在本文中，利用銅金奈米空球使我們成功地製備出奈米容器，奈米容器是一種複合奈米材料，其結構是利用銅金奈米空球以及網狀高分子所結合而成的一種核-殼結構，其中銅金奈米空球是實驗室之前成果，高分子外殼則是利用表面科技的操縱所得，而高分子外殼在此奈米容器中扮演著相當重要的角色，由於它的存在賦予了銅金奈米空球具有可控制性的通透能力。此外更藉由使用不同種類的物質作為填充物(像是染料分子DNA 之類的)來進行一系列的研究，這些研究皆是為了用以證明奈米容器的性質，而在此螢光光譜儀以及螢光顯微鏡的使用便有助於我們去證明製備出的奈米容器是具有可控制的填充以及釋放功能，並且可適用於多種物質的。

　The synthesis of nano-capsules by utilizing CuAu hollow nano-spheres was described in this study. Nano-capsules are the complex materials, with the core adopted of CuAu hollow nano-spheres and the shell made of net-like polymer with an engineered outermost layer. The net-like polymer plays an important role in this study, because it can provide the tunable permeability to CuAu hollow. The unique ability of the developed nanocapsules was further discussed by using several kinds of dye molecules and DNA as fillers. The multifunctional nano-capsules, capable of controlling incubation and release, were demonstrated. And the investigations of incubation and release have been characterized by fluorescence spectrophotometer and fluorescence microscope. The results confirmed that the nano-capsules indeed possessed encapsulating and releasing properties, and can be applied in various kinds of substances.

(01) J. H. Fendler, Chem. Rev., 87, 877 (1987)
(02) H. Freundlich, D. Striner, J. Chem. Soc., 1081 (1937)
(03) M. Ichikawa, N. Wada, J. Appl. Phys., 15, 755, (1976)
(04) D. G. Eadon, J. A. Creighton, J. Chem. Soc. Farady. Trans., 87, 3881 (1991)
(05) H. Hung, G. Q. Xu, W. Ji, Y. M. Kek, C. H. Chew, F. Q. Yan, P. S. Oh, S. H. Tang,
Lanmuir, 13, 172 (1997)
(06) I. Lisiecki, M. P. Pileni, J. AM. CHEM. SOC. 115, 3887 (1993)
(07) Q. Limin, M. Jiming, S. Ulin, J. Collo. Inter. Sci., 86, 498 (1997)
(08) Z. Paszti, Z.E. Horvath, G. Peto, A. Karacs, L. Guczi, Appl. Surf. Sci., 109, 67
(1997)
(09) N. A. Dhas, C. P. Raj, A. Gedanken, Chem. Mater., 10, 1446 (1998)
(10) A. Henglein, J. Phys. Chem. B, 104, 1206 (2000)
(11) G. Schimid, “Cluster and Colloids”, From Theory to Application
(12) Yu Chang, Mei Ling Lye, and Hua Chun Zeng, Langmuir, 21, 3746 (2005)
(13) H. Hirai, Hidehiko, Wakabayshi, M. Komiyama, Chem. Lett, 1047 (1983)
(14) S. M. Angel, L. F. Katz, D. D. Archibald, D. E. Honigs, Appl. Spectro., 43, 367
(1989)
(15)(a) Y. H. Yeh, M. S. Yeh, Y. P. Lee, C. S. Yeh, Chem. Lett., 1183 (1998) (b) M. S.
Yeh, Y. S. Yang, Y. P. Lee, H. F. Lee, Y. H. Yeh, C. S. Yeh, J. Phys. Chem. B., 103,
6851 (1999)
(16) A. Paul Alivisatos, Science, 404, 59 (2000)
(17) Younan Xia et al., J. AM. CHEM. SOC. 125, 13364-13365 (2003)
(18) A. Paul Alivisatos et al., Science, 304, 711 (2004)
(19) Younan Xia and Peidong Yang et al., Adv. Mater., 15, 353 (2003)
(20) http：//chiuserv.ac.nctu.edu.tw/~htchiu/
(21)(a) Yugang Sun, Bruan T. Mayers, and Younan Xia, Nano Lett., 2, 481-485 (2002)
(b)陳信甫, “銅奈米粒子的探討:硫醇吸附的影響與金銅奈米空球的製備＂, 國
立成功大學博碩士論文, 化學 (2002)
(22) Seiji Shinkai et al., Angew. Chem. Int. Ed., 42, 980 (2003)
(23) Frank Caruso, Rachel A. Caruso, Helmuth Mohwald, Science, 282, 1111 (1998)
(24) Yugang Sun and Younan Xia, Adv. Mater., 16, 264-268 (2004)
(25) F. Caruso, Adv. Mater., 13, 11 (2001)
(26) Hollow and Solid Spheres and Microspheres：Science and Technology Associated
with Their Fabrication and Application；Material Research Society：Pittsburgh, PA
(1994)
(27) S. W. Kim, M. Kim, W. Y. Lee, T. Hyeon, J. AM. CHEM. SOC. 124, 7642, (2002)
(28) Y. Sun, B. Mayers, Y. Xia, Adv. Mater., 15, 641 (2003)
(29) Bigelox W. C., Pickett D. L., Iisman W. A., J. Colloid Interface Sci., 1, 513
(1946)
(30) Dubois L. H., Nuzzo R. G., Ann. Phys. Chem., 43, 437 (1992)
(31) Kumar A., Biebuyk H. A., Whitesides G. M., Langmuir, 10, 1498 (1994)
(32) A. Paul Alivisatos et al., Science, 281, 2013 (1998)
(33) Francisco J. Arregui and Ignacio R. Matias, Optics Letters, 26, 131 (2001)
(34) Marc Saner, Daniel Streich, and Wolfgang Meier, Adv. Mater., 13, 1649 (2001)
(35) Dong-Yu Kim et al., Angew. Chem. Int. Ed., 44, 1096-1101 (2005)
(36) Gleb B. Sukhorukov et al., Angew. Chem. Int. Ed., 42, 4471-4475 (2003)
(37) Dmitry G. Shchukin and Gleb B. Sukhorukov., Adv. Mater., 16, 671-682 (2004)
(38) Frank Caruso, Chem. Eur. J., 6, 413-419 (2000)
(39) Yajun Wang and Frank Caruso, Angew. Chem. Int. Ed., 44, 2888-2892 (2005)
(40) Helmuth Mohwald et al., Nano Lett., ASAP
(41) Jin-Kyu Lee et al., Angew. Chem. Int. Ed., 44, 1068-1071 (2005)
(42) Gleb B. Sukhorukov and Helmuth Mohwald et al., Adv. Mater., 17, 468-472
(2005)
(43) Gleb B. Sukhorukov et al., Angew. Chem. Int. Ed., 44, 3310-3314 (2005)
(44) Juan Rodriguez-Hernandez and Sebastien Lecommandoux, J. AM. CHEM. SOC.
127, 2026-2027, (2005)
(45) Kumaresh S. Soppimath, Dorren Cherng-Wen Tan, and Yi-Yan Yang, Adv.
Mater., 17, 318 (2005)
(46) Gleb B. Sukhorukov et al., J. AM. CHEM. SOC. 126, 2274-3375, (2004)
(47) Xiaojun Zhao, Rovelyn Tapec-Dytioco, and Weihong Tan, J. AM. CHEM. SOC.
125, 11474-11475, (2003)
(48) Chia-Chun Chen et al., Adv. Mater., 17, 404-407 (2005)