| 研究生: |
戴伯勳 Tai, Bo-xun |
|---|---|
| 論文名稱: |
添加磷酸對瀝青混凝土成效影響之研究 Effect of Phosphoric Acid on the Performance of Asphalt Concrete |
| 指導教授: |
蕭志銘
Shiau, Jih-min |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 土木工程學系 Department of Civil Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 88 |
| 中文關鍵詞: | 瀝青混凝土 、磷酸 、改質劑 |
| 外文關鍵詞: | Modification, Phosphoric Acid, Asphalt Concrete |
| 相關次數: | 點閱:80 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
酸(acid)作為瀝青的改質劑能夠改善瀝青的溫感性,擴大瀝青使用的溫度範圍,增加瀝青的勁度(stiffness)以防止瀝青混凝土鋪面產生車轍;最近有研究指出添加磷酸(Phosphoric Acid)能夠增加瀝青在高溫時的勁度,但是與其他的改質劑相比,目前關於酸改質劑(acid modification)的資訊與研究還是相當有限。
本研究以AC-20為基底瀝青,磷酸作為改質劑,研究添加磷酸對瀝青膠漿性質的影響,並以磷酸改質瀝青製作馬歇爾試體,研究添加磷酸對瀝青混凝土成效的影響。
由試驗結果得知,添加磷酸確實能有效的增加瀝青膠漿的勁度,但是也會加速瀝青膠漿的老化;由於添加磷酸對瀝青膠漿有加勁的效果,所以添加磷酸後,瀝青混凝土的承載力、抵抗車轍變形能力、抗張強度和抗磨損能力都有所提升。然而添加磷酸也會降低瀝青混凝土抗水侵害的能力,磷酸的添加量越多,瀝青混凝土水侵害的情形越嚴重,所以根據試驗結果,建議磷酸可以添加到2%左右。
Acid can be used to improve asphalt temperature susceptibility, expand the temperature range that the asphalt uses, increase the asphalt stiffness in order to prevent rutting of the asphalt concrete. Recent studies showed that add the Phosphoric Acid could increase the asphalt stiffness at high temperatures, but the information and research of acid modification was still quite limited at present.
This study used AC-20 as the basis asphalt and Phosphoric Acid was used as a modifier to evaluate effect of Phosphoric Acid on the properties of asphalt, Marshall samples were fabricated with Phosphoric Acid modified asphalt to study effect of Phosphoric Acid on the performance of asphalt concrete.
According to result of tests, adding the Phosphoric Acid would increase asphalt stiffness, but would accelerate the asphalt aging. Because adding the Phosphoric Acid would increase asphalt stiffness, the resistance of rutting, tensile strength and the resistance of wearing of asphalt concrete were all improve. But the resistance to moisture damage was reduced. Results of the tests, showed that Phosphoric Acid could be added about 2%.
方楷逸,「改質瀝青應用於排水級配之抗水侵害研究」,國立成功 大學研究所碩士論文,台南,2002。
林桂儀,「評估不同添加料對瀝青混凝土之影響」,國立成功大學研究所博士論文,台南,2006。
林樹豪,「老化作用對瀝青質流性質之影響」,國立成功大學研究所碩士論文,台南,1993。
許聖國,「瀝青及改質瀝青老化速率模式之探討」,國立成功大學研究所碩士論文,台南,1999。
陳俐如,「改質瀝青老化與再利用之研究」,國立成功大學研究所碩士論文,台南,2005。
Ajideh, H., Rangel, A., and Bahia, H., “Can chemical modification of paving asphalts be equated to polymer modification? A laboratory study,” Transportation Research Record, n 1875, p 56-69 (2004).
Alexander, S.H., U.S. Patent #3,751,278, (1973).
Bell, C.A., Aging of Asphalt-Aggregate Systems, Report No.SHRPA-305 (1989).
Branthaver, J.F., Petersen, J.C., Robertson, R.E., Duvall, J.J., Kim, S.S., Harmaberger, P.M., Mill T., Ensley, E.K., Barbour, F.A., Schabron, J.F., “Binder Characterization and Evaluation,” Report No.SHRP-A-368 (1993).
Chiu, C., Tia, Mang., Ruth, B.E., and Page, G.C., “Investigation of Laboratory Aging Processes of Asphalt Binder Used in Florida,” Transportation Research Record 1436, pp.60-70 (1994).
Chollar, B., Kumari, D., Zenewitz, J., and Boone, J., “Chemical Modification of Asphalts”, preprints, Chemistry and Characterization of Asphalt Symposia, American Chemical Society, Volume 35, No. 3, July, pp 531-540 (1900).
Culley, R.W., “Relationships Between Hardening of Asphalt Saskatchewan, ” Journal of the Association of Asphalt Paving Technologists, Vol.38, pp.629-659 (1969).
Fabb, T.R.J. Quiet revolution. Highways, Jan./Feb.,20-25(1995).
George L.C., Encyclopedia of Chemistry, 2nd ed., Van Norstrand Co., New York, p 105 (1996).
Kandhal, P.S., and Chakraborty, S., “Effect of asphalt film thickness on short- and long-term aging of asphalt paving mixtures,” Transportation Research Record, n 1535 , p 83-90 (1996).
King, G., Bishara, S.W., and Fager, G., “Acid/base chemistry for asphalt modification,” Asphalt Paving Technology: Association of Asphalt Paving Technologists-Proceedings of the Technical Sessions, v 71, p 147-175 (2002).
Lu, X., and Isacsson, U., “Effect of Ageing on Bitumen Chemistry and Rheology,” Construction and Building Materials, Vol.16, pp.15-22 (2002).
Lu, X., and Isacsson, U., “Chemical and rheological Evaluation of ageing properties of SBS polymer modified bitumens,” Fuel, Vol.77, No.9/10, pp.961-972 (1998).
Mirza, M.W., and Witczak, M.W., “Development of a Global Aging System for Short and Long Term Aging of Asphalt Cements, ”Journal of the Association of Asphalt Paving Technologists , Vol.64, pp.393-430 (1995).
Petersen, J.C. “Effects of physico-chemical factors on asphalt ageing,” Proceedings of the 1st Materials Engineering Congress, American Society of Civil Engineering, pp.224~253 (1990).
Roberts, F.L., Kandhal, P.S., Brown, E.R., Lee, D.Y., and Kennedy, T.W., Hot Mix Asphalt Materials,Mixture Design, and Construction, NAPA Education Foundation, Second Edition ,Lanham, Maryland (1996).
Traxler, R.N., “Relation Between Asphalt Composition and Hardening by Volatilization and Oxidation,” Journal of the Association of Asphalt Paving Technologists, Vol.30, pp.359-377 (1961).