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研究生： 張雅雯
Chang, Ya-wen
論文名稱： 太陽能電池之材料及製程知識庫系統
A Knowledge-Based System for Materials and Processes in Solar Cell Fabrication
指導教授： 黃文星
Hwang, Weng-sing
學位類別： 碩士
Master
系所名稱： 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年： 2009
畢業學年度： 97
語文別： 中文
論文頁數： 144
中文關鍵詞： 太陽能電池 、知識庫
外文關鍵詞： knowledge-based, solar cell
相關次數： 點閱：124  下載：10 
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    • 太陽能發電產業發展蓬勃，知識日新月異，為了達到更有效率的學習，一個架構清晰的知識庫有其必要性。本研究以知識管理為出發點，針對太陽能電池的原理、材料及其製程，建構一太陽能電池知識庫。並以網頁形式呈現此知識庫。
    本研究所建立之知識庫具備分類清晰的架構；首先依太陽能電池的材料區分為矽太陽能電池、化合物半導體太陽能電池、染料敏化太陽能電池、有機高分子太陽能電池。其中矽太陽能電池又分成矽基太陽能電池及矽薄膜太陽能電池兩種。化合物半導體太陽能電池又分成二六族碲化鎘太陽能電池、銅銦鎵二硒系列太陽能電池及三五族砷化鎵太陽能電池等三種。每個不同的分類項目下方依太陽能電池中的結構、材料類別、以及製程等要點分述，最終彙整建構成一個太陽能電池知識庫，並將之以網頁形式呈現。
    本研究所建立之知識庫網站具有知識管理之價值，不僅能幫助太陽光電領域初學者瞭解各種太陽能電池中的結構、材料及製程，亦提供太陽光電領域進階人員一個實用的知識庫系統。而與其他的學習管道比較，本知識庫網站不僅便於增修、更新與擴充，更具備全文檢索功能，為一因應e世代潮流的知識取得管道。

    There are constantly new technologies and information generated in the field of photovoltaic. In order to extract knowledge effectively, we need a knowledge-based system with a clear structure. In this thesis research, a knowledge-based system for materials and processes in solar cell fabrication has been established from the standpoint of knowledge management and demonstrated in the form of web-sites.
    A clear structure is employed in this knowledge-based system. In the first level, all films were classified into four categories based on their electrical properties: silicon solar cell, compound semiconductor solar cell, dye sensitized solar cell and organic/polymer solar cell. In the second level, silicon solar cell was classified into two classes based on their structures: silicon based solar cell and thin film silicon solar cell. Compound semiconductor was further classified into three classes based on their materials: Cadmium telluride solar cell, CuInGaSe2 solar cell and GaAs solar cell. Each class at the second level was further divided in accordance with the positions, materials, processes, etc. Arranging all the information, the knowledge-based system was established.
    The solar cell knowledge-based system has the value of knowledge management. It can not only help the beginners but also more experienced engineers in the field of solar photovoltaic. Compare with other ways of knowledge acquisition, this knowledge-based system is easier to be modified and updated. It also has a Site-search function to enhance its value.

    目錄 中文摘要 I ABSTRACT II 致謝 III 目錄 V 第一章 緒論 1 1.1 研究動機與目的 1 1.2 研究內容與架構 2 1.3 研究流程 3 第二章 文獻回顧 7 2.1 無機太陽能電池元件運作原理 7 2.1.1 基本太陽能電池的運作原理 7 2.1.2 決定太陽能電池的效能的因素 8 2.2 太陽能電池實際設計考量 11 第三章 知識庫系統的架構 17 3.1 矽太陽能電池 17 3.1.1 矽基太陽能電池 17 3.1.1.1 基板 18 3.1.1.1.1 太陽能級多晶矽原料製造技術 19 3.1.1.1.2 太陽能級矽單晶片製造技術 22 3.1.1.1.3 多晶矽晶片製造技術 25 3.1.1.1.1.1鑄造多晶矽錠 26 3.1.1.1.1.2薄板多晶矽片製造技術 27 3.1.1.2 表面粗糙化結構 30 3.1.1.3 p-n二極體 31 3.1.1.3.1 磷擴散製程 32 3.1.1.3.2 邊緣絕緣處理 33 3.1.1.4 抗反射層 34 3.1.1.5 電極 36 3.1.2 薄膜矽太陽能電池 38 3.1.2.1 薄膜結晶矽太陽能電池 39 3.1.2.1.1 光線留滯結構 40 3.1.2.1.2 p-n薄膜 43 3.1.2.1.2.1薄膜沉積技術 43 3.1.2.1.2.2薄膜晶粒改善技術 46 3.1.2.2 薄膜非晶矽太陽能電池 50 3.1.2.2.1 TCO 53 3.1.2.2.2 p-i-n薄膜 53 3.1.2.2.2.1非晶矽的原子結構與特性 54 3.1.2.2.2.2 PECVD（Plasma Enhanced CVD） 55 3.1.2.2.2.3 HWCVD（Hot Wire CVD） 57 3.1.2.2.2.4 合金膜的形成 57 3.2 化合物半導體太陽能電池 58 3.2.1 三五族太陽能電池 58 3.2.1.1 Ge電池 60 3.2.1.2 GaAs電池 60 3.2.1.3 GaInP電池 61 3.2.1.4隧道結（Tunnel Junction） 62 3.2.2 二六族碲化鎘太陽能電池 63 3.2.2.1 p-n薄膜 64 3.2.2.1.1 物理氣相沉積法 65 3.2.2.1.2 密閉空間昇華法 66 3.2.2.1.3 氣相傳輸沉積法 67 3.2.2.1.4 電化學沉積法 67 3.2.2.1.5 噴塗沉積法 67 3.2.2.1.6 有機金屬化學氣相沉積法 68 3.2.2.1.7 網印沉積法 68 3.2.2.2 背面電極 68 3.2.3 銅銦鎵二硒系列太陽能電池 69 3.2.3.1 電極 70 3.2.3.2 p-type薄膜 71 3.2.3.2.1 CuInGaSe2及CuInSe2 71 3.2.3.2.2 二階段共同蒸鍍 72 3.2.3.2.3 三階段共同蒸鍍 73 3.2.3.2.4 硒化法 74 3.2.3.3 n-type薄膜 75 3.2.3.3.1 化學槽水域法 76 3.3 染料敏化太陽能電池 76 3.3.1 染料敏化太陽能電池的發電原理 78 3.3.2 多孔洞TiO2光導電極 79 3.3.3 染料光敏化劑 82 3.3.4 電解質 85 3.3.5 輔助電極 87 3.4 有機/高分子太陽能電池 88 3.4.1 有機/高分子太陽能電池的工作原理 89 3.4.2 有機/高分子太陽能電池的演進 91 3.4.2.1 單層結構 91 3.4.2.2 電子予體/受體雙層異質接面結構 92 3.4.2.3 電子予體摻混受體單層異質接面結構 92 3.4.2.4 高分子摻混無機半導體奈米材料之單層異質接面結構 94 3.4.3 常用於製作有機/高分子太陽能電池的材料 96 第四章 知識庫系統操作介面的設計 116 4.1 網頁設計的軟體工具 116 4.2 美工與影像處理 118 第五章 使用範例 124 5.1 利用主選單 124 5.2 利用全文檢索功能 124 第六章 總結 132 第七章 未來工作 134 參考文獻 135

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