| 研究生: |
陳衍銘 Chen, Yen-Ming |
|---|---|
| 論文名稱: |
氫氧化鈉添加於水庫淤泥製備輕質骨材:乾燥程序和燒製溫度 NaOH Addition on Production of Lightweight Aggregate from Reservoir Sludge : Drying Process and Firing Temperature |
| 指導教授: |
黃紀嚴
Huang, Chi-Yen |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 資源工程學系 Department of Resources Engineering |
| 論文出版年: | 2010 |
| 畢業學年度: | 98 |
| 語文別: | 中文 |
| 論文頁數: | 88 |
| 中文關鍵詞: | 水庫淤泥 、NaOH 、輕質骨材 |
| 外文關鍵詞: | reservoir sludge, NaOH, lightweight aggregates |
| 相關次數: | 點閱:156 下載:0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
台灣地區因自然及人為因素導致水庫淤積快速,現階段水庫浚渫後之淤泥多以棄置處理,此法不但不符經濟效益且易造成二次污染,若能予以資源化利用,可達到環境與經濟的雙贏效果。淤泥本身具有燒製輕質骨材的潛力,輕質骨材具有質輕、強度及耐燃等優良性質,可替代傳統砂石,乃淤泥處理的良好出路。
本研究以石門水庫淤泥為樣品,經成分分析符合燒製輕質骨材之條件。將淤泥前處理得到含水量30%之濕料(W系列)與乾料(D系列),添加高濃度NaOH混合造粒,燒製階段分為直接燒製與120℃預熱一小時後燒製。
研究結果發現添加NaOH能降低兩系列製程的燒製溫度,在1085~1045℃,W系列能得到體密度1.147~1.606g/cm3,抗壓強度1.72~21.07Mpa的燒結體;D系列能得到體密度1.012~1.377 g/cm3,抗壓強度1.68~7.89Mpa燒結體,皆符合輕質骨材標準。而W系列燒結體之性質與D系列燒結體相近,證實了以濕料直接燒製輕質骨材的可行性。添加NaOH和濕料直接燒製可降低技術及原料處理成本,有助於推廣淤泥燒製輕質骨材。
Reservoir sludge(sediments) is a common problem in Taiwan that damages the volume of Reservoirs , production of lightweight aggregates (LWAs) from reservoir sludge is a proper way to save their life. Instead drying and firing cost a lot on preparing LWAs. The purpose of this study is to prepare LWAs with NaOH addition to eliminate drying process and lower the firing temperature.
The experiment primarily studies the feasibility of LWAs made by reservoir sludge with NaOH addition. The sediments included the water content of 30%. The physical properties of sludge–made LWAs were measured. XRD, DTA, OM, SEM and MTS were used to examine the characterizations, including mineral phase, bloating mechanism, microstructure and compressive strength.
The bulk densities of sludge–made LWAs ranged between 1.14 g/cm3 and 1.60 g/cm3, and the compressive strengths ranged between 1.72 MPa and 21.07 MPa. The physical properties of sludge–made LWAs all meet the regulations for LWAs.
The results show it is feasible to prepare LWAs from reservoir sediment without drying by NaOH addition which can lower firing temperature in the range between 1085℃ and 1145℃. This method can greatly reduce the cost on LWAs production and further promote their applications on building industry.
1.何春蓀,「台灣地質概論」,經濟部中央地質調查所,1986
2.B. Roy, B. K., “Lightweight aggregate concrete in UK, ” International symposium on structure on structure lightweig aggregate concrete, ” Norway, June 1995
3.Helgesen, K. Hakon, “Lightweight aggregate concrete in Norway, ” International symposium on structure on structure lightweight aggregate concrete”, Norway, June 1995
4.工業技術研究院,「水庫、港灣淤砂回收作為土石資源利用之研究」,經濟部礦業司,民國94年11月
5.水資源局「水庫淤砂研究課題規劃」,1996
6.經濟部水利署網站
7.吳素禎等人,「水庫淤泥固化與棄置”中興工程顧問社/專案研究報告」,1999
8.Cheeseman, C. R., Makinde, A. and Bethanis, S., “Properties of lightweight aggregate produced by rapid sintering of incinerator bottom ash, ”Resources, Conservation and Recycling 43 pp. 147-162 2005
9.Ducman, V., Mladenovic, A. and Suput, J. S., “Lightweight aggregate based on waste glass and its alkali-silica ractivity, ” Cementand Concrete Research 32 pp. 223-226 2002
10.傅建璋,「升溫速率對石門水庫淤泥製備輕質骨材之影響」,國立成功大學資源工程研究所,2009
11.Short and Kinniburgh, “Light-weight Concrete” MAMLX III, ” London, 1963
12.林維明,吳介源,「當前輕質粒料混凝土應用的重要性」,台灣公路工程,第二十六卷,第五期,pp. 36-48 1999
13.k. Aurish, “Kleine Leichtbetonkunde, ”Bauverlag GMBH Wiesbadenund Berlin, pp. 21-44 1971
14.陳澤修,「綠色建築新材料冷結型煤灰輕質骨材」,現代營建,208期,1997
15.蔡尚晏,「水庫淤泥添加玻璃粉燒製輕質骨材之研究」,國立成功大學資源工程研究所,2008
16.王櫻茂,「人造輕質骨材混凝土」,豐生出版社,pp. 4-23 1976
17.L. John, Clarke, “Structural lightweight aggregate concrete, ”Blackie Academic & Professional, 1993
18.環保署回收再利用網站
19.余岳峰,「下水污泥焚化灰渣燒成輕質骨材特性之研究」, 國立中央大學環境工程研究所,2000。
20.黃兆龍,「混凝土性質與行為」,詹氏書局,台北,1997
21.C. M. Riley, “Relation of Chemical Properties to the Bloating of Clays, ”Journal of the American Ceramic Society, Vol. 34, No.4, pp. 121-128 1951
22.C. M. Riley, “The Bloating of Clay, ”John Wiely & Sons Inc., New York, 1990
23.John E. Conley, Hewitt Wilson, T. A. Klinefelter et al., “Production of Lightweight Concrete Aggregates from Clays, Shales, Slates and Other Material, ”U. S. Bureau of Mines Repts. Invest. 1948
24.程道腴,「耐火材料學」,徐氏基金會出版,pp. 164-165 1973
25.C. T. Chen, Kuen, S. W., J. C. Ing, “Effect of SiO2-Al2O3-flux ration change on the bloating characteristics of lightweight aggregate material produced from recycled sewage sludge,” Journal of Hazardous Materials B134, pp. 87-93 2006
26.顏聰,黃兆龍,「水庫淤泥輕質骨材產製及輕質骨材混凝土應用與推廣」,內政部建築研究所,民國92年
27.Klein, C. and Hurlbut, C. S., “Manual of Mineralogy, "John Wiley & Sons., 1993
28.張家碩,「水庫淤泥燒製輕質骨材的燒結行為之研究」,國立成功大學資源工程研究所,2005
29.「陶瓷製造技術」,中華民國陶業研究學會,1992
30.F. Gridi-Bennadji, B. Beneu, J. P. Laval and P. Blanchart, “Structural transformations of Muscovite at high temperature by X-ray and neutron diffraction, "Applied Clay Science 38, pp. 259–267 2008
31.Grim, R. E., “Clay Mineralogy, ”McGraw-Hill Book Company, Ing 1953
32.F. H. Norton, Fine Ceramics:Technology and applications, New York:McGraw-Hill Book, 1970
33.林珮瑤,「含水量水庫淤泥混合配料燒製輕質骨材之研究」,國立成功大學資源工程研究所,2007
34.方柊凱,「TiO2對Na-Ca-Al-Si系統之燃煤底灰轉化微晶玻璃其熱處理程序之研究」,國立成功大學資源工程研究所,2009
35.B. E. Warren, “Kristallogy. Mineralog. Petrogr., ” pp. 86, 349 1933
36.W. D. Kingery, H. K. Bowen, D. R.Uhlmann, “Introduction to Ceramics.2nd Ed, ” 1976
37.肖定全,「陶瓷材料」新文京開發出版,台北縣,pp. 21-59 2003
38.張瑜文,「水庫淤泥應用於無機聚合膠結材」,國立成功大學土木工程研究所,2008
39.Pavel Rovnanik, “Effect of curing temperature on the development of hard structure of metakaolin-based geopolymer, ”Construction and Building Materials xxx xxx–xxx 2010
40.P. Chindaprasirt, C. Jaturapitakkul and U. Rattanasak, “Influence of fineness of rice husk ash and additives on the properties of lightweight aggregate, ”Fuel 88(1), pp. 158-162 2009
41.Y. L. Wei, J. C. Yang, Y. Y. Lin, S. Y. Chuang and H. P. Wang, “Recycling of harbor sediment as lightweight aggregate, ” Marine Pollution Bulletin 57(6-12), pp. 867-872 2008
42.I. J. Chiou, K. S. Wang, C. H. Chen and Y. T. Lin, “Lightweight aggregate made from sewage sludge and incinerated ash, ” Waste Management 26, pp. 1453-1461 2006
43.Y. Hiramatsu, Y. Oka, Int. J. Rock Mech Min. Sci. pp. 89 1966
44.Y. Li, D. Wu, J. Zhang, L. Chang, Z. Fang, “Measurement and statistics of single pellet mechanical strength of differently shaped catalysts” Powder Technol vol. 113 pp. 179-184 2000
45.L. Heller, I. Miloslavski, Z. Aizenshtat, and L. Halicz, “Chemical and mass spectrometric analysis of volatiles derived from clays, ” Am. Mineral., Vol. 73 pp. 376-382 1988
校內:2020-12-31公開