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研究生: 徐崇益
Hsu, Chung-Yi
論文名稱: 探討Alq3蒸鍍條件對光電特性之影響
Opto-Electrical Characteristics of Alq3 Deposited by Thermal Evaporation
指導教授: 黃守仁
Whang, Thou-Jen
蘇炎坤
Su, Yan-Kuin
學位類別: 碩士
Master
系所名稱: 理學院 - 化學系碩士在職專班
Department of Chemistry (on the job class)
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 138
中文關鍵詞: 電子傳送層有機發光二極體
外文關鍵詞: Alq3, OLED, ETL
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  • 光激發光會產生消弭現象,是受環境參數所影響,當用來表現材料 Alq3 [ Tris ( 8-hydroxy quinoline ) aluminum ( Ⅲ ) ] 特性時,更能呈現材料的特徵性能。利用單一材料鍍層去獲得光激發光對參數變異,例如;承載基板、鍍層厚度、時間因素以及氧化受潮環境差異下之影響。
    本實驗主要目的,在於因實驗環境影響之考量,需在材料特性以及蒸鍍條件變異時,探討鍍層薄膜的均勻性和分子排列堆疊方式,對元件光電效能影響做一探討。
    製作單異質界面雙層結構元件,因蒸鍍參數變異之由,使得元件之電特性產生變化而加以探究,參數設定在可進行蒸鍍之真空下,當電洞傳送層 NPB 材料厚度 400 Å 、電子傳送層 Alq3 材料厚度 300 Å 之組合,蒸鍍速率控制在 ~2 Å/s 以及鍍層界面加溫控制在 60℃ ,時間 20 min 所製成之元件,有較佳的電特性效果顯現。

    Photoluminescence quenching of Alq3 [Tris ( 8-hydroxy quinoline ) aluminum (Ⅲ)] is seriously affected by many parameters including substrate material, layer thickness, storage time, and humidity et al. In this study, we have demonstrated device performance affected by film uniformity, atomic arrangement, material characteristics, and evaporation parameters. The optimal evaporation rate is 2 Å/s, and substrate heated at 60°C for 20 min when interface between deposited layers, and the thickness of NPB layer and Alq3 layer in the single hetero-junction device are 400 Å and 300 Å respectively.

    中文摘要…………………………………………………….Ⅰ 英文摘要………………………………………………….…Ⅱ 目錄………………………………………………………….Ⅲ 圖目錄……………………………………………………….Ⅶ 表目錄…………………………………...……………..ⅩⅠ 第一章 緒論………………………………………………….1 1-1 前言………………………………………………………1 1-2 Alq3材料里程碑…………………………………………1 1-3進行本實驗之動機……………………………………….5 第二章 理論………………………………………………….8 2-1 激發光…………………………………………………..8 2-2 放射螢光……………………………………………….10 2-3 比爾定律.………………………………………………13 2-4 選擇律定則…………………………………………….13 2-5 法蘭克 - 康登原理……………………………………14 2-6 電子能態間的躍遷過程……………………………….16 2-7 蕭基能障……………………………………………….17 2-8 電激發光……………………………………………….19 2-9 能量轉移……………………………………………….21 2-10消弭機制……………………………………………….26 第三章 實驗…………………………………………………28 3-1材料介紹………………………………………………..28 3-1-1電子傳送層: Alq3…………………………………..28 3-1-2電洞傳送層: NPB…………………………………….36 3-1-3導電玻璃………………………………………………39 3-1-4金屬電極………………………………………………40 3-1-5基板…………………………………………………..41 3-2實驗裝置……………………………………………....43 3-2-1有機真空蒸鍍系統……………………………………43 3-2-2紫外光可見光吸收光譜儀……………………………47 3-2-3光激發光光譜儀………………………………………50 3-2-4光學顯微鏡……………………………………………52 3-2-5功率計…………………………………………………54 3-2-6半導體參數分析儀…..………………………………54 3-3實驗方法……………………………..……………………….....55 3-3-1單層材料薄膜時之濃度消弭效應……………………55 3-3-2製作元件時之參數變因……………………………..56 3-4 實驗步驟……………………………………………….58 3-4-1單層薄膜製作…………………………………………58 3-4-2元件製作………………………………………………61 第四章 結果與討論…………………………………………66 4-1 實驗確認……………………………………………….66 4-1-1有機材料品質………………………………………..66 4-1-2有機蒸著機蒸鍍元件參數確認…………………....66 4-1-3有機材料 Alq3 在溶劑內之濃度效應………………67 4-2光激發光效能……………………………………………70 4-2-1 Alq3 光激發光檢測………………………………70 4-2-2光激發光受塑膠基板之影響………………………72 4-2-3光激發光受玻璃基板之影響…………………………76 4-2-4基板差異對光激發光放光強度之影響…………..81 4-2-5環境變異對光激發光放光強度之影響……………86 4-2-6鍍層表面裂解情況………………………………90 4-3元件電特性………………………………………………91 4-3-1單層(有機材料Alq3)元件受參數變異之電阻特性91 4-3-2元件受速率參數變異之電特性……………………95 4-3-3元件受厚度參數變異之電特性……………………97 4-3-3-1電子傳送層 Alq3 鍍層厚度參數變異…........97 4-3-3-2電子及電洞傳送層兩鍍層厚度參數變異.......103 4-3-4元件受基板溫度參數變異之電特性……………….104 4-3-5元件受環境曝露參數變異之電特性……….106 4-3-6元件表面裂解情況………………………………….108 第五章 結論……………………………………………….110 參考文獻……………………………………………………115 附錄…………………………………………………………119 自述…………………………………………………………125

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