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研究生: 吳浩文
Wu, Hao-Wen
論文名稱: 水熱法製備奈米結構氧化亞銅(Cu2O)及其相關應用
Fabrication and Applications of Nanostructured Cuprite (Cu2O) Using a Two-Step Hydrothermal Method
指導教授: 張高碩
Chang, Kao-Shuo
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2014
畢業學年度: 102
語文別: 英文
論文頁數: 57
中文關鍵詞: 氧化亞銅水熱法光觸媒光電流壓力相關性質
外文關鍵詞: Cu2O nanorods, two-step hydrothermal synthesis, photocatalysis, photoelectrochemical cell, piezo-related property
相關次數: 點閱:112下載:8
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  • 本研究論文成功地使用兩步驟的水熱法成長出奈米柱狀結構之氧化亞銅(Cu2O),並藉由通入氮氣以獲得更高純度之氧化亞銅。利用XRD、SEM、TEM、UV-VIS測量其相組成、形貌、結晶取向及能隙。
    我們也發現奈米柱狀氧化亞銅具有不同的應用並且量測其性質,包含:光觸媒、壓電特性、光電化學活性。通入30分鐘氮氣的試片具有最佳之光觸媒活性,因其氧化亞銅之純度最高。電流-電壓的量測也顯示氧化亞銅具有壓電性質:當施加越大的壓力,氧化亞銅的電流密度越高,此外,在相同壓力下,當照射可見光時,其電流密度也會提高。並發現壓光效應也可增加光觸媒活性。利用光電流來進行可靠度的測試,並顯示其強度約為3μA/cm2。

    In this study, Cu2O nanorods were successfully fabricated using a two-step hydrothermal method. In addition, a N2 purging process was used to purify the content of Cu2O. The XRD, SEM, TEM, and UV-VIS characterization tools were applied to check the phases, morphologies, crystallinity, and band gap of Cu2O nanorods, respectively.
    We found Cu2O nanorods can be applied to various promising applications, including photocatalysis, piezoresistive effects, and photoelectrochemical (PEC) activities. The sample after 30 mins N2 purging showed the best photodegradation efficiency because the highest purity of Cu2O was obtained, which exhibited the property of a direct energy band gap. The I-V characteristics showed the higher current density under higher pressures, indicating the piezoresistive effect. When a visible light was irradiated, the photo-induced piezoresistive effect was observed, which enhanced the photodegradation efficiency. The photocurrent of Cu2O nanorods was measured using a three-electrode configuration of a photoelectrochemical cell. Approximately 3μA/cm2 was observed and the signals were steady after the test of three runs and 8 cycles for each run.

    摘要 I Abstract II 致謝 III Contents V Table content VII Figure Content VIII Chapter 1 Introduction 1 1.1 Motivation 1 1.2 Background 1 1.2.1 Energy and environment 1 1.2.2 Solar energy 2 1.2.2.1 Heating 2 1.2.2.2 Electricity 3 1.2.2.3 Chemical Process 3 1.3 Photocatalysis 4 1.4 Popular photocatalytic materials 4 1.4.1 Literature review of fabrication methods 5 1.5 Cu2O nanowires as a photocatalyst 6 1.5.1 Crystal structures and properties of Cu2O 6 1.5.2 Applications of Cu2O 7 1.5.2.1 Photocatalytic applications 7 1.5.2.2 Photoelectrochemical applications 8 1.5.3 Nanostructures of Cu2O 10 1.5.4 Synthetic methods of Cu2O 11 1.5.4.1 Literature review 11 1.6 Hydrothermal method 14 1.6.1 Fundamental overview of hydrothermal synthesis 14 1.6.2 The advantages of hydrothermal process 14 1.6.3 Multi-step Hydrothermal method 15 1.6.4 Nitrogen purging 15 1.7 Research objectives 15 Chapter 2 Experimental methods 17 2.1. Materials 17 2.1.1. Precursor solution 17 2.1.2. Complex agents 17 2.1.3. Cleaning chemicals 17 2.1.4. Targeted pollutant 17 2.1.5. Substrate 17 2.2. Manufacturing processes 18 2.2.1. Substrate preparation 18 2.2.2. First step of the hydrothermal reaction: a seed layer growth 18 2.2.3. Second step of the hydrothermal reaction: morphology control 18 2.2.4 Photocatalytic study 20 2.3 Characterizations 21 2.3.1 X-ray Diffraction (XRD) 21 2.3.2 Scanning Electron Microscopy (SEM) 23 2.3.3. Transmission Electron Microscopy (TEM) 24 2.3.4 Optical measurement (band gap analysis) 24 2.3.5 Photodegradation measurement 25 2.3.6 Piezoresistance measurement 26 2.3.7 Photoelectrochemical (PEC) current measurement 28 Chapter 3 Results and discussion 30 3.1 Composition and morphology analysis 30 3.1.1 Choices of Complex agents 30 3.1.2 PVA as complex agent 30 3.1.3 Two-step hydrothermal synthesis 31 3.1.3.1 First-step: seed layer growth 31 3.1.3.2 Second-step: Cu2O nanostructure growth 32 3.1.3.3 Nitrogen purging 34 3.2 Analysis of Microstructures and Phases Using TEM 35 3.3 Optical properties of Cu2O nanorods 37 3.4 Applications 38 3.4.1 Piezoresistive performance 38 3.4.2 Photocatalytic property 39 3.4.3 Piezoresistive effect enhanced photocatalysis 42 3.4.4 Photocurrent 43 Chapter 4 Conclusions and future work 45 4.1 Conclusions 45 4.2 Future works 47 References 48

    1. John P. Barton and David G. Infield, “Energy Storage and Its Use With Intermittent Renewable Energy,” IEEE transactions on energy conversion, 19(2): pp. 441-448, 2004.
    2. Nick Johnstone, Ivan Hašcic and David Popp, “Renewable Energy Policies and Technological Innovation: Evidence Based on Patent Counts,” Environmental and Resource Economics, 45(1): pp. 133-155, 2009.
    3. Nathan S. Lewis and Daniel G. Nocera, “Powering the planet: Chemical challenges in solar energy utilization,” Proceedings of the National Academy of Sciences, 103: pp. 15729-15735, 2006.
    4. Junqiang Xia, Roger A. Falconer and Binliang Lin, “Impact of different tidal renewable energy projects on the hydrodynamic processes in the Severn Estuary, UK,” Ocean Modelling, 32(1-2): pp. 86-104, 2010.
    5. Margaret Kadiri, Reza Ahmadian, Bettina Bockelmann-Evans, William Rauen and Roger Falconer, “A review of the potential water quality impacts of tidal renewable energy systems,” Renewable and Sustainable Energy Reviews, 16(1): pp. 329-341, 2012.
    6. Christopher Koronos, Thomas Spachos and Nikolaos Moussiopoulos, “Exergy analysis of renewable energy sources,” Renewable Energy, 28: pp. 295-310, 2003.
    7. Christopher B. Field, J. Elliott Campbell and David B. Lobell, “Biomass energy: the scale of the potential resource,” Trends in Ecology and Evolution, 23: pp. 65-72, 2007.
    8. George W. Crabtree and Nathan S. Lewis, “Solar Energy Conversion,” Physics Today, 60(37-42): pp. 309-321, 2007.
    9. W. Saman, F. Bruno and E. Halawa, “Thermal performance of PCM thermal storage unit for a roof integrated solar heating system,” Solar Energy, 78: pp. 341-349, 2005.
    10. Harry A. Atwater and Albert Polman, “Plasmonics for improved photovoltaic devices,” Nature Materials, 9(3): pp. 205-214, 2010.

    11. Michael Gratzel, “Sol-Gel Processed TiO2 Films for Photovoltaic Applications,” Journal of Sol-Gel Science and Technology, 22: pp. 7-13, 2001.
    12. Michael Gratzel, “Photovoltaic and photoelectrochemical conversion of solar energy,” Philosophical Transactions of the Rotal Society A 365(1853): pp. 993-1005, 2007.
    13. K. M. Joshi and V. S. Shrivastava, “Photocatalytic degradation of Chromium (VI) from wastewater using nanomaterials like TiO2, ZnO, and CdS,” Applied Nanoscience, 1(3): pp. 147-155, 2011.
    14. Xiaobo Chen and Samuel S. Mao, “Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications,” Chemical Reviews, 107(7): pp. 2891-2959, 2007.
    15. D. G. Thomas and J. J. Hopfield, “Isoelectronic Traps Due to Nitrogen in Gallium Phosphide,” Physical Review, 150: pp. 680-689, 1966.
    16. Richard E. Malpas, Kingo Itaya and Allen J. Bard, “Semiconductor Electrodes. 20. Photogeneration of Solvated Electrons on p-Type GaAs Electrodes in Liquid Ammonia,” Joutnal of American Chemical Society, 101: pp. 2535-2537, 1979.
    17. Jun Zhang, Shengye Jin, H. Christopher Fry, Sheng Peng, Elena Shevchenko, Gary P. Wiederrecht and Tijana Rajh, “Synthesis and characterization of wurtzite ZnTe nanorods with controllable aspect ratios,” Journal of the American Chemical Society, 133(39): pp. 15324-15327, 2011.
    18. Shiyou Chen, X. G. Gong, Aron Walsh and Su-Huai Wei, “Crystal and electronic band structure of Cu2ZnSnX4 (X=S and Se) photovoltaic absorbers: First-principles insights,” Applied Physics Letters, 94: pp. 041903-041905, 2009.
    19. A. A. Said, M. Sheik-Bahae, D. J. Hagan, T. H. Wei, J. Wang, J. Young and E. W. Van Stryland, “Determination of bound-electronic and free-carrier nonlinearities in ZnSe, GaAs, CdTe, and ZnTe,” Journal of the Optical Society of America B, 9(3): pp. 405-414, 1992.
    20. Bosang S. Kim, Mohammad A. Islam, Louis E. Brus and Irving P. Herman, “Interdot interactions and band gap changes in CdSe nanocrystal arrays at elevated pressure,” Journal of Applied Physics, 89: pp. 8127-8140, 2001.

    21. Yu Chang, Joong Jiat Teo and Hua Chun Zeng, “Formation of Colloidal CuO Nanocrystallites and Their Spherical Aggregation and Reductive Transformation to Hollow Cu2O Nanospheres,” Langmuir, 21: pp. 1074-1079, 2005.
    22. AHM Amimul Ahsan, Abduallah Nazib and Md. Kamrul Hasan, “An Optimization of Optical Imaging System using Remote Sensing,” International Journal of Computer and Information Technology, 2: pp. 47-53, 2012.
    23. Akihiko Yoshikawa and Tamotsu Okamoto, “On the mechanism of growth-rate enhancement by photocatalysis in metalorganic vapor phase epitaxy of ZnSe,” Journal of Crystal Growth, 117: pp. 107-110, 1992.
    24. Stephen H. Frayne, Stacey N. Barnaby, Nako Nakatsuka and Ipsita A. Banerjee, “Growth and Properties of CdSe Nanoparticles on Ellagic Acid Biotemplates for Photodegradation Applications,” Materials Express, 2(4): pp. 335-343, 2012.
    25. Haojun Zhu and Quan Li, “Visible light-driven CdSe nanotube array photocatalyst,” Nanoscale Research Letters, 8(1): pp. 230-235, 2013.
    26. HaiYan Xu, JinKuang Dong and Chen Chen, “One-step chemical bath deposition and photocatalytic activity of Cu2O thin films with orientation and size controlled by a chelating agent,” Materials Chemistry and Physics, 143(2): pp. 713-719, 2014.
    27. Jing Shi, Jin Li, Xiaojian Huang and Yiwei Tan, “Synthesis and enhanced photocatalytic activity of regularly shaped Cu2O nanowire polyhedra,” Nano Research, 4(5): pp. 448-459, 2011.
    28. Renchun Yang, Fengyun Ma, Tingxian Tao, Dingxing Tang, Yiming Ren, Zhiming Chen, Xu Zhang and Maodong Xu, “Zn2+-assisted synthesis of concave Cu2O crystals and enhanced photocatalytic properties,” Catalysis Communications, 42: pp. 109-112, 2013.
    29. Bo Zhou, Hongxia Wang, Zhiguo Liu, Yanqiang Yang, Xiqiang Huang, Zhe Lu, Yu Sui and Wenhui Su, “Enhanced photocatalytic activity of flowerlike Cu2O/Cu prepared using solvent-thermal route,” Materials Chemistry and Physics, 126(3): pp. 847-852, 2011.
    30. Hui Shi, Ke Yu, Yang Wang, Qingjiang Wang and Ziqiang Zhu, “Shape evolution, photoluminescence and degradation properties of novel Cu2O micro/nanostructures,” Applied Physics A, 108(3): pp. 709-717, 2012.
    31. Wei Chen, Zhongli Fan and Zhiping Lai, “Synthesis of core–shell heterostructured Cu/Cu2O nanowires monitored by in situ XRD as efficient visible-light photocatalysts,” Journal of Materials Chemistry A, 1(44): pp. 13862-13868, 2013.
    32. JinKuang Dong, Haiyan Xu, FengJun Zhang, Chen Chen, Li Liu and GuoTian Wu, “Synergistic effect over photocatalytic active Cu2O thin films and their morphological and orientational transformation under visible light irradiation,” Applied Catalysis A: General, 470: pp. 294-302, 2014.
    33. Shaodong Sun and Zhimao Yang, “Recent advances in tuning crystal facets of polyhedral cuprous oxide architectures,” RSC Advances, 4(8): pp. 3804-3822, 2014.
    34. Hong Gao, Junying Zhang, Kejia Liu, Jing'an Yang, Mei Wang and Wenwen Wang, “Time-dependent hydrothermal synthesis and self-evolution mechanism of Cu2O microcrystals,” Materials Characterization, 71: pp. 112-119, 2012.
    35. Suzi Deng, Verawati Tjoa, Hai Ming Fan, Hui Ru Tan, Dean C. Sayle, Malini Olivo, Subodh Mhaisalkar, Jun Wei and Chorng Haur Sow, “Reduced graphene oxide conjugated Cu2O nanowire mesocrystals for high-performance NO2 gas sensor,” Journal of the Chemical Society, 134(10): pp. 4905-4917, 2012.
    36. Jiatao Zhang, Junfeng Liu, Qing Peng, Xun Wang and Yadong Li, “Nearly Monodisperse Cu2O and CuO Nanospheres: Preparation and Applications for Sensitive Gas Sensors,” Chemistry of Materials, 18: pp. 867-871, 2006.
    37. Benjamin D. Yuhas and Peidong Yang, “Nanowire-Based All-Oxide Solar Cells,” Journal of the American Chemical Society, 131: pp. 3756-3761, 2009.
    38. P. Poizot, S. Laruelle, S. Grugeon, L. Dupont and J-M. Tarascon, “Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries,” Nature, 407: pp. 496-499, 2000.
    39. Brian White, Ming Yin, Andrew Hall, Duy Le, Sergey Stolbov, Talat Rahman, Nicholas Turro and Stephen O’Brien, “Complete CO Oxidation over Cu2O Nanoparticles Supported on Silica Gel,” Nano Letters, 6: pp. 2095-2098, 2006.
    40. Jining Gao, Quanshui Li, Huabo Zhao, Lianshan Li, Chunling Liu, Qihuang Gong and Limin Qi, “One-Pot Synthesis of Uniform Cu2O and CuS Hollow Spheres and Their Optical Limiting Properties,” Chemistry of Materials, 20: pp. 6263-6269, 2008.
    41. Changsheng Dong, Minlin Zhong, Ting Huang, Mingxing Ma, Dirk Wortmann, Mihael Brajdic and Ingomar Kelbassa, “Photodegradation of methyl orange under visible light by micro-nano hierarchical Cu2O structure fabricated by hybrid laser processing and chemical dealloying,” ACS Appl Mater Interfaces, 3(11): pp. 4332-4338, 2011.
    42. Valtair M. Cristante, Alexandre G.S. Prado, Sonia M.A. Jorge, Jose P.S. Valente, Ariovaldo O. Florentino and Pedro M. Padilha, “Synthesis and characterization of TiO2 chemically modified by Pd(II) 2-aminothiazole complex for the photocatalytic degradation of phenol,” Journal of Photochemistry and Photobiology A: Chemistry, 195(1): pp. 23-29, 2008.
    43. Harry O. Finklea, “Photoelectrochemistry: Introductory Concepts,” Journal of Chemical Education, 60: pp. 325-327, 1983.
    44. Roel van de Krol, “Principles of Photoelectrochemical Cells,” Science & Technology, 102: pp. 13-67, 2012.
    45. Sergio Trasa’tti, “The Absolute Electrode Potential: An Explanatory Note,” Pure and Applied Chemistry, 58: pp. 955-966, 1986.
    46. Colleen M. McShane and Kyoung-Shin Choi, “Photocurrent Enhancement of n-Type Cu2O Electrodes Achieved by Controlling Dendritic Branching Growth,” Journal of the American Chemical Society, 131: pp. 2561-2569, 2009.
    47. Ran Ji, Wendong Sun and Ying Chu, “One-step hydrothermal synthesis of a porous Cu2O film and its photoelectrochemical properties,” Chemphyschem, 14(17): pp. 3971-3976, 2013.
    48. Yuzhuo Zhang, Yanqing Zhao, Fengyan Li, Zhixia Sun, Lin Xu and Xiaolan Guo, “Photovoltaic performance enhancement of Cu2O photocathodes by electrostatic adsorption of polyoxometalate on Cu2O crystal faces,” RSC Advances, 4(3): pp. 1362-1365, 2014.
    49. Ruslan Valiev, “Nanomaterial advantage,” Nature, 419: pp. 887-888, 2002.
    50. Dongjiang Yang, Hongwei Liu, Zhanfeng Zheng, Yong Yuan, Jin-cai Zhao, Eric R. Waclawik, Xuebin Ke and Huaiyong Zhu, “An Efficient Photocatalyst Structure: TiO2(B) Nanofibers with a Shell of Anatase Nanocrystals,” Journal of the American Chemical Society, 131: pp. 17885-17893, 2009.

    51. H. M. Fan, G. J. You, Y. Li, Z. Zheng, H. R. Tan, Z. X. Shen, S. H. Tang and Y. P. Feng, “Shape-Controlled Synthesis of Single-Crystalline Fe2O3 Hollow Nanocrystals and Their Tunable Optical Properties,” The Journal of Physical Chemistry C, 113: pp. 9928-9935, 2009.
    52. Yang Hou, Xinyong Li, Xuejun Zou, Xie Quan and Guohua Chen, “Photoeletrocatalytic Activity of a Cu2O-Loaded Self-Organized Highly Oriented TiO2 Nanotube Array Electrode for 4-Chlorophenol Degradation,” Environmental Science & Technology, 43: pp. 858-863, 2009.
    53. Catherine J. Murphy and Nikhil R. Jana, “Controlling the Aspect Ratio of Inorganic Nanorods and Nanowires,” Advanced Materials, 14: pp. 80-82, 2002.
    54. Mayur Valodkar, Angshuman Pal and Sonal Thakore, “Synthesis and characterization of cuprous oxide dendrites: New simplified green hydrothermal route,” Journal of Alloys and Compounds, 509(2): pp. 523-528, 2011.
    55. Anne-Lise Daltion, Ahmed Addad and Jean-Paul Chopart, “Potentiostatic deposition and characterization of cuprous oxide films and nanowires,” Journal of Crystal Growth, 282(3-4): pp. 414-420, 2005.
    56. Jin-Yi Chen, Pei-Jiang Zhou, Jia-Lin Li and Su-Qin Li, “Depositing Cu2O of different morphology on chitosan nanoparticles by an electrochemical method,” Carbohydrate Polymers, 67(4): pp. 623-629, 2007.
    57. Withana Siripala, Anna Ivanovskaya, Thomas F. Jaramillo, Sung-Hyeon Baeck and Eric W. McFarland, “A Cu2O/TiO2 heterojunction thin film cathode for photoelectrocatalysis,” Solar Energy Materials and Solar Cells, 77(3): pp. 229-237, 2003.
    58. Matthew J. Siegfried and Kyoung-Shin Choi, “Directing the architecture of cuprous oxide crystals during electrochemical growth,” Angewandte Chemie International Edition, 44(21): pp. 3218-3223, 2005.
    59. Julie K. Barton, Alexey A. Vertegel, Eric W. Bohannan and Jay A. Switzer, “Epitaxial Electrodeposition of Copper(I) Oxide on Single-Crystal Copper,” Chemistry of Materials, 13: pp. 952-959, 2001.
    60. S. Kenane and L. Piraux, “Electrochemical self-assembly of Cu/Cu2O nanowires,” Journal of Materials Research, 17: pp. 401-406, 2002.
    61. Peter McFadyen and Egon Matijevic, “Copper Hydrous Oxide Sols of Uniform Particle Shape and Size,” Journal of Colloid and Interface Science, 44: pp. 95-106, 1973.
    62. B. Balamurugan and B. R. Mehta, “Optical and structural properties of nanocrystalline copper oxide thin films prepared by activated reactive evaporation,” Thin Solid Films, 396: pp. 90-96, 2001.
    63. Guangwen Zhou and Judith C. Yang, “Temperature effect on the Cu2O oxide morphology created by oxidation of Cu(001) as investigated by in situ UHV TEM,” Applied Surface Science, 210(3-4): pp. 165-170, 2003.
    64. Shu-ling Xu, Xin-yu Song, Chun-hua Fan, Guo-zhu Chen, Wei Zhao, Ting You and Si-xiu Sun, “Kinetically controlled synthesis of Cu2O microcrystals with various morphologies by adjusting pH value,” Journal of Crystal Growth, 305: pp. 3-7, 2007.
    65. He Ying Zhao, Ye Feng Wang and Jing Hui Zeng, “Hydrothermal Synthesis of Uniform Cuprous Oxide Microcrystals with Controlled Morphology,” Crystal Growth & Design, 8: pp. 3731-3734, 2008.
    66. Wei Wang, Zhigang Liao, Yi Wang, Xiang Wu, Fengyu Qu and Xu Zhang, “Hydrothermal synthesis of highly symmetric 26-facet Cu2O polyhedra,” Crystal Research and Technology, 46(3): pp. 300-304, 2011.
    67. D. Chen, S. Ni, J. J. Fang and T. Xiao, “Preparation of Cu2O nanoparticles in cupric chloride solutions with a simple mechanochemical approach,” Journal of Alloys and Compounds, 504: pp. S345-S348, 2011.
    68. Michikazu Hara, Takeshi Kondo, Mutsuko Komoda, Sigeru Ikeda, Kiyoaki Shinohara, Akira Tanaka, Junko N. Kondo and Kazunari Domen, “Cu2O as a photocatalyst for overall water splitting under visible light irradiation,” Chemical Communications: pp. 357-358, 1998.
    69. P. Taneja, R. Chandra, R. Banerjee and P. Ayyub, “Structure and Properties of Nanocrystalline Ag and Cu2O Synthesized by High Pressure Sputtering,” Scripta Materialia, 44: pp. 1915-1918, 2001.
    70. Hailing Zhu, Junying Zhang, Chunzhi Li, Feng Pan, Tianmin Wang and Baibiao Huang, “Cu2O thin films deposited by reactive direct current magnetron sputtering,” Thin Solid Films, 517(19): pp. 5700-5704, 2009.
    71. P.R. Markworth, X. Liu, J.Y. Dai, W. Fan, T.J. Marks and R.P.H. Chang, “Coherent island formation of Cu2O films grown by chemical vapor deposition on MgO(110),” Journal of Materials Research, 16: pp. 2408-2414, 2001.
    72. J. Gajendiran and V. Rajendran, “PVA assisted Copper (Cu) @ cuprous oxide (Cu2O) nanostructures via hydrothermal method,” Der Pharma Chemica, 4: pp. 1879-1882, 2012.
    73. Zailei Zhang, Hongwei Che, Yingli Wang, Jiajian Gao, Lirun Zhao, Xilin She, Jin Sun, Poernomo Gunawan, Ziyi Zhong and Fabing Su, “Facile Synthesis of Mesoporous Cu2O Microspheres with Improved Catalytic Property for Dimethyldichlorosilane Synthesis,” Industrial & Engineering Chemistry Research, 51(3): pp. 1264-1274, 2012.
    74. Yuchi Cui, Huijuan Zhang and C. Cheong Wong, “Facile hydrothermal synthesis of novel Cu2O core-shell nanospheres via a template-free route,” Materials Letters, 86: pp. 104-107, 2012.
    75. Alireza Aslani, “Controlling the morphology and size of CuO nanostructures with synthesis by solvo/hydrothermal method without any additives,” Physica B: Condensed Matter, 406(2): pp. 150-154, 2011.
    76. Xiang Lan, Junying Zhang, Hong Gao and Tianmin Wang, “Morphology-controlled hydrothermal synthesis and growth mechanism of microcrystal Cu2O,” CrystEngComm, 13(2): pp. 633-636, 2011.
    77. Yongming Sui, Wuyou Fu, Haibin Yang, Yi Zeng, Yanyan Zhang, Qiang Zhao, Yangen Li, Xiaoming Zhou, Yan Leng, Minghui Li and Guangtian Zou, “Low Temperature Synthesis of Cu2O Crystals: Shape Evolution and Growth Mechanism,” Crystal Growth & Design, 10(1): pp. 99-108, 2010.
    78. Dong Ma, Haibo Liu, Haibin Yang, Wuyou Fu, Yanyan Zhang, Mingxia Yuan, Peng Sun and Xiaoming Zhou, “High pressure hydrothermal synthesis of cuprous oxide microstructures of novel morphologies,” Materials Chemistry and Physics, 116(2-3): pp. 458-463, 2009.
    79. K. Byrappa and T. Adschiri, “Hydrothermal technology for nanotechnology,” Progress in Crystal Growth and Characterization of Materials, 53(2): pp. 117-166, 2007.
    80. K. Byrappa and Masahiro Yoshimura, Handbook of Hydrothermal Technology: A Technology for Crystal Growth and Materials Processing, Norwich, New York: Noyes Publications, 2001.
    81. Wen-Chung Lu, Hoang-Diem Nguyen, Chun-Yi Wu, Kao-Shuo Chang and Masahiro Yoshimura, “Modulation of physical and photocatalytic properties of (Cr, N) codoped TiO2 nanorods using soft solution processing,” Journal of Applied Physics, 115(14): pp. 144305-144312, 2014.
    82. Sawanta S. Mali, Pravin S. Shinde, Chirayath A. Betty, Popatrao N. Bhosale, Won J. Lee and Pramod S. Patil, “Multistep hydrothermal route for nanocoral architecture of anatase TiO2: synthesis and characterization of dye-sensitized solar cell performance,” Progress in Photovoltaics: Research and Applications, 22(5): pp. 525-539, 2014.
    83. Chih-Min Lin, Yun-Ching Chang, Jimmy Yao, Chao Wang, Claire Luo and Stuart Yin, “Multi-step hydrothermally synthesized TiO2 nanoforests and its application to dye-sensitized solar cells,” Materials Chemistry and Physics, 135(2-3): pp. 723-727, 2012.
    84. Lijian Meng, Aifeng Ma, Pinliang Ying, Zhaochi Feng and Can Li, “Sputtered Highly Ordered TiO2 Nanorod Arrays and Their Applications as the Electrode in Dye-Sensitized Solar Cells,” Journal of Nanoscience and Nanotechnology, 11(2): pp. 929-934, 2011.
    85. Tara P. Dhakal, Chien–Yi Peng, R. Reid Tobias, Ramesh Dasharathy and Charles R. Westgate, “Characterization of a CZTS thin film solar cell grown by sputtering method,” Solar Energy, 100: pp. 23-30, 2014.
    86. Mallar Raya, Kakali Jana, N.R. Bandyopadhyay, S.M. Hossain, Daniel Navarro-Urrios, P.P. Chattyopadhyay and Martin A. Green, “Blue–violet photoluminescence from colloidal suspension of nanocrystalline silicon in silicon oxide matrix,” Solid State Communications, 149(9-10): pp. 352-356, 2009.
    87. D. Dasgupta, F. Demichelis, C. F. Pirri and A. Tagliaferro, “π bands and gap states from optical absorption and electron-spin-resonance studies on amorphous carbon and amorphous hydrogenated carbon films,” Physical Review B, 43(3): pp. 2131-2135, 1991.
    88. Naoto Takeno, Atlas of Eh-pH diagrams: Intercomparison of thermodynamic databases, Geological Survey of Japan Open File Report No. 419, 2005.
    89. Ming-Guo Ma and Ying-Jie Zhu, “Hydrothermal synthesis of cuprous oxide microstructures assembled from needles,” Journal of Alloys and Compounds, 455: pp. L15-L18, 2008.
    90. K. Santra, C. K. Sarkar, M. K. Mukherjee and B. Ghosh, “Copper oxide thin films grown by plasma evaporation method,” Thin Solid Films, 213: pp. 226-229,1992.
    91. Charles S. Smith, “Piezoresistance Effect in Germanium and Silicon,” Physical Review, 94(1): pp. 42-49, 1954.
    92. Toshiyuki Toriyama and Susumu Sugiyama, “Analysis of Piezoresistance in p-type Silicon for Mechanical Sensors,” Journal of Microelectromechanical Systems, 11: pp. 598-604, 2002.
    93. Woo-Young Yang and Shi-Woo Rhee, “Effect of electrode material on the resistance switching of Cu2O film,” Applied Physics Letters, 91: pp. 232907-232909, 2007.
    94. Y W Zhu, T Yu, FC Cheong, X J Xu, C T Lim, V B C Tan, J T L Thong and C H Sow, “Large-scale synthesis and field emission properties of vertically oriented CuO nanowire films,” Nanotechnology, 16(1): pp. 88-92, 2005.
    95. Eunkyoung Nam, Young-Hun Kang, Donggeun Jung, Young Sung Kim, “Anode material properties of Ga-doped ZnO thin films by pulsed DC magnetron sputtering method for organic light emitting diodes,” Thin Solid Film, 518: pp.6245-6248, 2010.
    96. P. J. French and A. G. R. Evans, “Piezoresistance in Polysilicon and Its Applications to Strain Gauges,” Solid-State electronics, 32: pp. 1-10, 1989.
    97. Joseph C. Doll and Beth L. Pruitt, Piezoresistor Design and Applications, CA: Stanford University, 2013.
    98. Wen H Ko, “Solid-State Capacitive Pressure Transducers,” Sensors and Actuators, 10: pp. 303-320, 1986.
    99. I-Wei Huang, Chia-Swee Hong and Brian Bush, “Photocatalytic Degradation of PCBs in TiO2 Aqueous Suspensions,” Chemosphere, 32: pp. 1869-1881, 1996.

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