能源危機造成油品價格直線狂標，使得柴油與漁船用油之價差越趨明顯。部分不肖業者基於個人利益竟以漁船用油替代行駛中柴油車用油，致使環境污染更加嚴重。柴油可以添加輕質循環油以替代柴油，但由於輕質循環油的硫份含量與多芳香烴含量亦均較一般柴油為高，2007年台灣柴油之規範，增加多芳香烴含量之限制，因此柴油中輕質循環油之添加比例勢必受限。因此，如何尋找適當之替代能源為減緩能源危機所造成之衝擊之不二法門。許多國家在替代性燃料方面之研究已相當普遍，而替代性燃料之主力為降低排放污染物對環境之衝擊和不需修正或更新引擎系統。生質柴油是以動物性脂肪或植物油藉甲醇或乙醇催化轉換而成。利用生質柴油替代柴油以達到減少油耗之目標。此外近年來，乳化柴油證實其內含之水，在燃燒過程中扮演相當重要之角色。乳化柴油具有使效能稍微提升且使柴油引擎在無損比油耗量之情況下減少熱式NO、煙灰、碳氫化合物及粒狀物微量等潛能。除此之外，乳化柴油亦減少其熱通量、 金屬溫度、熱力負荷以及在區軸油箱中之外層金屬碎片。
本研究係針對漁船用油、輕質循環油、棕櫚生質柴油、烷化生質柴油與奈米乳化柴油進行柴油引擎之多環芳香烴化合物(PAHs)之採樣及分析。PAHs樣品包含氣相與粒狀物相PAHs，二十一種個別PAHs以氣相層析質譜儀(GC/MS)分析之。本研究之目的為建立本土性柴油車與柴油發電機使用各種不同油品之PAHs排放基本資料，並了解生質柴油及乳化柴油對引擎排放廢氣污染減量及提昇能源效率之研究，以減少PAHs對民眾身體健康之衝擊。本研究之結論歸納如下：
1.柴油車非法使用漁船用油會明顯增加移動性污染源之PAHs排放，因此漁船用油非法使用情形值得注意。
2.若添加3.5%輕質循環油於柴油中，將使總PAHs與總BaPeq之排放量分別增加 80.4 % 與 201 % 。柴油中添加輕質循環油會明顯增加PAHs排放，因此輕質循環油添加在柴油中之比例應有所限制。
3.棕櫚生質柴油是一種高含氧量之油品，燃燒時可以增加燃燒效率，但添加50%以上棕櫚生質柴油將會造成燃燒不完全，抑制油品燃燒時熱能之釋放。未來的引擎需要進行修正以符合高比例之生質柴油油品之需求。
4.使用棕櫚生質柴油與柴油之混合油品以及烷化油與棕櫚生質柴油之混合油品經300小時(18,000 km)之耐久性測試後，對引擎運轉、燃燒室積污與引擎油之劣化情形無明顯之差異。
5.乳化柴油與生化溶液確實可明顯降低PAHs、 PM 與 SOF排放，提升燃燒效率並有效節能，隨著柴油價格之上升，含有生化溶液之乳化柴油將有商業應用之潛能。

The recent energy crisis caused the cost of fuel to rise dramatically. Thus, some people have used fishing boat fuel oil (FBFO) instead of premium diesel fuel (PDF) because of the price difference between FBFO and PDF, despite the increased risk of environmental pollution. Light cycle oil (LCO) can be added to PDF to reduce the consumption of diesel, but the sulfur and aromatic content in LCO are higher than those of PDF. The fraction of LCO being added in the PDF should be strictly regulated due to the maximum allowed sulfur (0.035wt%) and total aromatic contents (35wt%) in diesel fuel in Taiwan. A proper alternative energy source can slow down the impact of the energy crisis and alternative fuels such as biodiesel are being considered in many countries owing to increased environmental awareness and the rising price of diesel. Developing alternative diesel fuels is driven by the necessity to reduce the environmental impact of emissions without modifying engines. Biodiesel is produced from animal fats or vegetable oils with methanol or ethanol as the catalyst by transesterification reaction. Using biodiesel instead of diesel reduces fuel consumption. Recently, studies of water-in-oil emulsions in conventional liquid fuel engines have confirmed that the water in emulsified diesel plays an important role in the combustion process. Water emulsification has a potential to slightly improve the brake efficiency and to significantly reduce the formation of thermal NO, soot, hydrocarbons and PM in diesel engines with no worsening of specific fuel consumption. Besides, emulsified diesel also reduces the heat flux, the metal temperatures, thermal loading and the wear-metal debris in the crankcase oil of emulsified diesel.
The characteristics of polycyclic aromatic hydrocarbons (PAHs) in the exhaust of diesel engines fueled with fishing boat fuel oil, light cycle oil, palmbiodiesel, paraffinic biodiesel and emulsified diesel were investigated. PAHs samples including both gas- and particle-phases were collected and twenty one individual PAHs were analyzed primarily by a gas chromatography/mass spectrometer (GC/MS). The objective of this study is to set up the data bank for the calculation of total amount of PAHs emission, the PAHs dispersion modeling and the assessment of PAHs control.
The major conclusions of this study are as follows :
1.TDVs (traveling diesel vehicles) illegally using FBFO had a significant impact on the total amounts of PAHs emissions from mobile sources and hence deserve more attention.
2.If the maximum percentage of LCO being added to PDF was 3.5% in Taiwan, it would result in an 80.4 % and a 201 % increase in emissions of total PAHs and total BaPeq, respectively. These results strongly suggest that LCO used in traveling diesel vehicles significantly influences PAHs emissions. Therefore, the fraction of LCO being added in the PDF should be strictly regulated.
3. Palm-biodiesel is such an oxygenated fuel that can improve combustion efficiency in diesel engines, but adding more than 50% palm-biodiesel fraction to premium diesel fuel causes incomplete combustion in the diesel-engine generator and impedes the release of energy from the fuel. The modification of diesel engines is needed for high fraction of biodiesel blends in the future.
4.There was no significant difference in unusual operations and damage from deposits inside the chamber or in the inferior condition of the engine oil after 300 hrs (18,000 km) operation of engines by using palmbiodiesel-PDF blends or paraffinic-palmbiodiesel blends instead of PDF fueled on HDDEs.
5.Emulsified diesel and bio-solution did decrease PAHs, PM and SOF emissions from the exhaust of diesel generators and improve combustion efficiency and save energy effectively via adding bio-solution. With the increasing price of diesel, emulsified diesel containing NOE-7F has the potential for commercial application.

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