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研究生: 邱柏源
Chiou, Bo-Yuan
論文名稱: 在不同參數下以方向性凝固製備鋁銅合金對其凝固結構之影響分析
Experimental Analysis of Control-Parameter Effects on the Microstructures of Directionally Solidfied Aluminum-Copper Alloys
指導教授: 趙隆山
Chao, Long-Sun
學位類別: 碩士
Master
系所名稱: 工學院 - 工程科學系
Department of Engineering Science
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 155
中文關鍵詞: 方向性凝固鋁銅合金金相組織
外文關鍵詞: directional solidification, aluminum-copper alloy, metallographic organization
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  • 凝固是指在溫度降低時,物質由液態轉變成固態之過程。而在凝固過程中,會因為不同之濃度、溫度與冷卻條件等控制參數,會形成不同的巨觀及微觀結構以及決定各項之物理性質與化學性質,並可以運用在各種領域當中。
    方向性凝固,又稱為定向凝固,使金屬材料利用人為控制融熔金屬的結晶成長方向,得到結晶方向相近的柱狀晶,並更進一步獲得單晶結構的凝固方法。
    本研究是以方向性凝固製備鋁銅合金,使用不同濃度之鋁銅合金(91.5wt.%Al-6wt.%Cu-0.6wt.%Bi-0.7wt.%Fe)、(90wt.%Al-5wt.%Cu-1.2wt.%Mn-1.2wt.%Si-0.8wt.%Mg-0.7wt.%Fe)以及(91wt.%Al-4wt.%Cu-2wt.%Mg-1wt.%Mn-0.5wt.%Si-0.5wt.%Fe)作為研究材料。透過不同的控制參數實驗出九種不同之實驗組別,分析巨觀及微觀金相組織、冷卻曲線、溫度梯度、成長速率、晶粒尺寸及硬度值等。

    Solidification is a process in which a substance changes from a liquid state to a solid state when the temperature drops. In the solidification process, different control parameters such as concentration, temperature and cooling conditions will result in different macroscopic and microscopic structures and determine various physical and chemical properties, which can be applied in various fields.

    Directional solidification, also known as directional solidification, is a method of solidification in which the crystallization direction of the molten metal is artificially controlled to obtain columnar crystals with similar crystallization direction and further single crystal structure.

    In this study, Al-Cu alloys were prepared by directional solidification using different concentrations of Al-Cu alloys (91.5wt.%Al-6wt.%Cu-0.6wt.%Bi-0.7wt.%Fe), (90wt.%Al-5wt.%Cu-1.2wt.%Mn-1.2wt.%Si-0.8wt.%Mg-0.7wt.%Fe)and( 91wt.%Al-4wt.%Cu-2wt.%Mg-1wt.%Mn-0.5wt.%Si-0.5wt.%Fe) were used as study materials. Nine different experimental groups were experimented with different control parameters to analyze the macroscopic and microscopic metallographic organization, cooling curves, temperature gradient, growth rate, grain size and hardness values.

    摘要 I ABSTRACT II 目錄 XVIII 表目錄 XXI 圖目錄 XXIII 第一章 緒論 1 1-1研究動機 1 1-2文獻回顧 4 1-2-1方向性凝固 4 第二章 凝固理論模式 10 2-1凝固過程 11 2-1-1成核階段(Nucleation) 12 2-1-2晶粒成長與侵犯階段(Growth and Impingement) 15 2-1-3晶粒成長型態 16 2-2方向性凝固模式 19 第三章 實驗設備與方法 29 3-1實驗設備 29 3-1-1鑄件外模 29 3-1-2方向性凝固載台 30 3-1-3熔解爐 30 3-1-4冷激銅盒 30 3-1-5恆溫循環水槽 31 3-1-6液態氮桶 31 3-1-7空氣壓縮機 32 3-1-8溫度擷取裝置 32 3-1-9熱電偶 32 3-1-10點焊機 32 3-1-11研磨拋光機 33 3-1-12研磨水砂紙 33 3-1-13拋光絨布 33 3-1-14拋光液 34 3-1-15氫氟酸及標準作業流程 34 3-1-16光學顯微鏡 36 3-2實驗模式 36 3-2-1方向性凝固之實驗模式 36 3-3鑄件之材料分析 40 3-3-1金相處理之實驗設備 40 3-3-2巨觀金相組織觀察 41 3-3-3微觀金相組織觀察 44 3-3-4光學顯微鏡之金相觀察 45 3-3-5材料之機械性質 45 3-3-6實驗數據整理與計算 47 第四章 結果與討論 73 4-1方向性凝固實驗與結果 73 4 -1-1暫態溫度量測 74 4-1-1-1冷卻曲線之分析 74 4-1-1-2成長速率 75 4-1-1-3溫度梯度 77 4-1-1-4 G/V值與G∙V值 77 4-2金相組織 78 4-3材料機械性質 83 第五章 結論 151 5-1結論 151 參考文獻 153

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