| 研究生: |
陳郁雯 Chen, Yu-Wen |
|---|---|
| 論文名稱: |
不同形貌陽極氧化鋁的腐蝕特性與矽油封孔防蝕技術之研究 A study on the corrosion behavior and silicone oil sealing method of anodized aluminum oxides with various morphologies |
| 指導教授: |
鍾震桂
Chung, Chen-Kuei |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 機械工程學系 Department of Mechanical Engineering |
| 論文出版年: | 2023 |
| 畢業學年度: | 111 |
| 語文別: | 中文 |
| 論文頁數: | 90 |
| 中文關鍵詞: | 低純度鋁 、陽極氧化鋁 、複合式脈衝陽極氧化 、快速製備 、封孔技術 、抗腐蝕 、SLIPS |
| 外文關鍵詞: | Low-purity aluminum, AAO, HPA, sealing, corrosion resistance, SLIPS |
| 相關次數: | 點閱:39 下載:0 |
| 分享至: |
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現有文獻中,以陽極氧化鋁作為光滑的液體注入多孔表面(Slippery liquid-infused porous surface, SLIPS)基板通常具有以下缺點:製程時間長(2-20小時)、AAO擴孔導致機械性質下降,且通常以氟化物作為表面改質劑和潤滑油,儘管十分有效,但氟化物的成本昂貴、於高溫也有安全疑慮。
利用本實驗室開發的複合式脈衝陽極氧化(HPA)技術,可以在室溫以低純度鋁成功製備AAO,探討不同製程參數對AAO抗腐蝕性的影響,首先比較硬陽(100 V)和軟陽(40 V) 的差異,硬陽因為可以在短時間(5 min)內製備出具有足夠介電強度的氧化層,有效節省時間成本,且具有較佳的機械性質,故選做為後續實驗的參數;同時我們也研究了磷酸擴孔對AAO抗腐蝕性的影響,證實AAO結構形貌對於抗腐蝕性的影響十分微小。
而後將製備好的硬陽以熱水封孔處理,除了進一步提升硬度,勃姆石(Boehmite)會在AAO表面創建新的粗糙結構,經實驗證實新粗糙結構貯存潤滑油的能力甚至優於原本的孔洞結構。此外,本文採用價格便宜、穩定性高的二甲基矽油作為潤滑油,選擇並比較兩種容易執行的方法後,可以在短時間內一步完成AAO表面改質與潤滑油注入。
綜合以上結論,本實驗可以在短時間(50分鐘)製備出SLIPS,且腐蝕抑制效率一樣可以達到99%以上,同時具有優異的抗腐蝕性能和機械性質,於實際應用有相當大的潛力。
In this study, we compared the effects of different AAO parameters on the corrosion resistance of AAO by using the hybrid-pulse anodizing (HPA) technology. First, the difference between hard anodization (HA, 100 V) and mild anodization (40 V) was compared. Because HA can prepare an oxide layer with sufficient dielectric strength in a short time (5 min), which effectively saves time and cost, and has better mechanical properties, it is selected as the parameter for subsequent experiments. We also studied the effect of phosphoric acid pore expansion on the corrosion resistance of AAO, and confirmed that the impact of AAO structure morphology on corrosion resistance is very small. Then the prepared AAO is sealed with hot water. In addition to further improving the hardness, boehmite will create a new rough structure on the surface of AAO. It has been proved by experiments that its ability to store lubricating oil is even better than the original pore structure. Furthermore, we use cheap and highly stable silicone oil as the lubricant. After selecting and comparing two easy-to-implement methods, AAO surface modification and lubricant impregnation can be completed in one step in a short time.
Based on the above conclusions, this experiment can prepare SLIPS in a short time (50 minutes), and the corrosion inhibition efficiency can reach more than 99.9%. At the same time, it has excellent corrosion resistance and mechanical properties, and has considerable potential for practical applications.
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