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研究生: 廖秀蓮
Liao, Hsiu-Lien
論文名稱: 引入ZrO2介層對Porcelain與Ti基材鍵結特性之影響
The adhesion characteristics of porcelain and titanium with ZrO2 intermediate layer
指導教授: 張煥修
Chang, Edward
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2004
畢業學年度: 92
語文別: 中文
論文頁數: 63
中文關鍵詞: 氧化鋯鍵結強度
外文關鍵詞: porcelain, ZrO2, Ti
相關次數: 點閱:62下載:1
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  • 鈦金屬由於具有高強度、優良的抗腐蝕性及生物相容性等優點,近年來在牙科方面已被廣泛的應用。但由於鈦金屬在高溫極易氧化,而形成過厚易脫落的的氧化層,使得鈦金屬在燒附陶瓷上仍面臨許多問題。
    實驗中採用不同表面處理之鈦基材和ZrO2介層的有無作為變數,以觀察鍵結強度的改變。
    比較經不同表面處理之鈦基材,實驗結果顯示酸蝕處理會降低所殘留的雜質含量,且塗層強度略微增加。
    利用電漿熔射ZrO2作為介層,並藉由4點抗彎測試塗層的鍵結強度,比較PZT塗層(porcelain/Zirconia/titanium)與PT塗層(porcelain/titanium),PZT塗層的強度明顯高於PT塗層強度,顯示ZrO2的韌化性質和所提供的較高表面粗糙度會明顯強化塗層的鍵結強度。
    利用SEM/EDS、thin-film XRD分析破壞表面,發現PZT塗層破壞主要為porcelain的內聚破壞,而PT塗層則是沿著鈦基材與porcelain的界面處,顯示界面處為塗層產生破壞時的脆弱位置。

    Owing to the material’s properties such as high strength, corrosion resistance, and biocompatibility, titanium becomes accepted in dental applications in recent years. Since titanium is easily oxidized at high temperature and a thick oxidation layer could form quickly on the surface, there are still a lot of problems with firing porcelain on the material.In this study, two different Ti surface treatments with and without a ZrO2 bond coat were varied to observe the change of bonding strength of the porcelain coating on titanium.
    The surface of Ti was treated by two different ways (sandblasting and acid-etching). The bond strength was calculated by fracture loads in 4-point bending test. The result shows that, after acid-etching treating, the titanium surface may reduce the amount of impurity and will increase the bonding strength. Plasma-sprayed ZrO2 coating was used as bond coat between porcelain and Ti substrate. The bonding strength of PZT(porcelain/ZrO2/titanium)was found significantly higher than PT(porcelain/titanium).The rationale of the improvement by introducing the intermediate ZrO2 layer was explained. SEM/EDS and thin-film XRD analyses was used to observe the fracture surface. It was found that the fracture of PZT mainly occur at porcelain, and the fracture of PT mainly occur at porcelain and Ti interface. These results indicate the interface was the weakest point in the coating.

    目 錄 中文摘要…………………………………………………Ⅰ 英文摘要………………………………………………Ⅱ 目 錄…………………………………………………Ⅲ 第一章 緒 論……………………………………………1 1-1 前 言…………………………………………1 1-2 生醫材料的分類………………………………1 1-3 金屬與陶瓷之鍵結……………………………4 第二章 理論基礎及研究目的……………………………5 2-1 鈦與鈦合金在牙科上應用……………………5 2-2 牙科陶瓷的基本性質…………………………6 2-3 陶瓷塗層/金屬複合材料………………………6 2-4 牙科陶瓷應用於鈦金屬上的問題…………8 2-5 氧化鋯………………………………………8 2-5-1 氧化鋯的性質…………………………………8 2-5-2 氧化鋯的韌化機制……………………………9 2-6 電漿熔射原理及特性…………………………10 2-7 研究目的………………………………………11 第三章 實驗流程與方法………………………………12 3-1 鈦基材處理……………………………………12 3-2 塗層試片製作…………………………………13 3-3 塗層性質測試…………………………………13 3-3-1 表面粗糙度分析………………………………13 3-3-2 塗層形態觀察…………………………………14 3-3-3 塗層/(介層)/基材間元素擴散檢測………14 3-3-4 鍵結強度測試…………………………………15 3-3-5 Thin-film XRD分析…………………………15 3-3-6 破壞面與破壞路徑分析………………………16 第四章 實驗結果 ……………………………………17 4-1 粉末分析………………………………………17 4-2 鈦基材表面處理分析…………………………18 4-3 表面粗糙度分析………………………………18 4-4 塗層橫截面觀察………………………………19 4-5 試片橫截面之EPMA分析………………………19 4-6 鍵結強度測試…………………………………20 4-7 破壞面觀察……………………………………21 4-8 破斷面thin-film XRD繞射分析…………23 第五章 結果討論……………………………………25 5-1 鈦基材表面處理的影響………………………25 5-2 影響塗層鍵結強度因素………………………26 5-2-1 影響PT塗層鍵結強度因素……………………26 5-2-2 影響PZT塗層鍵結強度因素………………27 5-3 塗層破壞路徑………………………………28 5-3-1 porcelain/Ti塗層之破壞路徑……………29 5-3-2 porcelain/ZrO2/Ti複合塗層之破壞路徑…29 第六章 結 論………………………………………30 參 考 文 獻…………………………………………31

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