本論文利用低壓抽氣沉積法及乾膜轉印法製備硫醇化奈米銀線 (Thiolation silver nanowires)和奈米碳管 (Carbon nanotubes) 之奈米複合三層導電膜拉伸彈性電極材料。不同於以往文獻研究的單層導電膜或奈米複合導電膜材料，藉由結合奈米銀線的良好導電性及奈米碳管的優異機械性質，製作出奈米複合三層導電膜，以改良可拉伸彈性電極之性質。
在製作奈米複合三層導電膜前，首先將奈米銀線與苯甲基硫醇 (Benzyl mercaptan) 在溶液中進行混摻，使奈米銀線與硫醇官能基產生 硫-銀鍵結，即為硫醇化奈米銀線；接著加入奈米碳管，使得苯甲基硫醇化奈米銀線上的苯環分子與奈米碳管表面產生π-π堆疊作用力。期望能夠改善奈米銀線間的接觸並幫助奈米銀線與奈米碳管間之接著，且製作而成的三層導電膜拉伸彈性電極 (CNT/S-AgNW/CNT) 能夠在經過高拉伸率、多次拉伸及彎曲形變疲勞測試下，有效穩定R/R0電阻值的變化。
將硫醇化前後之三層CNT/AgNW/CNT導電膜與單層奈米銀線、奈米碳管導電膜拉伸彈性電極進行一系列電性量測、電子顯微鏡表面觀察及5,000次以上的拉伸、彎曲疲勞度測試，相較於硫醇化前的三層導電膜電極和單層導電膜電極皆大於10% 的R/R0變化量，CNT/S-AgNW/CNT之最大R/R0變化量僅3% 左右，表示硫醇化奈米銀線與奈米碳管之三層導電膜材料，經過多次形變後確實能夠有效穩定R/R0電阻值的變化；而在電子顯微鏡觀察下，電極表面會產生波浪狀結構，能夠抵銷拉伸過程中所帶來的長度變化。

In this work, stretchable nanocomposite electrodes were successfully fabricated by vacuum evacuation and transferring to PDMS. These electrodes consisted of silver nanowires (AgNW) and carbon nanotubes (CNTs), which could enhance mechanical compliance and electrical conductivity under deformation. They also have excellent properties such as flexibility, stretchability, and bending. The results show that, conductivity is improved when containing more AgNW, although this would lead to increasing resistance change (R/R0). However, adding CNT could help to stabilize R/R0 after repeat stretch-recovery treatment. Before modification, the best nanocomposite electrode was CNT/AgNW/CNT. The R/R0 increased 87% under 0%-60% strain after 10,000 repeat stretch-recovery treatment. In order to decrease R/R0 after treatment, AgNW was thiolated by benzyl mercaptan to form the S-Ag bonding and π-π stacking reaction between CNT/S-AgNW. After 10,000 stretch-recovery treatment, the R/R0 of CNT/S-AgNW/CNT electrode increased by only 3%. This is because benzyl mercaptan is a kind of coupling molecule that helps the CNT and AgNW structure to arrange more closely. As a result, we observed the formation of buckles instead of cracks by SEM, which help to stabilize resistance during long-term stretch-recovery treatment.

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