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研究生: 李昌澤
Li, Chang-Tze
論文名稱: 無鉛與含鉛銲錫材料變形動力學穩態潛變行為之比較
Comparisons of Steady Creep Behavior of Pb and Lead Free Solders Using the Theory of Deformation Kinetics
指導教授: 李超飛
Lee, C.F.
學位類別: 碩士
Master
系所名稱: 工學院 - 工程科學系
Department of Engineering Science
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 84
中文關鍵詞: 無鉛銲錫變形動力學穩態潛變
外文關鍵詞: the theory of deformation kinetics, lead free solders, steady creep
相關次數: 點閱:157下載:2
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  • 應用1981年Valanis及Lee所提議之變形動力學理論,對42Sn-58Bi、96.5Sn-3.5Ag、95.5Sn-3.8Ag-0.7Cu及63Sn-37Pb四種銲錫材料,在不同溫度和應力作用下之穩態潛變率數據,決定其變形動力學本構方程式之材料參數。依前述之理論架構本文進行拉或扭應力之穩態潛變率之相互轉換,並探討變形動力學參數與含鉛量介於37%至100%之
    Sn/Pb銲錫材料關係。
    對銲錫抗潛變能力之評估,本文分別以能柵傾斜率及材料內部位移對homologous溫度(T/Tm)的敏感度進行評估 。在基體(Bulk)型態下,以63Sn-37Pb為基準對前述三種不含鉛之銲錫進行T/Tm 0.5~0.9之間抗潛變能力之比較。42Sn-58Bi在常溫時(T/Tm約在0.5~0.6左右),抗潛變能力與63Sn-37Pb相當,在高溫下(T/Tm約在0.9左右),抗潛變能力比63Sn-37Pb低。95.5Sn-3.8Ag-0.7Cu 及96.5Sn-3.5Ag兩銲材與63Sn-37Pb之抗潛變能力比較則是未定。再以不含鉛95.5Sn-3.8Ag-0.7Cu 及96.5Sn-3.5Ag兩銲材作抗潛變能力比較,則加入0.7Cu之錫銀銲材在T/Tm 0.5~0.9之間均有較好的抗潛變能力。上述評估結果均與觀查此四種銲材微觀組織圖後所做成之結果相符。

    Both Valanis and Lee to propose the theory of deformation kinetics in 1981, that decide deformation kinetics constitutive equation of solder materials (42Sn-58Bi, 96.5Sn-3.5Ag, 63Sn-37Pb, 95.5Sn-3.8Ag-0.7Cu) parameter when different temperature and stress affects of steady state creep rate data. In accordance with, this theory carcass proceed pull or twist stress steady state creep rates of mutual transformation, and confer deformation kinetics parameter with lead amount between 37% and 100% Sn/Pb solder of relationship.
    Solders are estimated in anticreep ability. This text proceed estimate by both energy barrier gradient and a material internal displacement for homologous temperature (T/Tm) of sensitivity. This 63Sn-37Pb is compared model of this three kinds of lead free solders T/Tm between 0.5 and 0.9 anticreep ability in bulk specimen.While 42Sn-58Bi has similar anticreep ability to 63Sn-37Pb solder at room temperature(T/Tm about 0.5 to 0.6), it becomes lower anticreep ability as high temperature (T/Tm about 0.9). Both 95.5Sn-3.8Ag-0.7Cu and 96.5Sn-3.5Ag solders are uncertain anticreep ability to 63Sn-37Pb solder. Compare anticreep ability of 95.5Sn-3.8Ag-0.7Cu solder and 96.5Sn-3.5Ag solder, where join 0.7%Cu batter anticreep ability at T/Tm range between 0.5 and 0.9 . A result of the above-mentioned estimate tally with microstructuralfour of four kinds solder materials point of view.

    考試合格證明 摘要 Ⅰ 誌謝 Ⅱ 目錄 Ⅲ 表目錄 Ⅵ 圖目錄 Ⅶ 符號說明 Ⅹ 第一章 緒論 1 1-1 前言 1 1-2研究動機與目的 2 1-3文獻回顧 3 第二章 變形動力學穩態潛變率方程式 6 2-1一維變形動力學理論方程式 6 2-2三維穩態潛變本構方程式 7 2-2-1單軸拉伸之穩態潛變本構方程式 7 2-2-2純剪之穩態潛變本構方程式 8 2-2-3一維與三維本構方程式之K1參數轉換 10 2-3拉/扭工程截取應力值關係式 10 第三章 拉伸、純剪潛變實驗結果與參數之決定 13 3-1 無鉛和含鉛銲材拉伸、純剪穩態潛變率之實驗數據 13 3-2 變形動力學本構方程式參數之決定 13 3-3 拉伸與純剪潛變參數之轉換 16 3-4 Energy Barrier對無鉛銲材及Sn/Pb組成比之關係 16 3-5 K2、Engineering Cutoff Stress、K1 與Sn/Pb組成比 之關係 17 3-5-1 K2 與 Sn/Pb組成比之關係 17 3-5-2 Engineering Cutoff Stress 與 Sn/Pb組成比之關 係 18 3-5-3 K1 與Sn/Pb組成比之關係 19 第四章 無鉛與含鉛銲材穩態潛變特性之比較 21 4-1無鉛與含鉛銲材 Energy Barrier對潛變率影響的比較 21 4-2無鉛與含鉛銲材K2比值對T/Tm敏感度比較 22 4-3無鉛與含鉛銲材Engineering Cutoff Stress比值對 T/Tm敏感度比較 24 4-4無鉛與含鉛銲材能柵傾斜率的比較 25 4-5無鉛與含鉛銲材K1比值對T/Tm敏感度比較 28 4-6銲材抗潛變能力綜合評估 31 第五章 結論 33 參考文獻 85 自述

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