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研究生: 賴暄澔
Lai, Hsuan-Hao
論文名稱: 含鎂添加之SS400低碳鋼中介在物之高溫臨場研究
In-situ Study of Inclusions Behavior in SS400 with Magnesium Addition at High Temperature
指導教授: 郭瑞昭
Kuo, Jui-Chao
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 139
中文關鍵詞: 低碳鋼鎂含量高溫共軛焦雷射顯微鏡介在物釘紮力晶界遷移率
外文關鍵詞: Low carbon steel, Magnesium content, High temperature confocal laser scanning microscope, Pinning effect, Grain growth mobility
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  • 添加鎂於低碳鋼SS400中,所形成之介在物可有效抑止沃斯田鐵晶粒成長,本研究探討介在物在高溫下對沃斯田鐵晶界釘紮之效力,藉由高溫共軛焦雷射掃描顯微鏡臨場觀察並研究高溫下介在物與晶界間之交互作用。
    針對SS400鋼中介在物進行EDS成分分析,並藉由EBSD菊池線鑑定介在物結構,結果發現複合型介在物比例較非複合型高,並透過Factsage模擬介在物之生成過程。另外根據SEM的結果,MgO或MgO∙Al2O3通常位於中心,而MnS通常在外側,推測MnS會於MgO或MgO∙Al2O3介在物上異質成核。
    本實驗使用高溫共軛焦雷射掃描顯微鏡將試片持溫於1250℃,持溫時間10分鐘,透過即時影像計算單位時間內晶界移動量、沃斯田鐵晶粒尺寸等數值,求得晶粒成長速率、晶粒成長驅動力及晶界遷移率。最後藉由比較晶界遷移率得知MgO介在物釘紮力最佳,MgO∙Al2O3-MnS次之,MgO-MnS第三,MnS最差。

    The formation of inclusion in low carbon steel SS400 with Magnesium addition can inhibit austenite grain growth efficiently. In this study, we discussed the pinning effect on austenite grain boundary by inclusions at high temperature.
    The chemical composition of inclusions was analyzed by SEM-EDS, and then, the identification of inclusions by Kikuchi pattern was obtained by EBSD. And with the help of high temperature confocal laser scanning microscope(HT-CLSM), we investigated and observed the in-situ interaction process between grain boundary and inclusions.
    Grain growth velocity, grain growth driving force, and grain growth mobility were calculated by in-situ images. Finally, the grain growth mobility of inclusions was compared. By calculating grain growth mobility, it was found that MgO has the best pinning effect on grain growth, MgO∙Al2O3 is second, MgO-MnS complex is third, and MnS is the worst.

    中文摘要 I Extended Abstract II 致謝 XVI 目錄 XVII 表目錄 XXI 圖目錄 XXIII 第一章 前言 1 第二章 文獻回顧 3 2.1 氧化物冶金法 3 2.1.1 氧化物冶金法之演進 6 2.1.2 鋼中介在物之形成 10 2.1.2.1 介在物之簡介 10 2.1.2.2 介在物之種類 11 2.1.3 鎂氧化物冶金法 13 2.1.3.1 鎂之冶金性能 13 2.1.3.2 含鎂介在物之形成與變質效果 14 2.2 沃斯田鐵晶粒成長速率公式 20 2.2.1 晶粒成長速率之推導 20 2.2.2 晶粒成長公式之修正 25 2.3 抑制晶粒成長之效應 29 2.3.1 介在物釘紮力 29 2.3.2 溶質拉曳力 32 第三章 材料與實驗方法 35 3.1 實驗材料 35 3.2 介在物分析 37 3.2.1介在物成分分析 37 3.2.2 介在物結構分析 38 3.2.3 熱力學介在物模擬方法 39 3.3 介在物統計分析 42 3.3.1 介在物統計方法 42 3.4 介在物釘紮現象 45 3.4.1 高溫共軛焦雷射掃描顯微鏡熱處理實驗 45 3.4.2 晶粒成長驅動力之計算 49 3.4.2.1 沃斯田鐵晶界驅動力之計算方法 49 3.4.2.2 介在物釘紮力之計算方法 52 3.4.3 晶界遷移率之計算方法 54 第四章 實驗結果 56 4.1介在物成分及結構分析 56 4.1.1 介在物之成分及結構分析 56 4.1.2介在物之微觀結構 69 4.1.3 熱力學介在物模擬結果 75 4.2 介在物之統計分析 79 4.2.1 介在物統計結果 79 4.2.2 介在物粒徑尺寸分佈 82 4.3 介在物釘紮力之計算結果 89 4.3.1 高溫下介在物釘紮力之計算結果 95 第五章 討論 119 5.1 複合型介在物之形成 119 5.2 介在物對晶界遷移率之影響 125 第六章 結論 131 第七章 參考文獻 132

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