本研究合成一新穎性含光學活性菠酯基單體(Bornyl-4-(6-acryloyloxyhexyloxy) benzoate)，並利用其與β-環糊精形成包容錯合物來作一系列的特性探討。由1H-NMR分析得知，一光學活性單體可與兩到三個β-環糊精形成包容錯合物。此包容錯合物更進一步以FTIR、DSC、TGA、XRD、SEM及13C CP/MAS NMR鑑定。而由於光學活性單體幾乎被包合在β-環糊精中，因此即使加了熱起始劑(Benzoyl peroxide) 或光起始劑再加熱或照光也不能聚合。
於TEM下觀察，此包容錯合物在不同混合溶劑下將自組裝成不同的結構。在pyridine/water共溶劑中，包容錯合物呈現蝴蝶似結構；在pyridine/methanol混合溶液中，為棒狀結構；在pyridine/acetone系統則是球狀結構。且於pyridine/water與pyridine/methanol兩系統中，一旦共溶劑的比例達到1，包容錯合物的結構都將變為圓球形的結構。另一方面，以SEM、POM觀察，包容錯合物在溶劑中也可自組裝成為微米級結構，並在各個共溶劑系統，都是以薄片或棒狀結構方式呈現。

A novel chiral monomer containing bornyl group (Bornyl-4-(6-acryloyloxyhexyloxy) benzoate) was synthesized. The chiral monomer was then threaded with β-cyclodextrin. Formation of inclusion complexes was confirmed and characterized using FTIR, 1H-NMR, DSC, TGA, XRD, SEM, and 13C-CP/MAS NMR. From the result of 1H-NMR, it shows that two or three β-cyclodextrin molecules were threaded onto the synthesized chiral monomer. However, due to the stereo-hindrance of the threaded β-cyclodextrins, both thermo and photo polymerization were not observed.
Self-assembly of the synthesized inclusion complexes in various solvents were studied using TEM. In pyridine/water and pyridine/methanol cosolvents, butterfly-like and rod-like self-assembled structures were observed, respectively. Furthermore, in pyridine/acetone system, a ball-like structure was observed. Solvent ratio effect on the self-assembly of inclusion complex was investigated. It was found that in both pyridine/water and pyridine/methanol systems, self-assembled constructions of the systems changed to ball-like when the ratio of cosolvent reached 1. Micro-scaled self-assembled structure of the inclusion complexes was investigated using SEM and POM as well.

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