| 研究生: |
沈倉輝 Shen, Tsang-Huei |
|---|---|
| 論文名稱: |
重質油氣化爐之數值模擬與設計 Numerical Simulation and Design of Heavy Oil Gasifier Chamber |
| 指導教授: |
邱輝煌
Chiu, Huei-Huang |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 航空太空工程學系 Department of Aeronautics & Astronautics |
| 論文出版年: | 2004 |
| 畢業學年度: | 92 |
| 語文別: | 中文 |
| 論文頁數: | 97 |
| 中文關鍵詞: | 噴流床式氣化爐 、重質油 、氣化 、合成氣 |
| 外文關鍵詞: | heavy oil, entrained-flow gasifier, gasification, syngas |
| 相關次數: | 點閱:55 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
重質油氣化複合循環發電系統(IGCC)在改善熱效率、減少溫室氣體排放、以及燃料的多選擇性上之實際使用一直被人們寄予厚望。於是本論文研究主題為探討乳化重油ORIMULSION,其在噴流床式氣化爐中之氣化特性。初步先假設進口燃料為ORIMULSION高溫熱解(Pyrolysis)後之主要物質:CH4、H2O、CO、CO2、H2及C。目的在觀察及比較在經過整體氣化反應後,爐內溫度分佈及出口合成氣(Syngas)組成。在假設碳為氣態以及固定燃料供給量下,我們分別使用不同供氧量,紊流模式,壁面溫度及操作壓力為操作條件。研究發現,若增加氧化劑,會導致H2及CO產量減少,CO2增加,且對H2O影響不大。而使用DSM紊流模式下,H2O產量會有明顯的增加,且會計算出較慢的紊流混合速率。同時增加壁面溫度對合成氣產量影響不顯著。而操作壓力在1.8MPa下就可以達到預計的效果。
The practical use of Integrated extra heavy oil Gasification Combined Cycle (IGCC) power generation is expected from the viewpoints of the improvement of thermal efficiency, the decrease in emission of greenhouse gases, the fuel diversification, and the cost decrease, etc. The theme of studying in this thesis lies in probing into the emulsified heavy oil named ORIMULSION gasification characteristic in the entrained-flow gasifier. Tentatively, suppose the fuel imported as ORIMULSION composition after pyrolysis: CH4、H2O、CO、CO2、H2 and C. The purpose lies in observing and comparing the distribution of temperature in the chamber and the composition of syngas exported after the global gasification reactions finish. Furthermore, suppose gaseous carbon and fixed fuel supply, respectively we use different oxygen supply , turbulence model , wall temperature and operation pressure as operation conditions. The result of study shows: When increasing the oxidant supply, it will cause the reduction of H2 and CO and increase of CO2 in the exit, and it also have a little effect on H2O. If DSM turbulence model is enabled being used for calculating, then H2O will increase in a large amount obviously and calculate out slower turbulence mixing speed. The way to increase wall temperature does not have obvious influence on syngas exported at the same time. And operation pressure can get the ideal result of estimating at 1.8MPa.
【1】 R. Brewer , The Science of Ecology. 2nd ed., Saunders College Publishing, New York, 1994. pp.28.
【2】 S. Boyden , Biohistory: The Interplay Between Human Society and the Biosphere. Past and Present. United Nations Educational Scientific and Cultural Organization, Man and the Biosphere series, Vol.8, The Parthenon Publishing Group, Carnforth ,1992.
【3】 W.B. Clapham, Human Ecosystems, Clevand, Ohio ,1981.
【4】 郭博堯, 世界天然氣發展情勢,國政研究報告,2001
【5】 http://www.npf.org.tw/
【6】 R.H. Quig, L. Woodworth, “Clean power generation resulting from Orimulsion utilization”, Proceedings of the 22nd International Technical Conference on Coal Utilization and Fuel Systems, Clearwater,FL,16-19, 1997.
【7】 K. Olen, Orimulsion, in opportunity fuels guidebook , EPRI Technical Report TR-111487, Electric Power Research Institute, Palo Alto,1998.
【8】 R.H. Quig, “Orimulsion ash processing alternatives”, the 24th International Technical Conference on Coal Utilization and Fuel Systems, Cleanwater, FL, 1999
【9】 http://www.icheme.org
【10】 煤炭氣化技術及淨化技術之研究,台電電力綜合研究所報告,1994。
【11】 氣化複循環發電技術引進的策略規劃,工研院能資所報告,1994。
【12】 http://www.gasification.org/
【13】 http://members.tripod.com/~cturare/his.htm
【14】 http://www.netl.doe.gov/coalpower/gasification/
description/gasifiers.html
【15】 Joseph, Dennis, Lipscombe, Errey, F.Fletcher, B.S.Haynes, The development and testing of an air/steam blown entrained flow gasifier fueled with cotton waste and sawdust, in: Proceeding of USA Bioenergy 96 Conference, Nashville, Tennesse, USA, September 1996.
【16】 D.F. Fletcher, B.S. Haynes, J. Chen , S.D. Joseph, “ Computational fluid dynamics modeling of an entrained flow biomass gasifier ”, Appli. Math. Modelling, Vol.22, pp.747-757, 1998.
【17】 D.F. Fletcher, B.S. Haynes, F.C. Christo , S.D. Joseph, “A CFD based combustion model of an entrained flow biomass gasifier”, Appli. Math. Modelling, Vol.24, pp.165-182, 2000.
【18】 超重質油氣化爐數值解析技術之開發,日本電力中央研究所報告,2000年。
【19】 M. Ashizawa et al., July 2000,Development of a Research Gasifier for New Kind Liquid Fuel –Aiming at the Establishing of the Know-how of the Design and Operation for Gasifier-,CRIEPI Report W00003.
【20】 S. Hara et al., March 2001, Study on Gasification Characteristics for Extra Heavy Oil –Examination of a Gasification Reaction in Gasifier-, CRIEPI Report W00015.
【21】 http://ge-rd-info.denken.or.jp/ge-leaflet/pdf/ W01023.pdf
【22】 H. Watanabe, M. Otaka, S. Hara, M. Ashizawa, K. Kidoguchi, J.Inumaru, “Modelling and simulation for extra heavy oil gasification on entrained flow gasifier”, 2002 International Joint Power Generation Conference, Phonenix, AZ, USA, 2002.
【23】邱輝煌、蔡欣倫,“重質油氣化爐數值模擬與設計”,第四屆淨潔能源國際研討會,經濟能源委員會,國立成功大學能源中心,台南台灣,中華民國九十二年十二月四日。
【24】邱輝煌、蔡欣倫, “化石能源淨潔利用技術研發及推廣(4/5)計 畫”,子計畫四部分,經濟能源委員會年度報告書,國立成功大學能源中心,中華民國九十二年十二月。
【25】 CFX 4.4 Flow Solver: User Guide, CFX International, AEA Technology, Harwell Laboratory, Didcot, Oxfordshire, UK, 2000.
【26】 B.E. Launder, B.I.Sharma, “Application of the energy dissipation model of turbulence to the calculation of flow near a spinning disc ”, Letters in Heat and Mass Transfer, Vol.1, pp.131-138, 1974.
【27】 B.E. Launder, D.B. Spalding, “The numerical computation of turbulent flow”, Computer Methods in Applied Mechanics and Engineering, Vol.13, pp.269-289, 1974.
【28】 B.E. Launder, G.J.Reece, W.Rodi, “Progress in the development of a Reynolds-stress turbulence closure”, Journal of Fluid Mechanics, Vol.68, pp.537-566, 1975.
【29】 C.A. Miller, R.K. Srivastava, ”The combustion of Orimulsion and its generation of air pollutants”, Progress in Energy and Combustion Science,Vol.26,pp131-160,2000
【30】 李繼強,燃料與燃燒,大中國圖書公司,民國九十年。
【31】 Peter M. Maly, Vlamidir M. Zamansky, Loc Ho & Roy Payne, “ Alternative Fuel Reburning”, Fuel, Vol.78, pp327-334, 1999.
【32】 Taisuke Maki, Kouichi Miura, “A simulation model for the pyrolysis of Orimulsion”, Energy & Fuel, Vol.11, pp819-824, 1997.
【33】 D. Merrick, Coal combustion and conversion technology, Elsivier, New York, 1984.
【34】 http://www.iea-coal.org.uk
【35】 J.A. Arther, “Reaction between carbon and oxygen”, Trans. Faraday Society, Vol.47, pp164-178,1951
【36】 X.J. Liu, W.R. Zhang, T.J. Park, “Modelling coal gasification in an entrained flow gasifier”, Combustion Theory and Modelling, Vol.5, pp.595-608, 2001.
【37】 L.D. Smoot, D.T. Pratt, Pulverized-Coal Combustion and Gasification, Plenum Press, New York, 1979.
【38】 W.P. Jones, R.P. Lindstedt, “Global reaction schemes for hydrocarbon combustion ”, Combustion and Flame, Vol.73, pp.233- 249, 1988.
【39】 C.K. Westbrook, F.L. Dryer, “Simplified reaction mechanisms for the oxidation of hydrocarbon fuels in flames”, Combustion Science and Technology, Vol.27, pp.31-43,1981.
【40】 H. Susanto, A.A.C.M. Beenackers, “A moving bed gasifier with internal recycle of pyrolysis gas”, Fuel, Vol.75, pp.1339-1347,1996.
【41】 Y.C. Choi, X.Y. Li, T.J. Park, J.H. Kim, J.G. Lee, “Numerical study on the coal gasification characteristics in an entrained flow gasifier”, Fuel, Vol.80, pp.2193-2201, 2001.
【42】 P.K. Gururajan, P.K. Agarawal, J.B. Agnew, “Mathematical modeling of fluidized bed coal gasifiers”, Trans. IchemE, Vol.70, pp.211-238, 1992 .
【43】 J.R. Bakke, B.H. Hjertager, “The effect of explosion venting on empty vessels”, Int. J. Num. Meth. Eng., Vol.24, pp.129-140, 1987.
【44】 B.E. Magnussen, B.H. Hjertager, “On mathematical modelling of turbulent combustion with special emphasis on soot formation and combustion ”, Proceeding 16th Symposium(International) on Combustion, The Combustion Institute, pp.719-729, 1976.
【45】 http://criepi.denken.or.jp/eng/PR/Nenpo/2000E/00sets ubi4.