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研究生: 林致暄
Lin, Jhih-Syuan
論文名稱: 噴霧乾燥法製備表面改質之氮化鋁粉體
Prepare Surface Treatment of AlN Powder by Spray Drying Method
指導教授: 鍾賢龍
Chung, Shyan-Lung
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2003
畢業學年度: 91
語文別: 中文
論文頁數: 88
中文關鍵詞: 噴霧乾燥法氮化鋁
外文關鍵詞: aluminum nitride, spray dring method
相關次數: 點閱:111下載:11
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  • 本論文主要研究的目標是希望在氮化鋁的尖銳表面上批覆一層環氧樹脂,改變其原來的表面形態,變成為表面圓滑的顆粒,增加氮化鋁在各方面的應用。實驗上採用噴霧乾燥法來進行,主要探討的變因分成三部分:
    (1)不同的噴霧方式對於產物形態的影響
    (2)不同比例的環氧樹脂與氮化鋁混合成的進料對於產物 形態的影響
    (3)不同的氮化鋁粒徑對於產物形態的影響
    產物主要是以SEM、TEM、DSC等分析來進行完整而詳細的研究。

    In the present study, a spray coating method was developed to modify the surface of the combustion synthesized AlN powder. A layer of epoxy resin was formed on the surface of AlN powder to make a more sphere- like and morphology, which could increase applications of AlN in all respects, especially in composites. The research topic in present study could divide into three parts:
    (1)The effect of different spray method on the morphology of AlN product
    (2)The effect of different ratio of reactant on the morphology of product
    (3)The effect of different AlN particle size on the morphology of product
    The product analyzes by SEM、TEM、DSC.

    摘要………………………………………………………………………I Abstract…………………………………………………………………II 總目錄……………………………………………………………………III 表目錄……………………………………………………………………V 圖目錄……………………………………………………………………VI 符號………………………………………………………………………XI 第一章 緒 論……………………………………………………………1 1-1 簡介…………………………………………………………………1 1-2 氮化鋁的特性與其應用……………………………………………2 1-3 目前氮化鋁的合成技術……………………………………………4 1-4 研究動機……………………………………………………………5 第二章 噴霧乾燥原理 …………………………………………………7 2-1 簡 介 ………………………………………………………………7 2-2 原理…………………………………………………………………8 2-2.1 進料溶液的霧化 ………………………………………………8 2-2.2 霧化液滴與熱空氣的接觸………………………………………9 2-2.3 液滴焦煉硬化的過程……………………………………………9 2-2.4 硬化後顆粒粉末的分離與回收…………………………………10 2-3 熱平衡方式…………………………………………………………10 第三章 實驗儀器設備與藥品 …………………………………………16 3-1 簡介…………………………………………………………………16 3-2 藥品…………………………………………………………………17 3-3 實驗設備……………………………………………………………17 3-4 分析儀器……………………………………………………………20 第四章 實驗方法與結果討論 …………………………………………27 4-1 簡介…………………………………………………………………27 4-2 同向流(Co-Current)……………………………………………28 4-2.1 實驗步驟…………………………………………………………28 4-2.2 結果………………………………………………………………29 4-2.3 討論………………………………………………………………31 4-3 同向流(Co-Current)……………………………………………41 4-3.1 實驗步驟…………………………………………………………41 4-3.2 結果………………………………………………………………42 4-3.3 討論………………………………………………………………47 第五章 噴霧乾燥設備改進設計 ………………………………………78 5-1 舊有設備的缺點……………………………………………………78 5-2 改進要點與圖形設計………………………………………………79 第六章 綜合討論 ………………………………………………………83 參考文獻…………………………………………………………………85 自 述 ……………………………………………………………………88

    1.S.M. Kaplan and K. Felsvang,〝Spray Dryer Absorption of SO2 from Industrial Boiler Flue Gas,〞AICHE Symposium Series, Vol .76, No.201,1980,p23
    2.C.H. Norman, 〝Evaluation of the Effects of Selective Lime Slurry Preparation on Spray Dryer Efficiency in Flue Gas Desulfurization,〞M.S. Thesis, Univ. of Tenn., Knoxville, 1986
    3.袁中新,〝以噴霧乾燥原理同時去除燃燒廢氣中二氧化硫、氮氧化物及氯化氫之研究〞,國科會計畫研究報告NSC 79-0412-E006-38Z,1991。
    4.K. Masters, 〝Spray Drying Handbook,〞4th ed ., John Wiley, New York , 1985
    5.A.V. Virkar, T.B. Jackson, and R.A. Cutler, J. Am. Ceram. Soc. 72 (11), 2031 (1989).
    6.W.D. Kingery, H.K. Brown, and D.R. Uhlmann, Introduction to Ceramics, 2nd Edition, John Wiley and Sons, New York, p.3, 1976.
    7.汪建民,陶瓷技術手冊,上冊,中華民國粉末治金協會,頁2,民83。
    8.G. Pezzotti, I. Kamada, and S. Miki, Journal of the European Ceramic Society, 20, pp1197-1203, (2000).
    9.W. Kim, J.W. Bae, I.D. Choi, and Y.S. Kim, Polymer Engineering and Science, vol.39, no.4, pp756-765, (1999).
    10.Freddy Y.C. Boey, X.L. Song, C.Y. Yue, and Q. Zhao, Journal of Materials Processing Technology, 89-90, pp437-439, (1999).
    11.Daniel Tracy, Luu Nguyen, Richard Giberu, Anthony Gallo, and Charles Bischof, 1997.
    12.Eds.Man.F.Yan et al.,the American Ceramic Society, Inc., in: Advances in Ceramics, Vol.26: Ceramic Substrates and Packages for Electronic Application, pp.19-54.
    13.Ion V. Nicolaescu, Gabriel Tardos, and Richard E. Riman, "Thermogravimetric determination of carbon, nitrogen, and oxygen in aluminum nitrde, " Journal of the American Ceramic Society, 77, 9, pp.2265-2272, 1994.
    14.Gregg E. Potter, Arne K Knudsen, and James C. Tou, "Measurement of the oxygen and impurity distribution in polycrystalline aluminum nitride with secondary ion mass spectrometry, " Journal of the American Ceramic Society, 75, 12, pp.3215-3224, 1992.
    15.Anthony A. Gallo, Charles S. Bischof, Kevin E. Howard, Stephen A. Anderson, “Moisture Resistant Aluminum Nitride Filler for High Thermal Conductivity Microelectronic Molding Compound,” 1996 Electronic Component and Technology Conference, pp335-342, (1996).
    16.G.P. Partridge, 〝A Mechanistic Spray Dryer Mathematical Model Based on Film Theory to Predict Sulfur Dioxide Absorption and Reaction by a Calcium Hydroxide Slurry in the Constant Rate Period,〞PH.D. Dissertation, Univ. of Tenn., Knoxville, 1987.
    17.J. Klingspor, 〝Improved Spray Dry Scrubbing through Grinding of FGD Recycle Material,〞JAPCA, Vol.37, No.7, 1987, p801
    18.G. Selvaduray and L. Sheet, Mater. Sci. Technol. 9, 463(1993).
    19.F. J-H. Haussonne, Mater. Manufacturing Process 10(4), 717(1995).
    20.A. G. Merzhanov and I. P. Borovinskaya, Combust. Sci. Technol. 10, 195(1975).
    21.W.L. Yu, C.N. Lin, and S.L. Chung, "Self-propagating high-temperature synthesis method for synthesis of AlN powder," Journal of Materials Research, vol.14, no. 5, pp.1928-1933, 1999.
    22.W.C. Lee, C.L. Tu, C.Y. Weng, and S.L. Chung, "Novel process for combustion synthesis of AlN powder," Journal of Materials Research vol.10, no.3, pp.774-778, 1995.
    23.S.L. Chung and W.L. Yu, "Method for preparing aluminum nitride powders," U.S. Patent, 5846508, Dec. 8, 1998.
    24.S.L. Chung, "Method of manufacturing a powdery AlN," U.S. Patent, 5460794, Oct 24, 1995.
    25.S.L. Chung and W.C. Lee, "Method for producing nitride ceramic powders," U.S. Patent, 5453407, Sep 26, 1995.
    26.Howard, Kevin E. "Method of Making Moisture Resistant Aluminium Nitride Powder and Powder Produced Thereby," U.S. Patent, 5234712, Aug. 10, 1993.
    27.J.Y. Yeh, R.J. Demski, D.F. Gyorke, and J.I. Joubert,〝Experiment Evalution of Spray Dryer Flue Gas Desulfurization for Use with Eastern U.S. Coals,〞Proc. Of the EPA/EPRI Symposium on Flue Gas Desulfurization, Hollywood, Florida, 1982
    28.Y. Q. Li, T. Qiu, J. Xu, and X. C. He, “Surface Modification of Aluminium Nitride Powder”, J. Mater. Sci. Lett.,15, 1758-1761, 1996.
    29.M.H. Grant, Encyclopedia of Chemical Technology, 4th edition, vol. 21, John Wiley and Sons, New York, p.387, 1998.
    30.陳惠軍, “氮化鋁粉體表面披覆無機物之抗濕處理技術”, 成功大學碩士論文, 民91年畢業。
    31.謝承佑, “氮化鋁粉體水解性質探討與抗濕技術開發”, 成功大學碩士論文, 民91年畢業。
    32.M.H. Grant, Encyclopedia of Chemical Technology, 4th edition, vol. 21, John Wiley and Sons, New York, p.387, 1998.
    33.S.R. Dantuluri, 〝Limitation of Sulfur Dioxide Removal in a FGD Spray Dryer Using Once through Slaked Lime,〞PH.D. Dissertation, Univ. of Tenn., Knoxville, 1988.
    34.Messing, G.L., Zhang, S.C., and Jayanthi, G.V., J.AM. Ceram. Soc., 76(11),2707-2725(1993)
    35.Cho S.Y., J.H. Lee, S.J. Park, J. Materials Sci.,30, 3274-3278(1995)
    36.Anthony A. Gallo, Charles S. Bischof, Kevin E. Howard, Stephen A. Anderson, “Moisture Resistant Aluminum Nitride Filler for High Thermal Conductivity Microelectronic Molding Compound,” 1996 Electronic Component and Technology Conference, pp335-342, (1996).
    37.N. Kuramoto, H.Taniguchi, and I. Aso, Am.ceram.Soc.Bull.,68[4], p883-887, (1989).
    38.Eds.Man.F.Yan et al.,the American Ceramic Society, Inc., in: Advances in Ceramics, Vol.26: Ceramic Substrates and Packages for Electronic Application, pp.19-54.
    39.T.Ku Babu, G. Narsimhan, and C.R. Philips,〝An Experimental Study on Spray Dry SO2 Scrubbing, 〞77th Annual Meeting of JAPCA, Sanfrancisco, Cal., 1984.

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