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研究生： 謝會龍
Nugroho, Rusli Adi
論文名稱： 利用玻璃纖維作為TiO2薄膜載體以製作可撓式染料敏化太陽能電池
A Flexible Dye-Sensitized Solar Cell with Fiber Glass for Titanium Dioxide Film Coating
指導教授： 吳文騰
Wu, Wen-Teng
共同指導教授: 李玉郎
Lee, Yu-Lang
學位類別： 碩士
Master
系所名稱： 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年： 2011
畢業學年度： 99
語文別： 英文
論文頁數： 101
中文關鍵詞： 可撓式染料敏化太陽能電池 、再生能源 、可撓式 、玻璃纖維 、高溫處理
外文關鍵詞： A flexible dye-sensitized solar cells, renewable energy source, fiber glass, high temperature treatment
相關次數： 點閱：112  下載：2 
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    • 因應全球越來越注重環保概念影響之下，近年來染料敏化太陽能電池 (DSSCs)不僅價格低廉，高效率功能轉換以及符合環保科技已成為工程領域及學術研究最為熱門的研究之一。觀察現今研究發現，利用輕量化 加上可撓式的材質應用在可撓式染料敏化太陽能電池也逐漸成為熱門研究。為了符合商業化的需求，我們創造全新的可撓式染料敏化太陽能電池，不僅利用輕量化以及可撓式的特性外，更是能在高溫下去處理二氧化矽的燒結。
    本論文應用以及使用玻璃纖維材質包覆的二氧化矽當作電極，在TCO裡噴濺白金當作此電池的對電極，而D149和N179染料敏化劑以及MPN (3-methoxypropionitrile) 電解液當作有機的氧化還原反應也是用來完成包覆著玻璃纖維的可撓式染料敏化太陽能電池。
    光電流 – DSSC的電壓特性結果呈現為Jsc: 7.196 mA/m2, Voc: 0.65 Volt, FF: 0.517 以及在低於1 sun illumination (100mW/cm2)之下有2.421%的效果。本論文實驗指出使用玻璃纖維材質在高溫作業上產生可撓式染料敏化太陽能電池是可行的。

    Dye-sensitized solar cells (DSSCs) have been promoted in the decades due to their low cost, highly efficient conversion of visible light into electricity and also an eco-friendly production. Recently, a flexible dye-sensitized solar cell using light weighting and bendable materials also attract a lot of attention. In order to meet the requirements of commercial applications, we develop flexible dye-sensitized solar cells, which are light weighting and bendable materials with high temperature treatment for sintering process of TiO2.
    In the present study, we used TCO (transparent conducting oxides) glass and TiO2 paste which was coating in fiber glass as a working electrode. The platinum – sputtered in TCO glass was used as counter electrode for this cell. D149 and N719 dye sensitizers and MPN (3-methoxypropionitrile) electrolyte as organic redox solution were also used to complete the fabrication of dye-sensitized solar cell with fiber glass.
    The Photocurrent – Voltage characterization of DSSC give the result with Jsc: 7.196 mA/m2, Voc: 0.65 Volt, FF: 0.517 and 2.421 % efficiency under 1 sun illumination (100mW/cm2). This result indicates that using fiber glass as material for produce flexible dye-sensitized solar cell in high temperature treatment is possible.

    ABSTRACT i 摘要 ii ACKNOWLEDGMENT iii TABLE OF CONTENTS iv LIST OF TABLES vii LIST OF FIGURES viii CHAPTER ONE INTRODUCTION 1 1.1. Research Background 1 1.2. Research Motivation 3 CHAPTER TWO LITERATURE REVIEW 5 2.1. Titanium Dioxide 5 2.1.1. Titanium Dioxide Properties 5 2.1.2. The Evolution of Dye-Sensitized Solar Cells 7 2.1.3. CCIC Titanium Dioxide 16 2.2. Fiber Glass Properties and Application 16 2.3. Dye-Sensitized Solar Cells 20 2.3.1. The Development of Dye-Sensitized Solar Cells 20 2.3.2. Operating Principles of Dye-Sensitized Solar Cells 32 2.3.3. Composition of Dye-Sensitized Solar Cells 38 2.3.4. Characterization of Dye-Sensitized Solar Cells 46 2.4. Flexible Dye-Sensitized Solar Cells 48 CHAPTER THREE MATERIALS and METHODS 51 3.1. Chemical and Materials 51 3.1.1. Chemicals 51 3.1.2. Materials 52 3.2. Experimental Instruments 52 3.3. Experimental Analysis 56 3.4. Experimental Methods 58 3.4.1. Pretreatment of FTO Conducting Glass 58 3.4.2. Screen Printing Method 58 3.4.3. Preparation Photoelectrode for n-DSSC 58 3.4.4 Preparation Photoelectrode for Fiber Glass-DSSC 59 3.4.5. Preparation Photoelectrode for Fiber Glass-DSSC DSSC with blocking layer 59 3.4.6. Preparation Photoelectrode for Separated Sintering Analysis 59 3.4.7. Preparation of Counter Electrode with Pt-Sputtering 60 3.4.8. Assembling the Cells 60 CHAPTER FOUR RESULTS and DISCUSSIONS 61 4.1. Morphology of Titanium Dioxide Nanoparticles Film for Three Different Thickness of Fiber Glass 61 4.2. The Thickness Effect of Fiber Glass on the Performance of DSSCs 65 4.3. The Influence of Dye-Sensitizer on the Performance of Fiber Glass DSSCs 72 4.4. An Enhancement of Fiber Glass DSSCs by Increasing the Thickness of TiO2 Film Layer 76 4.5. The Influence of Blocking Layer (Precursor) on the Performance of Fiber Glass DSSCs 79 CHAPTER FIVE CONCLUSIONS and SUGGESTIONS 87 5.1. Conclusions 87 5.2. Suggestions 88 REFERENCES 90

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