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研究生： 湯琬容
Tang, Wang-Rung
論文名稱： 聚苯胺-聚(磺酸苯乙烯)複合物之特性與應用
Characterization and application of polyaniline-poly(styrene sulfonic acid) composite
指導教授： 溫添進
Wen, Ten-Chin
學位類別： 碩士
Master
系所名稱： 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年： 2007
畢業學年度： 95
語文別： 中文
論文頁數： 84
中文關鍵詞： 聚(磺酸苯乙烯) 、聚苯胺
外文關鍵詞： poly(styrene sulfonic acid), polyaniline
相關次數： 點閱：122  下載：1 
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    • 論文第一部份主要是探討聚苯胺摻雜聚(磺酸苯乙烯)之特性研究，利用電化學定電位法聚合聚苯胺，將聚苯胺浸泡於氨水溶液呈去摻雜態，再浸泡於聚(磺酸苯乙烯)，製備成聚苯胺-聚(磺酸苯乙烯)複合薄膜，由紫外光-可見光光譜圖鑑定高分子的結構型態，掃描式電子顯微鏡觀測發現，複合物有較佳附著性的三維網狀結構，並由歐傑電子光譜的深度分析瞭解聚(磺酸苯乙烯)提供大量且均勻分散的磺酸基團於聚苯胺內。循環伏安圖和化學分析電子光譜儀測試，複合物的電荷傳遞偏向表面控制，並且複合物比聚苯胺有較佳電化學活性和較高的掺雜度和較少的裂解產物。
    論文第二部份是探討聚苯胺摻雜聚(磺酸苯乙烯)之pH效應與沉積白金觸媒之甲醇催化能力研究。經由電化學交流阻抗分析和即時紫外光-可見光光譜的分析，聚苯胺-聚(磺酸苯乙烯)複合薄膜於pH=5.7的硫酸鈉溶液下仍然有很好的電化學活性，電荷轉移電阻為聚苯胺的1/45倍。利用電化學定電位法，將白金沉積於聚苯胺-聚(磺酸苯乙烯)複合物內，由能量分散式光譜儀和歐傑電子光譜的深度分析證實，白金是均勻的分散在三維網狀結構內。利用循環伏安掃描來測試觸媒的催化能力，聚苯胺-聚(磺酸苯乙烯)-白金的甲醇氧化活性為聚苯胺-白金的3倍。定電流法測試瞭解甲醇催化的穩定性和CO中毒效應，結果顯示白金於複合物下有較佳的穩定性。

    Polyaniline (PANI) was doped with poly(styrene sulfonic acid) (PSS) via doping-dedoping-redoping process, and polyaniline synthesized by electrochemically costant potential method. The characterization of pani-pss was studied UV-Visible spectroscopy, Scanning electron microscopy photographs and the depth profiles of auger electron spectroscopy reveal uniformly distribution of SO3H groups in the spatial network structure of PANI-PSS composite. By cyclic voltammetry and X-ray photoelectron spectroscopy, PANI-PSS composite was tended to surface bound transport processes and had higher electrochemical activity, higher doping level and lower degradation products then PANI.
    We empolyed in-situ UV-Visible spectroscopy and electrochemical impedance spectroscopy to study the redox activity and polarization. PANI-PSS composite reveals an excellent electro-redox activity in 0.5M Na2SO4 solution, and the pH of solution is 5.7. The charge transfer resistance of PANI-PSS composite is 1/45 times lower then that of PANI. Platinum was potentiostatically deposited in PANI-PSS composite. The uniformly distribution of platinum evidenced by scanning electron microscopy photographs electron dispersive element analysis and the depth profiles of auger electron spectroscopy. Cyclic voltammograms demonstrated the performance of PANI-Pt and PANI-PSS-Pt in the electrooxidation of methanol, and the electrocatalytic activity of methanol oxidation for PANI-PSS-Pt was three times larger than that for PANI-Pt. The stability and CO poison effect in the electrooxidation of methanol can be evaluated from the chronopotentiometric response, and the stability of PANI-PSS-Pt was well than PANI-Pt.

    中 文 摘 要……………………………………………..I 英 文 摘 要………………………………………….…II 致謝…………………………………………..……III 目錄……………………………………………………….IV 圖目錄………………………………………...…….VII 表目錄……………………………………......…….X 第一章 緒論…………………………………….……1 1-1 聚苯胺...…………………………………………………………………………1 1-1-1 聚苯胺之簡介……………………………………………………...……1 1-1-2 聚苯胺之合成與聚合機制………………………………………...……3 1-1-3 聚苯胺之摻雜……………………………………………………...……5 1-1-4 聚苯胺之電化學行為……………………………………………...……6 1-2 聚苯胺衍生物與複合物…………………………………………………………8 1-2-1 磺上取代聚苯胺衍生物…………………………………………...……8 1-2-2 氮上取代聚苯胺衍生物…………..……………………………….……9 1-2-3 磺酸化聚苯胺…………………………………………………….……10 1-2-4 苯胺共聚物……………………………………………………….……10 1-2-5 聚苯胺複合物…………………………………………………….……11 1-2-6聚苯胺/高分子酸複合物………………………………………….……12 1-3 聚苯胺應用…………..…………………………………………………………13 1-3-1 修飾電極………………………………………………………….……13 1-3-1-1 感測材料…………………………………………………....……14 1-3-1-2 甲醇燃料電池陽極觸媒..…………………………….…….……15 1-3-2 可充式固態電池…………..……..……………………………….……16 1-3-3 電變色元件……………………………………………………….……17 1-3-4 有機發光二極體(OLED)……………………...………………….……18 1-4 研究動機…….…………………………………………….……………………19 1-4-1聚苯胺摻雜聚(磺酸苯乙烯)之特性研究……...………………….……19 1-4-2聚苯胺摻雜聚(磺酸苯乙烯)之pH效應與沉積白金觸媒之甲醇催化能力研究……………………………………………………..……………19 第二章 聚苯胺摻雜聚(磺酸苯乙烯)之特性研究…………30 2-1 前言………………………………………………………….…………….……30 2-2 實驗部分…………………………………………………….…………….……31 2-2-1 藥品與裝置……………………………………………………….……31 2-2-2 聚苯胺-聚(磺酸苯乙烯)之製備………………………………….……31 2-2-3 紫外光/可見光光譜……………………………………………....……31 2-2-4 電化學分析………………………………………….…………………32 2-2-5 表面型態………………………………………………………….……32 2-2-6 歐傑電子光譜…………………………………………………….……32 2-2-7 化學分析電子光譜……………………………………………….……32 2-3 結果與討論……………………………………………………………….…….33 2-3-1 紫外光/可見光光譜…...………………………………………….……33 2-3-2 電化學特性……………………………………………………….……33 2-3-3 高分子表面型態………………………………………………….……35 2-3-4 聚(磺酸苯乙烯)分佈探討………......………………………………….35 2-3-4 結構分析…………….….…………..…………………………….……35 2-4 結論………………………………………………………………………..……37 第三章 聚苯胺摻雜聚(磺酸苯乙烯)之pH效應與沉積白金觸媒之甲醇催化能力研究…………………………………………………………49 3-1 前言………………………………………………………………………..……49 3-2 實驗部分…………………………………………………………………..……51 3-2-1 藥品與裝置……………………………………………………….……51 3-2-2聚苯胺-聚(磺酸苯乙烯)與聚苯胺-聚(磺酸苯乙烯)-白金之製 備…………………………...………….……51 3-2-3 交流阻抗分析…………………………………………………….……52 3-2-4 光譜電化學……………………………………………………….……52 3-2-5 材料分析………………………………………………………….……53 3-2-6 甲醇氧化測試……….……...…………………………………….……53 3-3 結果與討論………………………….………………………………………….53 3-3-1 pH效應……..…………………………...……………………….……53 3-3-1-1 電化學分析………………………….…………………….……53 3-3-1-2 交流阻抗分析……………………….…………………….……54 3-3-1-3 光譜電化學………………………….………………….....……56 3-3-2甲醇氧化之研究….……………………………….…………………….57 3-3-1-1聚苯胺-聚(磺酸苯乙烯)-白金之材料分析…….………….……57 3-3-1-2 甲醇催化能力探討.……………………………………….……59 3-3-1-3甲醇溶液下穩定度測試..………………………………….……60 3-4 結論………………………………………………………………………..……61 第四章 總結與建議…………………………..……72 4-1 總結…………………………………………………………………….…….72 4-2 未來工作建議………………………………………………………….…….73 參考文獻………………………………………….…….75 著作…………………………………………………..……83 自述………………………………………………..……84

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