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研究生: 陳宜群
Chen, Yi-Chun
論文名稱: 利用掃描式光電流顯微鏡探討光電元件之光響應特性
Photoresponse characteristics of photonic devices studied by scanning photocurrent microscopy
指導教授: 徐旭政
Hsu, Hsu-Cheng
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程學系
Department of Photonics
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 71
中文關鍵詞: 掃描式光電流顯微鏡光響應光電元件
外文關鍵詞: Scanning photocurrent microscopy, Photoresponse, Photonic devices
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  • 本實驗利用掃描式光電流顯微鏡(Scanning Photocurrent Microscopy,SPCM)研究光電元件的光響應特性。
    藉由掃描式光電流顯微鏡量測染料敏化太陽能電池光電流分佈,其表面光電流分不是不均勻的。在不同雷射波長入射下,可發現由於染料對於各種波長光吸收率不同,而產生的光電流量也有所不同。
    利用掃描式光電流顯微鏡量測單根SnO2奈米線元件的光電流分佈,藉由輸入不同偏壓,發現其光電流分佈有往反向偏壓電極處移動的現象,這可以證明電洞於奈米線內載子傳輸占有很重要的角色,進一步去分析奈米線光電流剖面分佈趨勢,可從中計算出電子與電洞的擴散長度。

    In this study, the photoresponse characteristics of photonic devices have been investigated by using scanning photocurrent microscopy (SPCM).
    The nonuniform distribution of photocurrents in dye-sensitized solar cells (DSSCs) was measured by SPCM. The magnitude of generated photocurrent is different at different excitation wavelength. According to the N719 absorption spectrum, the different magnitude of photocurrent is attributed to the different absorption of N719 dye at different wavelength.
    We investigated the photoresponse characteristics of single SnO2 nanowire device by scanning photocurrent microscopy. The maximum photocurrent position shifts toward the hole collector (negatively biased electrode) with increasing bias voltage, indicating that hole collection is the limiting factor in the total charge collection process. The photocurrent profile along the single SnO2 nanowire can decide the diffusion length of electrons and holes.

    摘要 Ⅰ Abstract Ⅱ 致謝 Ⅲ 章節目錄 Ⅳ 圖目錄 Ⅵ 表目錄 Ⅸ 第一章 緒論 1.1 文獻回顧 1 1.2 研究動機 10 1.3 論文大鋼 10 第二章 基礎理論 2.1 染料敏化太陽能電池理論 11 2.1.1 染料敏化太陽能電池結構 11 2.1.2 染料敏化太陽能電池工作原理 12 2.1.3 多孔性二氧化鈦 14 2.1.4 電解液 14 2.1.5 對電極 15 2.1.6 染料敏化劑 16 2.2 半導體光偵測器理論 17 2.2.1 SnO2二氧化錫特性 17 2.2.2 光的吸收 17 2.2.3 金屬與半導體接面理論 19 2.2.4 持續性光電流傳導效應 19 第三章 實驗架構 3.1 掃描式光電流顯微鏡 20 3.1.1 光學顯微鏡 23 3.1.2 雷射擴束系統 25 3.1.2.a 有無擴速系統刀口法實驗比較 28 3.1.2.b 未擴束前雷射光點大小量測 30 3.1.2.c 擴束後雷射光點大小量測 31 3.1.2.d 不同入射光點大小之空間解析度比較 32 3.1.3 鎖相放大器 33 3.1.4 電流計36 3.2 掃描式電子顯微鏡 37 第四章 數據與討論 4.1 利用掃描式光電流顯微鏡掃描染料敏化太陽能電池 38 4.2 利用掃描式光電流顯微鏡掃描單根SnO2奈米線元件 46 4.2.1 SnO2奈米線元件電流對電壓曲線量測 48 4.2.2 SnO2奈米線元件光響應特性量測 49 4.2.3 利用掃描式光電流顯微鏡量測SnO2奈米線之光電流(1) 51 4.2.4 利用掃描式光電流顯微鏡量測SnO2奈米線之光電流(2) 56 4.2.5 利用掃描式光電流顯微鏡量測SnO2奈米線之光電流(3) 63 第五章 結論與展望 5.1 結論 66 5.2 未來展望 67 第六章 參考文獻 參考文獻 68

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