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研究生： 張哲偉
Chang, Che-Wei
論文名稱： Zn-25Sn-xTi (x=0-0.06)高溫無鉛銲錫之微結構與機械性質之研究
The Microstructure and Mechanical Properties of Zn-25Sn-xTi(x=0-0.06) High Temperature Pb-free Solder
指導教授： 林光隆
Lin, Kwang-Lung
學位類別： 博士
Doctor
系所名稱： 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年： 2020
畢業學年度： 108
語文別： 中文
論文頁數： 136
中文關鍵詞： 高溫無鉛銲錫 、晶粒細化 、拉伸性質 、剪力性質
外文關鍵詞： High-temperature lead-free solder, grain refinement, tensile properties, shear properties
相關次數： 點閱：108  下載：0 
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    • 本研究主要探討鈦含量對Zn-25Sn銲錫合金組織與性質之影響，包括Zn-25Sn-xTi(x=0-0.06 wt%)銲錫的微觀組織、不同溫度之拉伸性質以及剪力性質等。Zn-25Sn銲錫的微觀組織分析顯示，基地呈現長板狀的富鋅相以及Sn-Zn共晶組織；添加Ti為Zn-25Sn提供許多成核位置，並抑制富鋅相的晶粒尺寸;添加Ti會改善其韌性以及延展性；在室溫下的拉伸試驗結果顯示，Zn-25Sn-0.02Ti呈現最大的伸長率和最佳的韌性，分別為37%以及21.17 MJ/m3。在80 ºC，100 ºC和120 ºC環境溫度之拉伸實驗結果顯示，隨著環境溫度的增加銲錫合金的強度會下降而延展性會上升，相較於室溫下的結果，Ti元素對銲錫合金有相同的趨勢，Zn-25Sn-0.02Ti銲錫在所有測試溫度下均表現出最大的延展性。Ni/Zn-25Sn/Ni接合面的微觀組織是由富鋅相和Sn-Zn共晶組織以及界面的Ni5Zn21介金屬化合物所組成;添加Ti對於Ni/Zn-25Sn-xTi/Ni銲錫在25°C的剪力強度影響不大(變化僅3%)，但是在25°C和100°C均呈現比Pb-5Sn / Ni銲錫接點更優異的剪力強度。

    This studydiscusses the effect of Ti content on the structure and properties of the Zn–25Sn solder alloy, including the microscopic structure of Zn–25Sn–xTi (x = 0–0.06 wt%) as well as its tensile and shear properties at different temperatures. The microscopic structure analysis of the Zn–25Sn solderrevealed a plate-like Zn-rich phase and a Sn–Zn eutectic structure. Ti was added to provide nucleation sites in Zn-25Sn and inhibit grain size in its Zn-rich phase. The toughness and ductility of the solder increased with Ti content. The results of the environmental-temperature tensile tests indicate that the Zn–25Sn–0.02Ti solder exhibited the highest elongation (37%) and toughness (21.17 MJ/m3) among all compositions. The strength and ductility of the solder alloys decreased and increased, respectively, with respect to an increase in environmental temperature in the range of 80oC to 120oC. The same results were observed with an increase in Ti content; the Zn–25Sn–0.02Ti specimen exhibited the highest ductility at all the test temperatures. The microscopic structure of the Ni/Zn-25Sn/Ni joint was composed of a Zn-rich phase, a Sn–Zn eutectic structure, and the Ni5Zn21 intermetallic compound. At 25°C, Ti content did not significantly affect the shear strength of the Ni/Zn–25Sn–xTi/Ni specimen (only by 3%). However, at both 25°C and 100°C, the Ni/Zn–25Sn–xTi/Ni specimen exhibited superior shear strength to that of Pb–5Sn/Ni.

    摘要 I EXTENDED ABSTRACT II 總目錄 XIII 表目錄 XVI 圖目錄 XVII 第一章 緒論 1 第二章 文獻回顧 4 2-1電子產品的高溫需求 4 2-2高溫銲錫的應用 4 2-3高溫無鉛銲錫的性質需求 5 2-4高溫無鉛銲錫合金系統 10 2-4-1金錫合金系統 10 2-4-2鉍銀合金系統 14 2-4-3鋅基合金系統 18 2-5材料機械性質分析 20 2-6高溫無鉛銲錫合金機械性質的比較 23 2-7晶粒細化方法 32 2-8研究動機與規劃 33 第三章 實驗步驟 35 3-1鋅錫鈦三元銲錫之配製 35 3-1-1石英封管 35 3-1-2銲錫鑄造 35 3-2鋅錫鈦三元銲錫合金之微觀組織觀察 36 3-3機械性質試驗 38 3-3-1拉伸試驗 38 3-3-2剪力試驗 38 3-4高溫無鉛銲錫之熱性質分析 40 3-5奈米壓痕試驗 40 第四章 結果與討論 44 4-1 ZN-25SN-XTI銲錫的熱性質分析 44 4-2鋅錫鈦銲錫合金的微觀組織分析 47 4-2-1爐冷鋅錫鈦銲錫合金的微觀組織 47 4-2-2鈦錫鋅三元介金屬化合物的分析 58 4-2-3鋅錫鈦銲錫共晶相分析 61 4-3鋅錫鈦銲錫在室溫下的拉伸試驗分析 62 4-3-1降伏強度(0.2% yield stress) 62 4-3-2最大抗拉強度以及平均延展性 63 4-3-3韌性(Toughness) 67 4-3-4微觀組織對銲錫拉伸性質的影響 69 4-3-5破斷面分析 70 4-3-6鋅錫鈦銲錫過冷度的分析 71 4-4 鋅錫鈦銲錫在高溫下的拉伸行為 77 4-4-1溫度對機械性質的影響 77 4-4-2微觀組織對銲錫拉伸性質的影響 79 4-4-3銲錫高溫拉伸的破斷行為 84 4-5ZN-25SN-XTI銲錫與NI基板接合的機械性質 92 4-5-1銲錫與Ni基板接合的微觀組織 92 4-5-2銲錫接點間化合物的組成分析 93 4-5-3銲錫與基板之間的介金屬化合物組織分析 100 4-5-4銲錫接點在不同環境溫度下的剪力試驗 102 4-5-5銲錫接點破壞形貌 108 第五章 結論 118 參考文獻 121 附錄1 134 附錄2 135 CURRICULUM VITAE (CV) 136

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