vol. 93, no. 10, pp. 1691–1703, Oct. 2005.
[2] F. Kish et al., “From Visible Light-Emitting Diodes to Large-Scale III–V Photonic Integrated Circuits,” Proc. IEEE, vol. 101, no. 10, pp. 2255–2270, Oct. 2013.
[3] S Kunić, Z Šego "OLED technology and displays. "Proceedings ELMAR-2012. IEEE, pp. 31-35, 2012.
[4] Tu, Ning. "Quantum Dot Light-Emitting Diode: Structure, Mechanism, and Preparation." Quantum Dots-Fundamental and Applications. IntechOpen, 2020.
[5] S. Shahnawaz, S. S. Sudheendran, M. R. Nagar, R. A. Yadav, S. Gull, D. K. Dubey, and J.-H. Jou, “Hole transporting materials for organic light emitting diodes: An Overview,” Journal of Materials Chemistry C, 2019.
[6] D. Vasudevan, R. R. Gaddam, A. Trinchi, and I. Cole, “Core–shell quantum dots: Properties and applications,” Journal of Alloys and Compounds, vol. 636, pp. 395–404, Jul. 2015.
[7] B. G. Kumar et al., “Structural control of InP/ZnS core/shell quantum dots enables high-quality white LEDs,” Nanotechnology, vol. 29, no. 34, p. 345605, Aug. 2018.
[8] A. AbouElhamd, K. Al-Sallal, and A. Hassan, “Review of Core/Shell Quantum Dots Technology Integrated into Building’s Glazing,” Energies, vol. 12, no. 6, p. 1058, Mar. 2019.
[9] D. Vasudevan, R. R. Gaddam, A. Trinchi, and I. Cole, “Core–shell quantum dots: Properties and applications,” Journal of Alloys and Compounds, vol. 636, pp. 395–404, Jul. 2015.
[10] VL. Colvin, CS. Michael, and A. Paul Alivisatos. "Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer. "Nature, vol. 370. no.6488, pp. 354-357, 1994.
[11] B. O. Dabbousi, M. G. Bawendi, O. Onitsuka, and M. F. Rubner, “Electroluminescence from CdSe quantum‐dot/polymer composites,” Appl. Phys. Lett., vol. 66, no. 11, pp. 1316–1318, Mar. 1995.
[12] Y. Sun, Y. Jiang, X. W. Sun, S. Zhang, and S. Chen, “Beyond OLED: Efficient Quantum Dot Light‐Emitting Diodes for Display and Lighting Application,” Chem. Rec., vol. 19, no. 8, pp. 1729–1752, Aug. 2019.
[13] S. Coe, W.-K. Woo, M. Bawendi, and V. Bulović, “Electroluminescence from single monolayers of nanocrystals in molecular organic devices,” Nature, vol. 420, no. 6917, pp. 800–803, Dec. 2002.
[14] R. H. Friend et al., “Electroluminescence in conjugated polymers,” Nature, vol. 397, no. 6715, pp. 121–128, Jan. 1999.
[15] P. E. Burrows, V. Bulovic, S. R. Forrest, L. S. Sapochak, D. M. McCarty, and M. E. Thompson, “Reliability and degradation of organic light emitting devices,” Appl. Phys. Lett., vol. 65, no. 23, pp. 2922–2924, Dec. 1994.
[16] J. M., Caruge, E. J. Halpert, and V. Wood. "V. Bulovi c, MG Bawendi." Nat. Photonics ,vol. 2, pp. 247, 2008.
[17] E. Sezer, “Conducting nanocomposite systems,” in The New Frontiers of Organic and Composite Nanotechnology, Elsevier, pp. 143–235, 2008.
[18] T. Jaseetharan, “ENHANCING THE PERFORMANCE OF PbS:Hg QUANTUM DOT - SENSITIZED SOLAR CELLS BY CONTROLLING THE SURFACE CHARGE OF TiO2 ELECTRODE,” Sri Lanka, p. 5, 2018.
[19] B. S. Mashford et al., “High-efficiency quantum-dot light-emitting devices with enhanced charge injection,” Nature Photon, vol. 7, no. 5, pp. 407–412, May 2013.
[20] J. Kwak et al., “Bright and Efficient Full-Color Colloidal Quantum Dot Light-Emitting Diodes Using an Inverted Device Structure,” Nano Lett., vol. 12, no. 5, pp. 2362–2366, May 2012.
[21] M. A. Cotta, “Quantum Dots and Their Applications: What Lies Ahead?,” ACS Appl. Nano Mater., vol. 3, no. 6, pp. 4920–4924, Jun. 2020.
[22] IG, Kaplan. The Pauli Exclusion Principle: Origin, Verifications, and Applications. John Wiley & Sons, 2017.
[23] A. Endo, M. Ogasawara, A. Takahashi, D. Yokoyama, Y. Kato, and C. Adachi, “Thermally Activated Delayed Fluorescence from Sn4+-Porphyrin Complexes and Their Application to Organic Light Emitting Diodes - A Novel Mechanism for Electroluminescence,” Adv. Mater., vol. 21, no. 47, pp. 4802–4806, Dec. 2009.
[24] Y. Shirasaki, G. J. Supran, M. G. Bawendi, and V. Bulović, “Emergence of colloidal quantum-dot light-emitting technologies,” Nature Photon, vol. 7, no. 1, pp. 13–23, Jan. 2013.
[25] Y. Shirasaki, G. J. Supran, M. G. Bawendi, and V. Bulović, “Emergence of colloidal quantum-dot light-emitting technologies,” Nature Photon, vol. 7, no. 1, pp. 13–23, Jan. 2013.
[26] Wong, Y. Michael, and Z.C. Eli. "Purely organic thermally activated delayed fluorescence materials for organic light‐emitting diodes." Advanced Materials, vol.29, no. 22, pp. 1605444, 2017.
[27] W. S. Jeon, T. J. Park, S. Y. Kim, R. Pode, J. Jang, and J. H. Kwon, “Ideal host and guest system in phosphorescent OLEDs,” Organic Electronics, vol. 10, no. 2, pp. 240–246, Apr. 2009.
[28] H. Yersin, ed. Highly efficient OLEDs with phosphorescent materials. Weinheim: Wiley-VCH, 2008.
[29] C. B. Murphy, Y. Zhang, T. Troxler, V. Ferry, J. J. Martin, and W. E. Jones, “Probing Förster and Dexter Energy-Transfer Mechanisms in Fluorescent Conjugated Polymer Chemosensors,” J. Phys. Chem. B, vol. 108, no. 5, pp. 1537–1543, Feb. 2004.
[30] S. Tang, J. Yao, J. Chen, and J. Luo, “Preparation of indium tin oxide (ITO) with a single-phase structure,” Journal of Materials Processing Technology, vol. 137, no. 1–3, pp. 82–85, Jun. 2003.
[31] M. Bender, W. Seelig, C. Daube, H. Frankenberger, B. Ocker, and J. Stollenwerk, “Dependence of film composition and thicknesses on optical and electrical properties of ITO–metal–ITO multilayers,” Thin Solid Films, vol. 326, no. 1–2, pp. 67–71, Aug. 1998.
[32] A. V. Volkov et al., “Understanding the Capacitance of PEDOT:PSS,” Adv. Funct. Mater., vol. 27, no. 28, p. 1700329, Jul. 2017.
[33] X. Zhu et al., “A study of optical properties enhancement in low-bandgap polymer solar cells with embedded PEDOT:PSS gratings,” Solar Energy Materials and Solar Cells, vol. 99, pp. 327–332, Apr. 2012.
[34] C. Schmitz et al., “Polymeric Light‐Emitting Diodes Based on Poly(p‐phenylene ethynylene), Poly(triphenyldiamine), and Spiroquinoxaline,” Adv. Funct. Mater., no. 1, p. 6, 2001.
[35] Y. Yin et al., “Electroluminescent properties of poly[N,N′-bis(4-butylphenyl)-N,N′-bis(phenyl)benzidine] doped with 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene,” Displays, vol. 38, pp. 32–37, Jul. 2015.
[36] H. Chen et al., “All-Solution-Processed Quantum Dot Light Emitting Diodes Based on Double Hole Transport Layers by Hot Spin-Coating with Highly Efficient and Low Turn-On Voltage,” ACS Appl. Mater. Interfaces, vol. 10, no. 34, pp. 29076–29082, Aug. 2018.
[37] Q. J. Sun, B. H. Fan, Z. A. Tan, C. H. Yang, Y. F. Li, and Y. Yang, “White light from polymer light-emitting diodes: Utilization of fluorenone defects and exciplex,” Appl. Phys. Lett., vol. 88, no. 16, p. 163510, Apr. 2006.
[38] J. Sohn, D. Ko, H. Lee, J. Han, S.-D. Lee, and C. Lee, “Degradation mechanism of blue thermally activated delayed fluorescent organic light-emitting diodes under electrical stress,” Organic Electronics, vol. 70, pp. 286–291, Jul. 2019.
[39] M. Kim, S. K. Jeon, S.-H. Hwang, and J. Y. Lee, “Stable Blue Thermally Activated Delayed Fluorescent Organic Light-Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light-Emitting Diodes,” Adv. Mater., vol. 27, no. 15, pp. 2515–2520, Apr. 2015.
[40] DY. Park, et al. "High efficiency quantum dot light-emitting diode by solution printing of zinc oxide nanoparticles." Journal of nanoscience and nanotechnology, vol. 20, no. 7, pp. 4454-4457, 2020.
[41] M. Kim, S. K. Jeon, S.-H. Hwang, and J. Y. Lee, “Stable Blue Thermally Activated Delayed Fluorescent Organic Light-Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light-Emitting Diodes,” Adv. Mater., vol. 27, no. 15, pp. 2515–2520, Apr. 2015.
[42] T. Nagata, S. Oh, T. Chikyow, and Y. Wakayama, “Effect of UV–ozone treatment on electrical properties of PEDOT:PSS film,” Organic Electronics, vol. 12, no. 2, pp. 279–284, Feb. 2011.
[43] X. Liu et al., “Boosting the efficiency of carbon-based planar CsPbBr3 perovskite solar cells by a modified multistep spin-coating technique and interface engineering,” Nano Energy, vol. 56, pp. 184–195, Feb. 2019.
[44] M. R. Ahmadian-Yazdi, F. Zabihi, M. Habibi, and M. Eslamian, “Effects of Process Parameters on the Characteristics of Mixed-Halide Perovskite Solar Cells Fabricated by One-Step and Two-Step Sequential Coating,” Nanoscale Res Lett, vol. 11, no. 1, p. 408, Dec. 2016.
[45] C.-Y. Han and H. Yang, “Development of Colloidal Quantum Dots for Electrically Driven Light-Emitting Devices,” J. Korean Ceram. Soc, vol. 54, no. 6, pp. 449–469, Nov. 2017.
[46] C.-Y. Han and H. Yang, “Development of Colloidal Quantum Dots for Electrically Driven Light-Emitting Devices,” J. Korean Ceram. Soc, vol. 54, no. 6, pp. 449–469, Nov. 2017.
[47] A. Kumar et al., “Effects of HTL and ETL Thicknesses on the Performance of PQT-12/PCDTBT:PC 61 BM/ZnO QDs Solar Cells,” IEEE Photon. Technol. Lett., vol. 32, no. 12, pp. 677–680, Jun. 2020.
[48] P. O. Anikeeva, C. F. Madigan, J. E. Halpert, M. G. Bawendi, and V. Bulović, “Electronic and excitonic processes in light-emitting devices based on organic materials and colloidal quantum dots,” Phys. Rev. B, vol. 78, no. 8, p. 085434, Aug. 2008.
[49] Y. Tang, G. Xie, X. Liang, Y.-X. Zheng, and C. Yang, “Organic and quantum-dot hybrid white LEDs using a narrow bandwidth blue TADF emitter,” J. Mater. Chem. C, vol. 8, no. 31, pp. 10831–10836, 2020.
[50] B.-H. Kang et al., “Enhanced Charge Transfer of QDs/Polymer Hybrid LED by Interface Controlling,” IEEE Electron Device Lett., vol. 34, no. 5, pp. 656–658, May 2013.
[51] H.-T. Vu, C.-C. Yang, B.-S. Nguyen, and Y.-K. Su, “Hybrid PVK: OXD-7: QDs Emitting Layer for High Color Purified Quantum Dot Light Emitting-Diode,” in 2018 4th International Conference on Green Technology and Sustainable Development (GTSD), Ho Chi Minh City, Vietnam, pp. 726–728, Nov. 2018.
[52] Y. R. Park, H. Y. Jeong, Y. S. Seo, W. K. Choi, and Y. J. Hong, “Quantum-Dot Light-Emitting Diodes with Nitrogen-Doped Carbon Nanodot Hole Transport and Electronic Energy Transfer Layer,” Sci Rep, vol. 7, no. 1, p. 46422, Jun. 2017.
[53] W. Zheng et al., “All-solution processed inverted QLEDs with double hole transport layers and thermal activated delay fluorescent dopant as energy transfer medium,” Organic Electronics, vol. 77, p. 105544, Feb. 2020.
[54] Y.-N. Zhang, Y.-S. Liu, M.-M. Yan, Y. Wei, Q.-L. Zhang, and Y. Zhang, “Efficient Quantum-Dot Light-Emitting Diodes Employing Thermally Activated Delayed Fluorescence Emitters as Exciton Harvesters,” ACS Appl. Mater. Interfaces, vol. 10, no. 8, pp. 7435–7441, Feb. 2018.
[55] W. Zheng et al., “Enhancing the efficiency and the luminance of quantum dot light-emitting diodes by inserting a leaked electron harvesting layer with thermal-activated delayed fluorescence material,” Organic Electronics, vol. 65, pp. 357–362, Feb. 2019.
[56] Q. Lin et al., “Cadmium-free quantum dots based violet light-emitting diodes: High-efficiency and brightness via optimization of organic hole transport layers,” Organic Electronics, vol. 25, pp. 178–183, Oct. 2015.
[57] P. Wei, D. Zhang, and L. Duan, “Modulation of Förster and Dexter Interactions in Single‐Emissive‐Layer All‐Fluorescent WOLEDs for Improved Efficiency and Extended Lifetime,” Adv. Funct. Mater., vol. 30, no. 6, p. 1907083, Feb. 2020.
[58] T. Hosokai, H. Nakanotani, S. Santou, H. Noda, Y. Nakayama, and C. Adachi, “TADF activation by solvent freezing: The role of nonradiative triplet decay and spin-orbit coupling in carbazole benzonitrile derivatives,” Synthetic Metals, vol. 252, pp. 62–68, Jun. 2019.