本研究以溶液聚合法，合成出具有導離子性的均聚物，和將導離子性的單體加入親水基(AM)/疏水基(MA)單體合成無規共聚高分子，分別為P、PcAM、PcMA，利用傅立葉紅外線光譜儀(FT-IR)及核磁共振儀(1H-NMR)證實成功合成和利用凝膠滲透色譜(GPC)確認三種高分子分子量(Mn)分別是347,461Da、377,103Da，376,500Da，並將高分子作為正極黏著劑應用於鋰電池中，探討其正極漿料流變性質和電化學性質，且以商業用黏著劑PVDF進行比較。本研究以傅立葉紅外線光譜儀確認出導離子官能基與正極漿料中的導電碳作用位置；並以迴旋式磁流變儀中的動態頻率掃描觀察到添加PcAM、PcMA的漿料中，網格強度較小；以及利用光學顯微鏡，以及高分子與導電碳形成的薄膜之導電度測試，確認出P及其共聚高分子能使漿料中導電碳的分散較為均勻，其中又以PcAM的分散表現最佳。此外在電化學測試中，PcAM在LiNi1/3Co1/3Mn1/3O2電池放電速率10C電容為70 mAh g-1；在LiFePO4電池中於5C放電速率電容仍有118 mAh g-1，相比PVDF擁有更佳的電化學表現。經由循環充放電測試中，本實驗合成的黏著劑在磷酸鋰鐵電池200圈充放電測試維持庫侖效率99%。

In this study, we synthesized three kinds of polymer, including: P, PcAM, and PcMA. P was homopolymer which was polymerized via ion conducting monomer. PcAM / PcMA were random copolymers which were polymerized via ion conducting monomer incorporated hydrophile (AM) / lyophile (MA) monomer, respectively. The number average molecular weight of P, PcAM and PcMA were 347,461Da, 377,103Da and 376,500Da respectively via GPC. These three polymers were used as binders for cathode of lithium battery. Herein, we discussed rheological properties of electrode slurry and electrochemical performance with various binders. By FT-IR, we found the interaction between conductive agent (SuperP) and our binders, which occurred at conducting group and -NH2 of hydrophile group. Additionally, we found that modified-polymers, PcAM and PcMA, were more well dispersed than P in the N-Methyl-2-Pyrrolidone. By angular frequency sweep test of cathode slurry, we observed that PcAM and PcMA could more effectively disperse percolated structure composed of SuperP via colloidal force, however, commercial Polyvinylidene difluoride (PVDF) was not observed this phenomenon. Also, we used Optical Microscope to observe dispersion of SuperP in different polymer-contained slurry and measured electrical conductivity of polymer/SuperP film to confirm that when using PcAM as binder, the dispersion of SuperP would become better. In electrochemical performance of LFP cathode, PcAM exhibited 118mAh g-1 at 5 C rate compared with 71 mAh g-1 for PVDF. In cycling test, PcAM exhibited better cycling stability. After charging-discharging with 1 C rate 200 times, its capacity retention was 99% compared with 93.7% for PVDF.

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