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研究生：	朱韻文 Chu, Yun-Wen
論文名稱：	CuInS2奈米管-氧化鋅複合薄膜之製備與其應用於全固態無機太陽能電池之研究 Formation of CuInS2 Nanotube-ZnO Nanoparticle Composite Films for Use in Solid-state Inorganic Solar Cells
指導教授：	吳季珍 Wu, Jih-Jen
學位類別：	碩士 Master
系所名稱：	工學院 - 化學工程學系 Department of Chemical Engineering
論文出版年：	2010
畢業學年度：	98
語文別：	中文
論文頁數：	91
中文關鍵詞：	CuInS2 奈米管陣列、氧化鋅複合薄膜、全固態無機太陽能電池
外文關鍵詞：	CuInS2 nanotube arrays, ZnO composite films, Solid-state inorganic solar cells
相關次數：	點閱：83 下載：0
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本研究以連續離子吸附與反應法合成CuInS2奈米管，並在CuInS2奈米管間隙之間成長氧化鋅奈米粒，以形成一CuInS2 奈米管-氧化鋅奈米粒複合薄膜。其中成長氧化鋅複合薄膜的製程有兩種，分別為金屬有機化學氣相沉積法和無鹼化學浴法。本研究嘗試找出兩種製程成長氧化鋅複合薄膜之最佳化參數，再經由一道退火處理改善複合薄膜內氧化鋅奈米粒的結晶性。進一步組裝固態無機的ITO/CuInS2 奈米管/氧化鋅奈米粒複合薄膜/Al 太陽能電池。結果顯示，以化學浴法形成氧化鋅薄膜所組裝之電池具有較佳之表現。目前所得CuInS2 奈米管-氧化鋅奈米粒複合薄膜電池之最高效率為0.033 ％。

In this study, CuInS2 nanotube arrays have been synthesized using successive ionic layer adsorption and reaction(SILAR) method. ZnO nanoparticles (NPs) are deposited in the interstices of CuInS2 nanotubes to form a CuInS2 nanotube-ZnO nanoparticle composite films. Formation of the ZnO nanoparticle composite films have been achieved using metalorganic chemical vapor deposition (MOCVD) and base-free chemical bath deposition(CBD) method. The optimal growth conditions are found for the growing ZnO composite films using both processes.Annealing of the ZnO composite films, is needed to improve the film quality. The solid-state inorganic ITO/CuInS2 nanotubes/ZnO nanoparticle composite film/Al solar cells are further fabricated. The CuInS2 nanotube-ZnO nanoparticle solar cell has an efficency of 0.033％ by using the CBD ZnO process.

摘要.......................................................I
Abstract..................................................II
致謝.....................................................III
目錄......................................................IV
表目錄....................................................IX
圖目錄.....................................................X
第一章緒論..................................................1
1-1 前言...................................................1
1-2 CuInS2材料.............................................2
1-3 氧化鋅(ZnO)材料.........................................3
1-4 CuInS2薄膜式太陽能電池簡介...............................4
1-5 研究動機與目的..........................................4
第二章 文獻回顧與理論基礎.....................................6
2-1太陽能電池發展概況........................................6
2-1.1結晶矽太陽能電池(Crystalline silicon solar cells).......6
2-1.2薄膜太陽能電池(Thin film solar cells)..................7
2-1.3染料敏化太陽能電池(Dye sensitized solar cell, DSSC).....9
2-2 CuInS2材料性質.........................................10
2-2.1 晶體結構.............................................10
2-2.2化學組成與光電性質.....................................12
2-3成長CuInS2薄膜之方法....................................14
2-3.1真空製程..............................................14
2-3.2 非真空製程...........................................15
2-4無鹼化學浴沉積法成長氧化鋅複合薄膜.........................21
2-5金屬有機化學氣相沉積法(MOCVD)成長氧化鋅薄膜................24
2-6 CuInS2薄膜式太陽能電池組成結構與工作原理..................26
2-6.1 基板................................................27
2-6.2吸光層...............................................27
2-6.3緩衝層...............................................28
2-6.4 透光層兼電子傳導層....................................29
2-6.5 金屬/導電玻璃對電極...................................29
2-6.6 CuInS2薄膜式太陽能電池工作原理.........................30
2-7 太陽能電池的電流電壓輸出特性.............................32
2-7.1 太陽光的頻譜照度......................................32
2-7.2 光電轉化效率的計算....................................34
第三章 實驗步驟與研究方法....................................37
3-1 實驗材料...............................................37
     3-2 實驗流程..........................................39
3-2.1基板前處理............................................40
3-2.2基板親水性處理與氧化鋅晶種層之披覆.......................40
3-2.3氧化鋅奈米線成長.......................................41
3-2.4以連續式離子層吸附與反應法製備CuInS2吸收層...............41
3-2.5硫氣氛退火處理........................................43
3-2.6氣相氧化鋅複合薄膜之成長................................44
     3-2.6.1化學氣相沉積法成長氧化鋅複合薄膜..................44
             3-2.6.2氧化鋅複合薄膜退火處理..................45
3-2.7液相氧化鋅複合薄膜之成長...............................45
     3-2.7.1以化學浴成長氧化鋅界面層於CuInS2奈米管表
             面上...........................................45
             3-2.7.2 無鹼化學浴成長氧化鋅複合薄膜............45
             3-2.7.3溶劑熱法成長氧化鋅複合薄膜...............45
3-2.7.4氧化鋅複合薄膜退火處理...............................46
3-2.8組裝CuInS2奈米管/氧化鋅全固態無機太陽能電池..............46
     3-3 分析及鑑定........................................48
3-3.1掃描式電子顯微鏡.......................................48
3-3.2紫外光/可見光光譜儀....................................49
3-3.3 X光繞射分析儀........................................51
第四章 結果與討論...........................................54
4-1 氧化鋅奈米線之特性分析..................................54
     4-2 CuInS2奈米管之特性分析.............................56
4-3氣相氧化鋅複合薄膜之成長與分析............................60
4-3.1成長溫度對複合結構表面形態之影響.........................60
        4-3.2成長溫度對複合結構特性之影響....................62
4-3.3成長時間對複合結構表面形態與特性之影響...................64
4-3.4不同退火條件之效應.....................................69
 4-4液相氧化鋅複合薄膜之成長與分析...........................72
        4-4.1溶液pH值對CuInS2奈米管表面成長氧化鋅晶種層之影響..72
        4-4.2 CuInS2奈米管-氧化鋅複合薄膜表面形態分析.........74
4-4.3 CuInS2奈米管-氧化鋅複合薄膜結構分析....................76
4-4.4 不同成長溫度條件之效應................................78
4-4.5 溶劑熱法成長氧化鋅複合薄膜之表面形態與效能分析...........81
        4-4.6化學浴法成長氧化鋅複合薄膜不同退火條件之效應......84
第五章 總結論..............................................86
第六章 未來工作與建議.......................................87
第七章 參考文獻............................................88

                                    

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