本研究針對台灣KC地區中兩座垃圾焚化廠(GS及RW廠)及ㄧ座燃煤電廠(PW廠)之煙道廢氣以及周遭大氣之戴奧辛/呋喃之檢測，來評估並推測三廠對當地環境PCDD/Fs之貢獻度，以及利用特徵剖面來分析其相關性，所得結論歸納如下：1. KC 地區GS廠煙道廢氣中總PCDD/Fs I-TEQ濃度介於0.0579～0.136 ng I-TEQ/Nm3之間，平均為 0.0899 ng I-TEQ/Nm3；RW廠煙道廢氣中總PCDD/Fs I-TEQ濃度介於0.0295～0.0597 ng I-TEQ/Nm3之間，平均為0.0442 ng I-TEQ/Nm3；PW電廠煙道廢氣中總PCDD/Fs I-TEQ濃度介於0.00241～0.207 ng I-TEQ/Nm3之間，平均為0.0499 ng I-TEQ/Nm3。三廠煙道廢氣排放總PCDD/Fs I-TEQ濃度均未超過廢棄物焚化爐0.1 ng I-TEQ/Nm3及固定式污染源1 ng I-TEQ/Nm3法規規範值。2. KC地區周界大氣中以總PCDD/Fs I-TEQ毒性當量觀點論之，夏季總毒性低於春季及秋季，與國外研究有相同之趨勢。判斷此現象由 (1)光解及OH自由基效應(2)雨量(3)大氣邊界層高度以及(4)季節性污染源等因素所造成。3. 由三廠之特徵剖面跟三季周界大氣特徵剖面推論，除了三廠之外，還有其他污染源，包含醫療廢棄物焚化爐、鑄鐵廠、銅二級冶煉以及鋁二級冶煉，導致周界大氣特徵剖面跟三廠之特徵剖面相關性並不高。4. 以三廠煙道排放量模擬之周界大氣戴奧辛/呋喃增量與周界大氣之監測值比較，三廠排放之戴奧辛/呋喃總量佔當地約60％，但對周邊地區之貢獻度低於2%。

The characteristics of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in ambient air of both municipal solid waste incineration (MSWI) and coal-fired power plants in KC area in Taiwan were investigated. The conclusions are as follows: 1. The toxic equivalency (TEQ) concentration in the flue gas of MSWI on GS were from 0.0579 to 0.136 ng I-TEQ/Nm3 with a mean value of 0.0899 ng I-TEQ/Nm3. The TEQ concentration in the flue gas of MSWI on RW were from 0.0295 to 0.0597 ng I-TEQ/Nm3 with a mean value of 0.0442 ng I-TEQ/Nm3. The TEQ concentration in the flue gas of power plant on PW were from 0.00241 to 0.207 ng I-TEQ/Nm3 with a mean value of 0.0499 ng I-TEQ/Nm3. All of the PCDD/Fs concentrations in stack flue gas are lower than the concentration of the standard of Taiwan EPA. 2. The summer TEQ concentration of PCDD/Fs in the atmosphere is lower than those in spring and fall at KC area. Those might be due to the following reasons: (1) photolysis and OH radical effect; (2) rainfall; (3) the altitude of atmosphere boundary layer; (4) pollutants varied with seasons. 3. The PCDD/F congener profiles in the plants flue gas and in ambient air indicated that there might have other stationary or mobile sources cause the difference between them. 4. Comparing to the PCDD/F concentrations in ambient air of vicinities, the contributon of PCDD/F from the plants are lower than 2 %.

Alcock, R. E.; Gemmill, R.; Jones, K. C. “Improvements to the UK PCDD/F and PCB Atmospheric Emission Inventory following an Emissions Measurement Programme” Chemosphere, Vol. 38, pp.759-770, 1999.
Alcock, R. E.; Jones, K. C. “Dioxins in the Environment: a Review of Trend Data” Environmental Science & Technology Vol. 30, pp. 3133-3143, 1996.
Ballschmiter, K.; Zoller, W.; Buchert, H.; Class, T. F. Z. Analytical Chemistry, Vol. 322, pp.587, 1985.
Cains, P. W.; Mccausland, L. J.; Fernandes, A. R.; Dyke, P. “Polychlorinated Dibenzo-p-dioxins and Dibenzofurans Formation in Incineration: Effects of Fly Ash and Carbon Source” Environmental Science and Technology, Vol.31, pp. 776-785, 1997.
Caserini, S.; Monguzzi, A. M. “PCDD/Fs Emissions Inventory in the Lombardy Region: Results and Uncertainties” Chemosphere, Vol.48, pp.779-786, 2002.
Cleverly, D.; Schaum, J.; Winter, D.; Schweer, G.; O'Rourke, K. “The Inventory of Sources of Dioxin in the United States” Organohalogen Compounds, Vol. 36, pp. 1-6, 1998
Chen, C.M. “The emission inventory of PCDD/PCDF in Taiwan” Chemosphere, Vol.54, pp. 1413–1420, 2004.
Dickson, L. C.; Lenoir, D.; Hutzinger, O. “Quantitative Comparison of de Novo and Formation of Polychlorinated Dibenzo-p-dioxins under Simulated Municipal Solid Waste Incinerator Postcombustion Conditions” Environmental Science and Technology, Vol. 26, pp. 1822-1828, 1992.
Dickson, L. C.; Lenoir, D.; Hutzinger, O. “Surface-catalyzed Formation of Chlorinated Dibenzodioxins and Dibenzofurans during Incineration”, Chemosphere, Vol. 19, pp.277-282, 1989.
Dyke, P.; Coleman, P. and James, R. “Dioxins in Ambient Air, Bonfire Night 1994” Chemosphere, Vol.34, pp.1191-1201, 1997.
Eduljee, G. H.; Dyke, P. “An Updated Inventory of Potential PCDD and PCDF Emission Sources in the UK” The Science of the Total Environment, Vol. 177, pp. 303-321, 1996.
Everaert, K.; Baeyens, J. “The Formation and Emission of Dioxins in Large Scale Thermal Processes” Chemosphere, Vol. 46, pp. 439-448, 2002.
Green, N. J. L.; Lohmann, R. Jones, K. C. “Seasonal, Anthropogenic, Air Mass, and Meteorological Influences on the Atmospheric Concentrations of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans (PCDD/Fs): Evidence for the Importance of Diffuse Combustion Sources” Environmental Science and Technology, Vol. 33, pp. 2864-2871, 1996.
Gulletta, B. and Touati, A. “PCDD/F Emissions from Burning Wheat and Rice Field Residue” Atmospheric Environment, Vol. 37, pp. 4893–4899, 2003.
Hagenmaier, H.; Brunner, H. “Isomerspecific Analysis of Pentachlorophenol and Sodium Pentachlorophenate for 2,3,7,8- substituted PCDD and PCDF at sub-ppb Levels” Chemosphere, Vol. 16, pp. 1759-1764, 1987.
Hell K.；Altwicker E. R.；Stieglitz L.；AddinkIino R., “Comparison of 2,4,6-trichlorophenol conversion to PCDD/PCDF on a MSWI-fly ash and a model fly ash”Chemosphere, Vol. 40, pp. 995-1001, 2000.
Heister, E.; Bruckman, P.; Bohm, R.; Eynck, P.; Mülder, A.; Ristow, W. Organohalogen Compounds, Vol. 24, pp. 147-152, 1995.
Imagawa T.; Takeuchi M.; Sadakata M.; Weber R.“Formation Rates of Polychlorinated Dibenzofurans and Dibenzo-p-Dioxins from Polycyclic Aromatic Hydrocarbons, Activated Carbon and Phenol” Chemosphere, Vol. 39, pp. 2749-2756, 1999.
Japan Ministry of the Environment, The Environmental Monitoring Report on the Persistent Organic Pollutants (POPs) in Japan, 2002.
Karasek, F. W.; Dickson, L. C. “Model studies of polychlorinated dibenzo-p-dioxin formation during municipal refuse incineration” Science, Vol. 237, pp.754-756, 1987.
Kobayashi, S.; Kitadai, M.; Sameshima, K.; Ishii, Y. Tanaka, A. “A Theoretical Investigation of the Conformation Changing of Dioxins in the Binding site of Dioxin Receptor Model; Role of Absolute Hardness–electronegativity Activity Diagrams for Biological Activity” Journal of Molecular Structure, Vol. 475, pp. 203-217, 1999.
Launhardt, T.; Thoma, H. “Investigation on Organic Pollutants from a Domestic Heating System Using Various Solid Biofuels” Chemosphere, Vol. 40, pp. 1149-1157, 2000.
Lin L. F.； Lee W. J.；Li H. W.； Wang M. S.；Chang-Chien G. S. “Characterization and inventory of PCDD/F emissions from coal-fired power plants and other sources in Taiwan”, Chemosphere, Vol. 68, pp. 1642-1649, 2007.
Lohmann, R.; Jones, K. C. “Dioxins and furans in air and deposition: A review of levels, behaviour and processes” Science of the Total Environment, Vol. 219, pp. 53-81, 1998.
Lorber, M.; Pinsky, P.; Gehring, C. Sovocool, W. “Relationships between Dioxins in Soil, Air, Ash and Emissions from a Municipal Solid Waste Incinerator Emitting Large Amounts of Dioxin” Chemosphere, Vol. 37, pp. 2173-2197, 1998.
Luijk, R.; Akkerman, D. M.; Slot, P.; Olie, K.; Kapteijn, F. “Mechanism of Formation of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in the Catalyzed Combustion of Carbon”, Environmental Science and Technology, Vol. 28, pp. 312-321, 1994.
May, G. “Chloracne from the accidental production of tetrachloro- benzodioxin” The American Journal of Medicine, Vol. 39, pp. 128-135, 1982.
McKay, G. “Dioxin Characterisation, Formation and Minimisation during Municipal Solid Waste (MSW) Incineration: Review”, Chemical Engineering Journal, Vol. 86, pp. 343-368, 2002.
Milligan, M. S.; Altwicker, E. “The Relationship between de Novo Synthesis of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans and Low-Temperature Carbon Gasification in Fly Ash”, Environmental Science and Technology, Vol. 27, pp.1595-1601, 1993.
Moses, M. and Prioleau, P. G. “Cutaneous Histologic Findings in Chemical Workers with and without Chloracne with past Exposure to 2,3,7,8- tetrachlorodibenzo-p-dioxin” The American Journal of Medicine, Vol. 12, pp. 497-506, 1985.
National Cancer Institute, Dioxins and Dibenzofurans in Carcinogenesis, 1980-1986. In：Greenlee, WF,ed. Oncology overview. Washington, D.C.：International Cancer Data Bank, National Cancer Institute, 1987.
Nakao, T. ; Aozasa, O., Ohta, S. ; Miyata, H. “Formation of toxic chemicals including dioxin-related compounds by combustion from a small home waste incinerator” Chemosphere, Vol. 62, pp. 459–468, 2006.
Olie, K.; Vermeulen, P. L.; Hutzinger, O. “Chlorodibenzo-p-dioxins and Chlorodibenzofurans Are Trace Components of Fly Ash and Flue Gas of Some Municipal Incinerators in the Netherlands” Chemosphere, Vol. 6, pp. 455-459, 1977.
Okamoto, Y.; Tomonari, M. “Formation Pathways from 2,4,5-Trichlorophenol (TCP) to Polychlorinated Dibenzo-p-dioxins (PCDDs): An Ab Initio Study” The Journal of Physical Chemistry A., Vol. 103, pp. 7686-7691, 1999.
Quaß, U.; Fermann, M. W.; Bröker, G. “Steps Towards A European Dioxin Emission Inventory” Chemosphere, Vol. 40, pp. 1125-1129, 2000.
Safe, S. “Polychlorinated Biphenyls (PCBs) and Polybrominated Biphenyls (PBBs)：Biochemistry, Toxicology and Mechanism of Action” CRC Crit Rev in toxicol, Vol. 13, pp. 319-393, 1984.
Schwarz, G.; Steiglitz, L.; Roth, W. “Formation Conditions of Several Polychlorinated Compound Classes on Fly Ash of a Municipal Waste Incinerator” Organohalogen Compounds, Vol. 3, pp.169-172, 1990.
Silbergeld, E. K.; Mattison, D. R.“Experimental and Clinical Studies on the Reproductive Toxicology of 2,3,7,8-tetrachlorodibenzo-p-dioxin” The American Journal of Medicine, Vol. 11, pp.131-144, 1987.
Stieglitz, L.; Vogg, H., Report KFK 4379, Laboratorium fur Isotopentechnik, Institut fur Heize Chemi, Kernforschungszentrum Karlsruhe, 1988.
Tan, P.; Hurtado, I.; Neuschütz, D. “Thermodynamic Modeling of PCDD/Fs Formation in Thermal Processes” Environmental Science and Technology, Vol. 35, pp. 1867-1874, 2001.
UNEP, Dioxin and Furan Inventory, National and Regional Emissions of PCDD/Fs. UNEP Chemicals, Geneva, Switzerland. 1999. Available from:<http://www.chem.unep.ch/pops/newlayout/repdocs.html>.
US EPA, Combustion Emissions Technical Resource Document (CETRED), Report No. EPA 530-R-94-014, Washington, DC, 1994b.
US EPA, Database of Sources of Environmental Releases of Dioxin like Compounds in the United States, EPA/600/C-01/012, 2001.
US EPA, Health Assessment Document for 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) and Related Compounds”, EPA/600/Bp-92/001c Estimating Exposure to Dioxin-Like Compounds, EPA/600/6-88/005Cb, Office of Research and Development, Washington, DC, 1994a.
USEPA, The Inventory of Sources of Dioxin in the United States, EPA/600/P-98/002Aa, April 2005.
Wang, L. C.; Lee, W. J.; Lee, W. S.; Chang-Chien, G. P. “Effect of chlorine content in feeding wastes of incineration on the emission of polychlorinated dibenzo-p-dioxins/dibenzofurans”, The Science of the Total Environment, Vol. 302, pp.185～198, 2003a.
Wang, L. C.; Lee, W. J.; Lee, W. S.; Chang-Chien, G. P.; Tsai, P. J. “Characterizing the emission of polychlorinated dibenzo-p-dioxins and dibenzofurans from crematories and their impacts to the surrounding environment”, Environmental Science and Technology, Vol. 37, pp.62～67, 2003b.
Wang, L. C.; Lee, W. J.; Tsai, P. J.; Lee, W. S.; Chang-Chien, G. P. “Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from stack flue gases of sinter plants”, Chemosphere, Vol. 50, pp.1123-1129, 2003c.
WHO Regional Office for Europe, Copenhagen, “PCBs, PCDDs and PCDFs: Prevention and Control of Accidental and Environmental Exposures” Environmental Health Series, Vol. 32, 1987.
Wiesenhahn, D. F.; Li, C. P.; Penner, S. S. “A Simplified Model for Dioxin and Furan Formation in Municipal-waste Incinerators” Energy, Vol. 13, pp. 225-237, 1988.
Wikström, E.; Marklund, S. “Secondary Formation of Chlorinated Dibenzo-p-dioxins, Dibenzofurans, Biphenyls, Benzenes, and Phenols during MSW Combustion” Environmental Science and Technology, Vol. 34, pp. 604-609, 2000.
王琳麒，“污染源及大氣中戴奧辛/呋喃之特徵”，國立成功大學環境工程學系博士論文，2003。
紀凱獻，“北台灣大氣環境中戴奧辛濃度之分佈特性研究”，國立中央大學環境工程研究所碩士論文，2001。
張簡國平、李文智、王琳麒、蔡政穎、余建源、吳俊達、洪忠賢，“台灣PCDD/Fs之排放清單:重要之大氣排放源”，戴奧辛研討會，2002。
張簡國平，“露天燒稻草 戴奧辛濃度超高”，生物醫學年會，2006。
環保署，九十一、九十二、九十三年度建立台灣地區戴奧辛排放清冊及排放資料庫三年工作計畫九十三年度報告，EPA-91-FA12-03-A074，2005。
環保署，“固定污染源戴奧辛排放標準”， http://w3.epa.gov.tw/epalaw/index.aspx，2008
環保署，“廢棄物焚化爐戴奧辛管制及排放標準”， http://w3.epa.gov.tw/epalaw/index.aspx，2008
環保署，“固定污染源管制”，
http://stationary.estc.tw/news.asp?xItem=1888&CtNode=529，2008
環保署，樹林垃圾焚化爐附近居民血液中戴奧辛濃度資料之建立專案工作計畫，2000a。
環保署，95年度戴奧辛環境流布整合管制之規劃與執行研析計畫，EPA-95-J104-02-102，2007。
陳元武，“環境空氣中戴奧辛檢測方法研究”，環境檢驗雙月刊，31期，2000。