本篇所探討的主題是製備條件對活性碳纖維及所吸附鈷之物性和化性的影響。製備條件包括酸洗、溶劑、氧化等，鑑定技術包括TG-MS、Physisorption、SEM/EDX、ESCA等，並以程溫反應測試樣品催化N2O分解的活性。
我們發現，酸洗使活性碳纖維的雜質量由2.65wt%降至0.68wt%，但未明顯的改變活性碳纖維表面積、孔洞體積和吸附鈷量。乙醇製備的樣品比起水製備的樣品具較高的吸附鈷量。在乙醇製備的樣品裡，鈷均勻地分佈在活性碳纖維內外；在水製備的樣品裡，鈷在活性碳纖維上的分佈為內少外多；在乙醇製備再經由水洗的樣品裡，鈷在活性碳纖維上的分佈為內多外少。孔洞分析儀的結果顯示，氧化造成重量及孔洞的損失，而鈷會使得在30Å附近的孔洞降的量較少。對N2O的催化分解，以乙醇製備的樣品具最佳活性。

We study the effect of preparation conditions on physical and chemical properties on activated carbon fiber(ACF),and cobalt adsorbed on activated carbon fibers. The conditions include acid-wash, solvent and oxidation etc., Characterization techniques include TG-MS, SEM/EDX, Physisorption etc., we measure the activity of the sample that catalyze N2O decomposition as well.
We found that acid-wash of ACF decrease the impurities from 2.65wt% to 0.68wt%, and activated carbon fiber’s surface area,pore volume and adsorption capacity for cobalt have insignificant change. The sample that prepared from ethanol has higher amount of adsorption for cobalt than the sample prepared from water.For the sample prepared from ethanol, cobalt distributed evenly on ACF; For the sample prepared from water, the outer part of activated carbon fiber have higher amount of cobalt than the inner part;For the sample prepared from ethanol but washed with water afterword, the inner part of ACF have higher amount of cobalt than the outer part. The results of Nitrogen adsorption isotherm reveal that oxidation cause loss of weight and pore volume, the presence of cobalt maintain the pore of ACF near 30Å. For N2O decomposition, the sample prepared from ethanol has the best activity.

1.A.Shindo，Studies on Graphite Fibers，Rep.Government Industr.Res. Inst. Osaka.No.317(1961)
2.J. W. Johnson et al.，Brit. Pat.1，110，791(1968)
3.W. Watt&W. Johnson，Proc.3rd Conf. On Ind. Carbon and Graphite，Soc.Chem.Ind.，London，1971，p.417
4. N.Grassie and J. N. Hay，J. Polymer Sci.，56，189(1962)
5. N. Grassie and R. McGuchan ，European Polymer J.，7，1503(1971)
6. N. Grassie and R. McGuchan ，European Polymer J.，8，257(1972)
7. N. Grassie and R. McGuchan ，European Polymer J.，8，865(1972)
8. N. Grassie and R. McGuchan ，European Polymer J.，9，113(1973)
9. E.Fitzer and D.J. Muller，Carbon，13，63(1975)
10.O.P.Bahl and L.M> Manocha，Carbon，12，417(1974)
11. O.P.Bahl and B.B. Mathur，Fiber Sci. and Tech.，12，31(1979)
12. L.M. Manocha and O.P. Bahl ，Fiber Sci. and Tech.，13，199(1980)
13. S.B. Warner ，L.H.Peebles Jr.，D.R.Uhlmann，J. Mteri. Sci.，14，556(1979)
14. S.B. Warner ，L.H.Peebles Jr.，D.R.Uhlmann，J. Mteri. Sci.，14，565(1979)
15. S.B. Warner ，L.H.Peebles Jr.，D.R.Uhlmann，J. Mteri. Sci.，14，1893(1979)
16. S.B. Warner ，L.H.Peebles Jr.，D.R.Uhlmann，J. Mteri. Sci.，14，2764(1979)
17.W. Watt and W. Johnson，Nature，257，210(1975)
18.V.Raskovic and S.Marinkovic，Carbon，16，351(1978)
19.O.P. Bahl et al.，Fiber Sci. and Tech.，13，155(1980)
20. Juntgen， H.，Fuel 65，1436（1986）
21. van der Lee，G.，Bastein，A. G. T. M.，van der Boogert， J.，Schuller，B.，Luo，H. Y.，and Ponec，V.，J.Chem. Soc. Faraday Trans. I，83，2103（1987）
22. Lin，Y. J.，Resasco，D.E.，and Haller，G.L.，J.Chem.Soc. Faraday Trans. I，83，2091（1987）
23. Ross，R.A.，Fairbridge，C.，and MacCallum，J.R.，carbon 23，209（1985）
24. Vodyankin, A. Yu.; Kurina, L. N.; Popov, V. N. (Russia). Zh. Fiz. Khim., 73(3), 572-574 (Russian) MAIK Nauka.1999
25. Güldür, Çigdem; Balikçi*, Filiz.，International Journal of Hydrogen Energy Volume: 27, Issue: 2, February, pp. 219-224（2002）
26.J.W. Johnson，Appli. Polym. Symp.，No.9，229(1969)
27.G.A.Cooper and R.M. Mayer，J.Mater.Sci.，6，60(1971)
28.E. Fitzer et al.，Carbon，24，387(1986)
29. Chong, P.J.; Stakheev, A.Yu.; Lee, C.W.; Park, S.J. Applied Catalysis B: Environmental Volume: 9, Issue: 1-4, September 2 , pp. 65-76，1996
30.G.N.Arons and R.N. Macnair，Textile Research J.，JAN，60(1972)
31.G.N.Arons et al.，Textile Research J.，SEP，539(1973)
32.R.Y.Lin and J. Economy，Applied Polymer Symposium，No.21，143(1973)
33. G.N.Arons et al.，Textile Research J.，NOV，874(1974)
34.J.Economy and R.Y.Lin，Applied Polymer Symposium，No.29，199(1976)
35.L.B. Adams and E.A. Bouchar，Carbon，16，75(1978)
36.U.S.Patent 4，256，607(1981)
37. U.S.Patent 4，362，646(1982)
38. U.S.Patent 4，412，937(1983)
39. U.S.Patent 4，460，650(1984)
40.S.F. Grebennikov and L.I. Fridman，Khimicheskie Volokna No.6，14(1987)
41.Ismail M.K. Ismail，Carbom，25，653(1987)
42. 趙承琛: 界面科學基礎, PP.19-31, 7th ed.,復文書局, 1985
43. McCabe,W.L.,J.C. Smith and Harrit,:Unit Opera of Chemical Engineering, McGraw-Hill Inc.,1985
44. Chi,Chiang Whan,:Dynamic of Fixed Bed Bed Adsorbers, Illinois Insititute of Tech.,1968
45. Tang,Shin-Ru,:Prediction Equillbria for Gasphase adsorption of Volatile Organic Compounds:the Imapct of Relative Humidity and Multi compoent Interactions, Master Thesis of Michigan Technology Univ.,1986
46. Solomans,T.W.Graham,:Organic Chemistry,P.81,3rd.ed.,John Wiley & Sons,Inc.,1984
47. 蔣本基, 張璞:利用廢棄污泥研製吸附劑以去除有機蒸氣之研究, 國立臺灣大學環境研究所研究報告(II),No.128,75年
48. 尤建華: 利用廢棄物研製吸附劑以去除有機溶劑蒸氣之可行性研究, 國立臺灣大學環境工程研究所碩士論文, 民國73年
49. Dubinin,M.M. and H.F. Stoeckli,:Homogeneous and Heterogeneous Micropores Structures in Carbonaneous Adsorbents, J.Colloid Interface Secience, Vol.75,P.134,1980
50. Langumir,I.J.:Aner.Chem.Soci.,38,222,1976
51. Brunauer,S.,P,Emmet and Teller E.J.,:Amer.Chem.Soci.,60,309,1938
52. 葉和明: 單元操作(下) ,三民書局, 民國72年
53. Urano et.al.,:Prediction Method for Adsorption Capacities of Organic Vapors, E.S.&T., Vol13,No.1,P10,1981
54. Seasone et.al.,:Prediction of Removal Vapors from Air by Adsorption on Activated Carbons in Removal of Organic Vapors E.S.&T., Vol.13,No.12,P1511,1979
55. Suzuki.M. and A.Sakoda,:Gas Adsorption on Activated Carbon with Size Distribution of Micropores, J. of Chem. Eng. of Japan,P.279,Vol.15,No.2,1982
56. Liptak,:Enviromental Engineering Handbook, Vol.2,Chilton Book Company,Randor,Pen,1974
57. Gregg,S.J. and K.S.W. Sing,:Adsorption,Surface Area and Porosity, Academic Press., London and New York,1969
58. Stern.,:Air pollution, Vol.4,3rd ed.
59. Scamehorn,J.F.,:Removal of Vinyl Chloride from Gaseous Streams by Adsorption on Activated Carbon,Ind.Eng.Chem.Process Des,Ddev., Vol.18,No,2
60. Werner,M.D.,:The Effects of Relative Humidity on the Vapor Phase Adsorption of Trichloroehtylene by Activated Carbon, Am.Ind.Hyg.Assoc.J., Vol.46,No.10,P.585,1985
61. Ackley,M.W.,:Residence Time Model for Rersprator Sorbent Beds, Am.Ind.Hgy.Assoc.J., Vol.46No.11,1985
62. Kenson,R.E.,:Recovery and Reuse of Solvent from VOC Air Emmissions,Env.Progress,Vol.4,No.3,P.161,1985
63. I.Mochida，Y.Korai，M.Shirahama，S.Kawano，T.Hada，Y.Seo，M.Yoshikawa，A.Yasutake，Carbon 38（2000）227
64. Mcleod,A.I. and S.C.Mcbeath,:Charcoal Cloth in Order Related Adsorption, Firtration and Seperation,P.164, May/Jun,1986
65. Kuro-Oka,M.,T.Suzuki,T.Nitta and T.Katayama,:Adsorption Isotherm of Hydrocarbons and Carbon Dioxide on Activated Fiber Carbon, J.of Chem. Eng.of Japan,P.588,Vol.17, No.6,1984
66. Suzuki, M., ”Activated Carbon Fiber ： Fundamentals and Application”,Carbon,32,577(1994)
67. Suzuki ,M., “Application of Fiber Adsorbents in Water Treatment” , Water Sci.Technol.,23,1649,(1991)
68. Yang,M.C. and D.G.Yu.,”Catalytic Oxidation of Sulfur Dioxide on Polyacrylonitrile-Base Active Hollow Carbon Fiber”, J. App. Poly.Sci. , 62,2287(1996)
69. Arons,G,N.,Macnair,R N.,Coffin,L.G. and Hogan,H.D.,”Sorptive Textile Systems Containing Activated Carbon Fibers” , Textile.Res.J. , 44,874(1974)
70. Brasquet,C. and P.Le Cloirec,”Adsoption onto Actived Carbon Fibers: Application to Water and Air Treatments” , Carbon. , 35 , 1307 – 1313 (1997)
71. Jin,H.,S.E. Park.,J. M.Lee., and S.K. Ryu.,”Shape-selectivity of Activated Carbon Fibers as a Palladium Catalyst Support”,Carbon .,34 , 429 (1996)
72.Sakoda，A.，M.Suzuli.，R.Hirai.，and K. Kawano.，”Trihalomethane Adsorption on Activated Carbon Fibers”，Water Res.，25，219（1991）