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研究生: 陳衍銘
Chen, Yen-Ming
論文名稱: 氫氧化鈉添加於水庫淤泥製備輕質骨材:乾燥程序和燒製溫度
NaOH Addition on Production of Lightweight Aggregate from Reservoir Sludge : Drying Process and Firing Temperature
指導教授: 黃紀嚴
Huang, Chi-Yen
學位類別: 碩士
Master
系所名稱: 工學院 - 資源工程學系
Department of Resources Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 88
中文關鍵詞: 水庫淤泥NaOH輕質骨材
外文關鍵詞: reservoir sludge, NaOH, lightweight aggregates
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  • 台灣地區因自然及人為因素導致水庫淤積快速,現階段水庫浚渫後之淤泥多以棄置處理,此法不但不符經濟效益且易造成二次污染,若能予以資源化利用,可達到環境與經濟的雙贏效果。淤泥本身具有燒製輕質骨材的潛力,輕質骨材具有質輕、強度及耐燃等優良性質,可替代傳統砂石,乃淤泥處理的良好出路。
    本研究以石門水庫淤泥為樣品,經成分分析符合燒製輕質骨材之條件。將淤泥前處理得到含水量30%之濕料(W系列)與乾料(D系列),添加高濃度NaOH混合造粒,燒製階段分為直接燒製與120℃預熱一小時後燒製。
    研究結果發現添加NaOH能降低兩系列製程的燒製溫度,在1085~1045℃,W系列能得到體密度1.147~1.606g/cm3,抗壓強度1.72~21.07Mpa的燒結體;D系列能得到體密度1.012~1.377 g/cm3,抗壓強度1.68~7.89Mpa燒結體,皆符合輕質骨材標準。而W系列燒結體之性質與D系列燒結體相近,證實了以濕料直接燒製輕質骨材的可行性。添加NaOH和濕料直接燒製可降低技術及原料處理成本,有助於推廣淤泥燒製輕質骨材。

    Reservoir sludge(sediments) is a common problem in Taiwan that damages the volume of Reservoirs , production of lightweight aggregates (LWAs) from reservoir sludge is a proper way to save their life. Instead drying and firing cost a lot on preparing LWAs. The purpose of this study is to prepare LWAs with NaOH addition to eliminate drying process and lower the firing temperature.
    The experiment primarily studies the feasibility of LWAs made by reservoir sludge with NaOH addition. The sediments included the water content of 30%. The physical properties of sludge–made LWAs were measured. XRD, DTA, OM, SEM and MTS were used to examine the characterizations, including mineral phase, bloating mechanism, microstructure and compressive strength.
    The bulk densities of sludge–made LWAs ranged between 1.14 g/cm3 and 1.60 g/cm3, and the compressive strengths ranged between 1.72 MPa and 21.07 MPa. The physical properties of sludge–made LWAs all meet the regulations for LWAs.
    The results show it is feasible to prepare LWAs from reservoir sediment without drying by NaOH addition which can lower firing temperature in the range between 1085℃ and 1145℃. This method can greatly reduce the cost on LWAs production and further promote their applications on building industry.

    目錄 摘要 I ABSTRACT I 致謝 II 目錄 III 圖目錄 I 表目錄 I 第一章 緒論 1 1-1前言 1 1-2研究動機與目的 2 第二章 理論基礎與前人研究 4 2-1水庫淤泥概況 4 2-1-1水庫淤泥形成因素 4 2-1-2水庫淤泥淤積概況 4 2-1-3水庫淤泥處理 6 2-2輕質骨材概述 8 2-2-1輕質骨材種類及發展 8 2-2-2輕質骨材特性 10 2-2-3輕質骨材膨脹機理 12 2-3輕質骨材燒結理論 15 2-3-1矽酸鹽礦物結晶構造 15 2-3-2 黏土-水系統 21 2-3-3黏土之乾燥[33] 23 2-3-4玻璃結構與組成 24 2-3-5玻化 25 2-3-6液相燒結 25 2-3-7燒結理論 26 2-4無機聚合物概述 27 2-4-1無機聚合物起源與組成 27 2-4-2無機聚合物反應機制與結構 28 2-5前人研究 30 第三章 實驗方法與步驟 32 3-1實驗流程 32 3-2性質測試 34 3-2-1 粒徑分析 34 3-2-2 成分分析 34 3-2-3 X-Ray繞射分析(XRD) 34 3-2-4 熱行為分析(DTA) 35 3-2-5 光學顯微鏡(OM) 35 3-2-6 燒結體基本物理性質測試 35 3-2-7 燒結體強度試驗 36 3-2-8 燒結體顯微結構分析 37 第四章 結果與討論 38 4-1淤泥原樣分析 38 4-1-1淤泥粒徑及粉末型態分析 38 4-1-2淤泥原樣XRD繞射分析 39 4-1-3淤泥成分分析 40 4-1-4淤泥熱行為分析 42 4-2燒結體性質 43 4-2-1燒結體外觀 43 4-2-2燒結體體密度 46 4-2-3 燒結體之物理性質 53 4-2-4燒結體抗壓強度 57 4-2-5燒結體截面結構分析 66 4-2-6燒結體顯微結構分析 71 4-2-7 燒結體礦物相 78 第五章 結論與建議 83 5-1結論 83 5-2建議 84 參考文獻 86

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